Decomposition of Yttrium-Doped Barium Cerate in Carbon Dioxide

Besmann, Theodore M.; Carneim, Robert D.; Armstrong, Timothy R.

doi:10.1007/978-0-387-34526-0_5

Theodore M. Besmann²,
Robert D. Carneim³ &
Timothy R. Armstrong³

1556 Accesses

Abstract

Doped barium cerate and related perovskite ceramics currently dominate the high-temperature proton conductor field. Unfortunately, these materials have very stringent environmental limitations necessitating the costly and complex conditioning or cleaning of the application feed-gas. This work shows through both experimental results and thermodynamic modeling that Ba(Ce, Y)O_3–δ is ill-suited for use in environments containing CO₂.

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Authors and Affiliations

Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA
Theodore M. Besmann
Metals and Ceramics Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA
Robert D. Carneim & Timothy R. Armstrong

Authors

Theodore M. Besmann
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Robert D. Carneim
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Timothy R. Armstrong
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Correspondence to Theodore M. Besmann .

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Editors and Affiliations

U.S. Department of Energy, National Energy Technology Laboratory, Pittsburgh, PA, USA
Arun C. Bose

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Besmann, T.M., Carneim, R.D., Armstrong, T.R. (2009). Decomposition of Yttrium-Doped Barium Cerate in Carbon Dioxide. In: Bose, A.C. (eds) Inorganic Membranes for Energy and Environmental Applications. Springer, New York, NY. https://doi.org/10.1007/978-0-387-34526-0_5

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DOI: https://doi.org/10.1007/978-0-387-34526-0_5
Publisher Name: Springer, New York, NY
Print ISBN: 978-0-387-34524-6
Online ISBN: 978-0-387-34526-0
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)

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