Abstract
Worldwide in the past decade, nanoscience and nanotechnology has become a popular field for research and development. As an example to explain its potential significance, heterogeneous catalysis was cited as a successful application that has great benefits for society. Thus, it is reasonable to expect that the explosion in new developments in nanoscience and nanotechnologywould have a significant impact on the understanding, practice, and applications of catalysis. In this paper, a brief account is presented using selected examples to illustrate ways that these recent developments have advanced heterogeneous catalysis, both in terms of better control of heterogeneous catalytic processes, and of applying catalysis to developments in nanotechnology.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
http://www.nano.gov/html/facts/whatIsNano.html, December 30, 2004.
F. Zaera, A. J. Gellman, and G. A. Somorjai, Surface science studies of catalysis: classification of reactions, Acc. Chem. Res. 19, 24 (1986).
R. M. Crooks, M. Zhao, L. Sun, V. Chechik, and L. K. Yeung, Dendrimer-encapsulated metal nanoparticles: Synthesis, characterization, and applications to catalysis, Acc. Chem. Res. 34, 181 (2001).
M. Zhao, L. Sun, and R. M. Crooks, Preparation of Cu nanoclusters within dendrimer templates, J. Am. Chem. Soc. 120, 4877 (1998).
H. Lang, R. A. May, B. L. Iverson, and B. D. Chandler, Dendrimer-encapsulated nanoparticle precursors to supported platinum catalysts, J. Am. Chem. Soc. 125, 14832 (2003).
A. J. Zarur, and J. Y. Ying, Nature 403, 65 (2000).
A. I. Kozlov, M. C. Kung, W. M. Xue, and H. H. Kung, A “soft-chemical” method to synthesize Lewis acid surfaces of aluminum oxide, Angew. Chem. Int. Ed. 42, 2415 (2003).
W. M. Xue, M. C. Kung, A. I. Kozlov, K. E. Popp, and H. H. Kung, Catalytic aminolysis of epoxide by alumina prepared from amine-protected Al precursor, Catal. Today 85(24), 219 (2003).
M. C. Klunduk, T. Maschmeyer, J. M. Thomas, and B. F. G. Johnson, The influence of steric congestion on the catalytic performance of TiIV active centers in the epoxidation of alkenes, Chem. Eur. J. 5, 1481 (1999).
M. D. Jones, R. Raja, J. M. Thomas, B. F. G. Johnson, D. W. Lewis, J. R. Kenneth, and D. M. Harris, Enhancing the enantioselectivity of novel homogeneous organometallic hydrogenation catalysts, Angew. Chem. Int. Ed. 42, 4326 (2003).
J. S. Beck, J. C. Vartuli, W. J. Roth, M. E. Leonowicz, C. T. Kresge, K. D. Schmitt, C. T. W. Chu, D. H. Olson, E. W. Sheppard, S. B. McCullen, J. B. Higgins, and J. L. Schlenker, A new family of mesoporous molecular sieves prepared with liquid crystal templates, J. Am. Chem. Soc. 114, 10834 (1992).
J. M. Thomas, R. Raja, G. Sankar, and R. G. Bell, Molecular-sieve catalysts for the selective oxidation of linear alkanes by molecular oxygen, Nature 398, 227 (1999); J. M. Thomas, Designing a molecular sieve catalyst for the aerial oxidation of n-hexane to adipic acid, Angew. Chem. Int. Ed. 39, 2313 (2000).
W. M. Xue, M. C. Kung, and H. H. Kung, Rational synthesis of asymmetric bicyclic siloxane, Chem. Commun. 2164 (2005). ([AQ] Author: Please provide volume number in references [13], [14].)
Z. Chang, M. C. Kung, and H. H. Kung, Stepwise synthesis of siloxane chains, Chem. Commun. 206 (2004).
G. Huysmans, A. Ranquin, L. Wyns, J. Steyaert, and P. Van Gelder, Encapsulation of therapeutic nucleoside hydrolase in functionalised nanocapsules, J. Control. Rel. 102, 171 (2005).
S. Okada, S. Peng, W. Spevak, and D. Charych, Color and chromism of polydiacetylene vesicles, Acc. Chem. Res. 31, 229 (1998).
E. T. Kisak, B. Coldren, and J. A. Zasadzinski, Nanocompartments enclosing vesicles, colloids, and macromolecules via interdigitated lipid bilayers, Langmuir 18, 284 (2002).
F. Li, L. Zhang, and R. M. Metzger, On the growth of highly ordered pores in anodized aluminum oxide, Chem. Mater. 10, 2470 (1998).
J. W. Elam, D. Routkevitch, P. P. Mardilovich, and S. M. George, Conformal coating on ultrahigh-aspect-ratio nanopores of anodic alumina by atomic layer deposition, Chem. Mater. 15, 3507 (2003).
M. K. Singh, E. Titus, P. K. Tyagi, U. Palnitkar, D. S. Misra, M. Roy, A. K. Dua, C. S. Cojocaru, and F. Le Normand, Ni and Ni/Pt filling inside multiwalled carbon nanotubes, J. Nanosci. Nanotechnol. 3, 165 (2003).
B. J. Hinds, N. Chopra, T. Rantell, R. Andrews, V. Gavalas, and L. G. Bachas, Aligned multiwalled carbon nanotube membranes, Science 303, 62 (2004).
T. Shimoboji, E. Larenas, T. Fowler, A. S. Hoffman, and P. S. Stayton, Temperature-induced switching of enzyme activity with smart polymer-enzyme conjugates, Bioconjugate Chem. 14 (3), 517 (2003).
H. Dai, Carbon nanotubes: Synthesis, integration, and properties, Acc. Chem. Res. 35, 1035 (2002).
S. M. Bachilo, L. Balzano, J. E. Herrera, F. Pompeo, D. E. Resasco, and R. B. Weisman, Narrow (n, m),-distribution of single-walled carbon nanotubes grown using a solid supported catalyst, J. Am. Chem. Soc. 125, 11186 (2003).
B. Chen, G. Parker II, J. Han, M. Meyyappan, and A. M. Cassell, Heterogeneous single-walled carbon nanotube catalyst discovery and optimization, Chem. Mater. 14, 1891 (2002).
W. F. Paxton, K. C. Kistler, C. C. Olmeda, A. Sen, S. K. St. Angelo, Y. Cao, T. E. Mallouk, P. Lammert, and V. H. Crespi, Catalytic nanomotors: autonomous movement of striped nanorods, J. Am. Chem. Soc. 126, 13424 (2004).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2007 Springer
About this chapter
Cite this chapter
Kung, H.H., Kung, M.C. (2007). Nanotechnology and Heterogeneous Catalysis. In: Zhou, B., Han, S., Raja, R., Somorjai, G.A. (eds) Nanotechnology in Catalysis. Nanostructure Science and Technology. Springer, New York, NY. https://doi.org/10.1007/978-0-387-34688-5_1
Download citation
DOI: https://doi.org/10.1007/978-0-387-34688-5_1
Publisher Name: Springer, New York, NY
Print ISBN: 978-0-387-34687-8
Online ISBN: 978-0-387-34688-5
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)