Skip to main content

Photocatalytic Hydrogen Production from Water on Visible Light-Responsive TiO2 Thin Films Under Solar Light Irradiation

  • Chapter
  • First Online:
Environmentally Benign Photocatalysts

Part of the book series: Nanostructure Science and Technology ((NST))

Abstract

The recent progress in the photocatalytic decomposition of water by visible light-responsive TiO2 (Vis-TiO2) thin film photocatalysts is reviewed here. Special attention is focused on the separate evolution of H2 and O2 from water using Vis-TiO2 thin films prepared by a radio-frequency magnetron sputtering method. These Vis-TiO2 thin films were found to act as efficient photocatalysts for the decomposition of water with the separate evolution of H2 and O2 from H2O under visible or solar light irradiation.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 89.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 119.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  • Anpo M (1997) Photocatalysis on titanium oxide catalysts: Approaches in achieving highly efficient reactions and realizing the use of visible light. Catal Surv Jpn 1:169–179

    Article  CAS  Google Scholar 

  • Anpo M (2004) Preparation, characterization, and reactivities of highly functional titanium oxide-based photocatalysts able to operate under UV–Visible light irradiation: Approaches in realizing high efficiency in the use of visible light. Bull Chem Soc Jpn 77:1427–1442

    Article  CAS  Google Scholar 

  • Anpo M, Takeuchi M (2003) The design and development of highly reactive titanium oxide photocatalysts operating under visible light irradiation. J Catal 216:505–516

    Article  CAS  Google Scholar 

  • Anpo M, Dohshi S, Kitano M, Hu Y, Takeuchi M, Matsuoka M (2005) The preparation and characterization of highly efficient titanium oxide-based photofunctional materials. Annu Rev Mater Res 35:1–27

    Article  CAS  Google Scholar 

  • Asahi R, Morikawa T, Ohwaki T, Aoki K, Taga Y (2001) Visible-light photocatalysis in nitrogen-doped titanium oxides. Science 293:269–271

    Article  CAS  Google Scholar 

  • Cai QY, Paulose M, Varghese OK, Grimes CA (2005) The effect of electrolyte composition on the fabrication of self-organized titanium oxide nanotube arrays by anodic oxidation. J Mater Res 20:230–236

    Article  CAS  Google Scholar 

  • Choi WY, Termin A, Hoffman MR (1994) The role of metal ion dopants in quantum-sized TiO2: Correlation between photoreactivity and charge carrier recombination dynamics. J Phys Chem 98:13669–13679

    Article  Google Scholar 

  • Fujishima A, Honda K (1972) Electrochemical photolysis of water at a semiconductor electrode. Nature 238:37–38

    Article  CAS  Google Scholar 

  • Fujishima A, Rao TN, Tryk DA (2000) Titanium dioxide photocatalysis. J Photochem Photobiol C: Photochem Rev 1:1–21

    Article  CAS  Google Scholar 

  • Hurum DC, Agrios AG, Gray KA, Rajh T, Thurnauer MC (2003) Explaining the enhanced photocatalytic activity of Degussa P25 mixed-phase TiO2 using EPR. J Phys Chem B 107:4545–4549

    Article  CAS  Google Scholar 

  • Irie H, Watanabe Y, Hashimoto K (2003) Carbon-doped anatase TiO2 powders as a visible-light sensitive photocatalyst. Chem Lett 32:772–773

    Article  CAS  Google Scholar 

  • Khan SUM, Al-Shahry M, Ingler WB Jr (2002) Efficient photochemical water splitting by a chemically modified n-TiO2. Science 297:2243–2245

    Article  CAS  Google Scholar 

  • Kikuchi H, Kitano M, Takeuchi M, Matsuoka M, Anpo M, Kamat PV (2006) Extending the photoresponse of TiO2 to the visible light region: Photoelectrochemical behavior of TiO2 thin films prepared by the radio frequency magnetron sputtering deposition method. J Phys Chem B 110:5537–5541

    Article  CAS  Google Scholar 

  • Kitano M, Takeuchi M, Matsuoka M, Thomas JM, Anpo M (2005) Preparation of visible light-responsive TiO2 thin film photocatalysts by an RF magnetron sputtering deposition method and their photocatalytic reactivity. Chem Lett 34:616–617

    Article  CAS  Google Scholar 

  • Kitano M, Funatsu K, Matsuoka M, Ueshima M, Anpo M (2006) Preparation of nitrogen-substituted TiO2 thin film photocatalysts by the radio frequency magnetron sputtering deposition method and their photocatalytic reactivity under visible light irradiation. J Phys Chem B 110:25266–25272

    Article  CAS  Google Scholar 

  • Kitano M, Takeuchi M, Matsuoka M, Thomas JM, Anpo M (2007) Photocatalytic water splitting using Pt-loaded visible light-responsive TiO2 thin film photocatalysts. Catal Today 120:133–138

    Article  CAS  Google Scholar 

  • Maeda K, Teramura K, Lu D, Takata T, Saito N, Inoue Y, Domen K (2006) Photocatalyst releasing hydrogen from water: Enhancing catalytic performance holds promise for hydrogen production by water splitting in sunlight. Nature 440:295

    Article  CAS  Google Scholar 

  • Matsuoka M, Kitano M, Takeuchi M, Anpo M, Thomas JM (2005) Photocatalytic water splitting on visible light-responsive TiO2 thin films prepared by a RF magnetron sputtering deposition method. Top Catal 35:305–310

    Article  CAS  Google Scholar 

  • Sayama K, Mukasa K, Abe R, Abe Y, Arakawa H (2001) Stoichiometric water splitting into H2 and O2 using a mixture of two different photocatalysts and an IO 3 /I shuttle redox mediator under visible light irradiation. Chem Commun 2416–2417

    Google Scholar 

  • Takeuchi M, Anpo M, Hirao T, Itoh N, Iwamoto N (2001) Preparation of TiO2 thin film photocatalysts working under visible light irradiation by applying a RF magnetron sputtering deposition method. Surf Sci Jpn 22:561–565

    Article  CAS  Google Scholar 

  • Torimoto T, Fox RJ, Fox MA (1996) Photoelectrochemical doping of TiO2 particles and the effect of charge carrier density on the photocatalytic activity of microporous semiconductor electrode films. J Electrochem Soc 143:3712–3717

    Article  CAS  Google Scholar 

  • Umebayashi T, Ymaki T, Itoh H, Asai K (2002) Band gap narrowing of titanium dioxide by sulfur doping. Appl Phys Lett 81:454–456

    Article  CAS  Google Scholar 

  • Zhao GL, Utsumi S, Kozuka H, Yoko T (1998) Photoelectrochemical properties of sol-gel-derived anatase and rutile TiO2 films. J Mater Sci 33:3655–3659

    Article  CAS  Google Scholar 

  • Zou Z, Ye J, Sayama K, Arakawa H (2001) Direct splitting of water under visible light irradiation with an oxide semiconductor photocatalyst. Nature 414:625–627

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by a “Grant-in-Aid for the Creation of Innovations through Business–Academic–Public Sector Cooperation” (No. 13308) from the Ministry of Education, Culture, Sports, Science, and Technology of Japan. The authors would like to express sincere thanks for their kind support.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Masaaki Kitano .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2010 Springer Science+Business Media LLC

About this chapter

Cite this chapter

Kitano, M., Takeuchi, M., Matsuoka, M., Ueshima, M., Anpo, M. (2010). Photocatalytic Hydrogen Production from Water on Visible Light-Responsive TiO2 Thin Films Under Solar Light Irradiation. In: Anpo, M., Kamat, P. (eds) Environmentally Benign Photocatalysts. Nanostructure Science and Technology. Springer, New York, NY. https://doi.org/10.1007/978-0-387-48444-0_23

Download citation

Publish with us

Policies and ethics