Abstract
After performing this experiment, the student shall be able to:
-
Understand key interactions between metal sulfides and their natural surroundings.
-
Mimic mine tailings and observe their oxidation by different species.
-
Test the role of Fe(III) as a natural oxidizer.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
Literature References
August, E. E.; McNight, D. M.; Hrncir, D. C.; Garhart, K. S. “Seasonal Variability of Metals Transport Through a Wetland Impacted by Mine Drainage in the Rocky Mountains,” Environ. Sci. Technol. 2002, 36, 3779–3786.
Batty, L. C.; Younger, P. L. “Critical Role of Macrophytes in Achieving Low Iron Concentrations in Mine Water Treatment Wetlands,” Environ. Sci. Technol. 2002, 36, 3997–4002.
Bonnissel-Gissinger, P.; Alnot, M.; Ehrhardt, J.-J.; Behra, P. “Surface Oxidation of Pyrite as a Function of pH,” Environ. Sci. Technol. 1998, 32, 2839–2845.
Chernyshova, I. V. “An in Situ FTIR Study of Galena and Pyrite Oxidation in Aqueous Solution,” J. Electroanal Chem. 2003, 558, 83–98.
Hansen, J. P.; Jensen, L. S.; Bedel, S.; Dam-Johansen, K. “Decomposition and Oxidation of Pyrite in a Fixed-Bed Reactor,” Ind. Eng. Chem. Res. 2003, 42, 4290–4295.
Hao, Y.; Dick, W. A. “Potential Inhibition of Acid Formation in Pyritic Environments Using Calcium Sulfite Byproduct,” Environ. Sci. Technol. 2000, 34, 2288–2292.
Horan, J. H.; Wildeman, T. R. Dept. of Chemistry and Geochemistry, Colorado School of Mines. “Environmental Chemistry in Colorado Toxic Mine Drainage: Chemistry and Treatment,” 2005, http://www.mines.edu/fs_home/jhoran/ch126/index.htm
Horan, J. H.; Wildeman, T. R.; Ernst, R. “Acid Mine Drainage Laboratory Experiments,” 214th. Am. Chem. Soc. Nat. Meet., Chem. Ed. Division Paper # 005. Las Vegas, NV, Sept. 7–11, 1997.
Howard, A. G. Aquatic Environmental Chemistry; Oxford Chemistry Primers. Oxford Science Publications: Oxford, 1998. Chapter 5.
Ibanez, J. G. “Microscale Environmental Chemistry. Part 6. Water Acidification by Oxidation of Mineral Sulfides (Acid Mine Drainage),” Chem. Educ. 2006, 11, 251–253.
Kargbo, D. M.; Atallah, G.; Chatterjee, S. “Inhibition of Pyrite Oxidation by a Phospholipid in the Presence of Silicate,” Environ. Sci. Technol. 2004, 38, 3432–3441.
Kuslu, S.; Bayramoglu, M. “Microwave-Assisted Dissolution of Pyrite in Acidic Ferric Sulfate Solution,” Ind. Eng. Chem. Res. 2002, 41, 5145–5150.
McNeil, M. B.; Little, B. J. “The Use of Mineralogical Data in Interpretation of Long-Term Microbiological Corrosion Processes: Sulfiding Reactions,” J. Am. Inst. Conserv. 1999, 38, 186–199.
Naicker, K.; Cukrowska, E.; McCarthy, T. S. “Acid Mine Drainage Arising from Gold Mining Activity in Johannesburg, South Africa and Environs,” Environ. Poll. 2003, 122, 29–40.
News of the Week. Chem. & Eng. News. Nov. 10, 2003, p. 16.
Nordstrom, D. K.; Alpers, C. N.; Ptacek, C. J.; Blowers, D. W. “Negative pH and Extremely Acidic Mine Waters from Iron Mountain, California,” Environ. Sci. Technol. 2000, 34, 254–258.
Rawls, R. “Some Like it Hot”, Chem. Eng. News Dec. 21, 1998. p. 35–39.
Singer P. C.; Stumm, W. “Acidic Mine Drainage: The Rate Determining Step,” Science 1970, 167, 1121–1123.
Sundstrom, R.; Astrom, M.; Osterholm, P. “Comparison of the Metal Content in Acid Sulfate Soil Runoff and Industrial Effluents in Finland,” Environ. Sci. Technol. 2002,36, 4269–4272.
Usher, C. R.; Cleveland, C. A. Jr.; Strongin, D. R.; Schoonen, M. A. “Origin of Oxygen in Sulfate during Pyrite Oxidation with Water and Dissolved Oxygen: An In Situ Horizontal Attenuated Total Reflectance Infrared Spectroscopy Isotope Study,” Environ. Sci. Technol. 2004, 38, 5604–5606.
Wildeman, T. R.; Schmiermund, R. “Mining-Influenced Waters: Their Chemistry and Methods of Treatment,” 2004 National Meeting of the American Society of Mining and Reclamation and The 25th West Virginia Surface Mine Drainage Task Force, April 18–24, 2004.
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 2008 Springer Science+Business Media, LLC
About this chapter
Cite this chapter
Ibanez, J.G., Hernandez-Esparza, M., Doria-Serrano, C., Fregoso-Infante, A., Singh, M.M. (2008). Acid Mine (or Acid Rock) Drainage. In: Environmental Chemistry. Springer, New York, NY. https://doi.org/10.1007/978-0-387-49493-7_11
Download citation
DOI: https://doi.org/10.1007/978-0-387-49493-7_11
Publisher Name: Springer, New York, NY
Print ISBN: 978-0-387-49492-0
Online ISBN: 978-0-387-49493-7
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)