Green Engineering-Integration of Green Chemistry, Pollution Prevention, and Risk-Based Considerations

  • David Shonnard
  • Angela Lindner
  • Nhan Nguyen
  • Palghat A. Ramachandran
  • Daniel Fichana
  • Robert Hesketh
  • C. Stewart Slater
  • Richard Engler

Abstract

Literature sources on green chemistry and green engineering are numerous. The objective of this chapter is to familiarize readers with some of the green engineering and chemistry concepts, approaches and tools. In order to do this, the chapter is organized into five sections as follows.

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References

  1. 1.
    EPA Green Engineering Web site, www.epa.gov/oppt/greenengineering.Google Scholar
  2. 2.
    EPA Green Chemistry Web site, 12 Principles of Green Chemistry, www.epa.gov/oppt/greenchemistry/princi-ples.html.Google Scholar
  3. 3.
    Anastas, P.T., and Warner, J.C., Green Chemistry: Theory and Practice, Oxford University Press, New York, 1998.Google Scholar
  4. 4.
    Malone, M. F. and Huss. R.S., “Green Chemical Engineering Aspects of Reactive Distillation,” Environ. Sci. Technol. 37, 23, 5325–5329, 2003.CrossRefGoogle Scholar
  5. 5.
    Allen, D. T., and Shonnard, D.R., Green Engineering: Environmentally Conscious Design of Chemical Processes (3rd ed.), Prentice-Hall, NJ, 2004.Google Scholar
  6. 6.
    Douglas. J. M., Conceptual Design of Chemical Processes, McGraw-Hill, New York, 1988.Google Scholar
  7. 7.
    Rossiter, A. P. and Klee. H., Hierarchical Review for Waste Minimization, A. P. Rossetier ed., McGraw-Hill, New York, 1995.Google Scholar
  8. 8.
    Schultz, M. A., Stewart, D.G., Harris, J. M. Rosenblum, S. P., Shakur, M.S., and O’Brien, D. E., Reduce costs with dividing-wall columns, CEP, May pp 64–71, 2002.Google Scholar
  9. 9.
    El-Halwagi, M. M., Pollution Prevention Through Process Integration, Academic Press, San Diego, CA, 1997.Google Scholar
  10. 10.
    Liu, Y. A., Lucas, B., and Mann, J. M., “Up-to-date tools for water system optimization,” Chem. Eng, 111(1), 30–41, 2004.Google Scholar
  11. 11.
    Allen, D. T. and Rosselot, K. S., Pollution Prevention for Chemical Processes, John Wiley and Sons, New York, 1997.Google Scholar
  12. 12.
    Tunca, C., P. A. Ramachandran, and M. P. Dudukovic, Role of chemical reaction engineering in sustainable development, Paper presented at AIChE session 7d, Austin, Texas, November 10, 2004.Google Scholar
  13. 13.
    Mulholland, K.L. and Dyer, J.A., Pollution Prevention: Methodology, Technologies, and Practices, American Institute of Chemical Engineers, New York, p. 214, 1999.Google Scholar
  14. 14.
    Ney, Ronald E. Jr., Where Did That Chemical Gol Van Nostrand Reinhold, New York, 1990.Google Scholar
  15. 15.
    Mackay, D., Patterson, S., diGuardo, A, and Cowan, CE. “Evaluating the environmental fate of a variety of types of chemicals using the EQC Model. Environ. Toxicol. Chem., 15, 1627–1637, 1996.CrossRefGoogle Scholar
  16. 16.
    Andren, A.W., Mackay, D., Depinto, J. V., Fox, K., Thibodeaux, L.J., McLachlan, M., and Haderlein, S. Intermedia partitioning and transport. In: Klečka, G., Boethling, B., Franklin, J., Grady, L., Graham, D., Howard, P.H., Kannan, K., Larson, B., Mackay, D., Muir, D., and van de Meent, D., editors, Evaluation of Persistence and Long-Range Transport of Organic Chemicals in the Environment. SETAC Press, Pensacola, FL, pp. 131–168, 2000.Google Scholar
  17. 17.
    Franklin, J., Atkinson, R., Howard, PH., Orlando, J. J., Seigneur, C., Wallington, T.J., and Zetzsch, C. Quantitative determination of persistence in air. In: Klečka G, Boethling, B., Franklin, J., Grady, L., Graham, D., Howard, PH., Kannan, K., Larson, B., Mackay, D., Muir, D., and van de Meent, D., editors, Evaluation of Persistence and Long-Range Transport of Organic Chemicals in the Environment. SETAC Press, Pensacola, FL, pp. 7–62, 2000.Google Scholar
  18. 18.
    Thibodeaux, L.J. Environmental Chemodynamics: Movement of Chemicals in Air, Water, and Soil, 2nd edition. John Wiley & Sons, New York, 1996.Google Scholar
  19. 19.
    Clark, M.M. Modeling for Environmental Engineers and Scientists. John Wiley & Sons, New York, 1997.Google Scholar
  20. 20.
    Schnoor, J.L. Environmental Modeling. John Wiley & Sons, New York, 1997.Google Scholar
  21. 21.
    Bishop, PL. Pollution Prevention: Fundamentals and Practice. Waveland Press, Long Grove, IL, 2004.Google Scholar
  22. 22.
    Thomas, R.G. Volatilization from water. In: Lyman, WJ, Reehl, WF, and Rosenblatt, D.H., editors. Handbook of Chemical Property Estimation Methods. American Chemical Society, Washington, DC, pp. 15-1–15-34, 1990.Google Scholar
  23. 23.
    Larson, R. A. and Weber, E. J. Reaction Mechanisms in Environmental Organic Chemistry. Lewis Publishers, Boca Raton, FL, 1994.Google Scholar
  24. 24.
    Lerman, A. Time to chemical steady states in lakes and oceans. In: Hem, J.D., editor. Nonequilibrium Systems in Natural Water Chemistry. Advan. Chem. Ser. #106, American Chemical Society, Washington, DC, pp. 30–76, 1971.CrossRefGoogle Scholar
  25. 25.
    Thibodeaux, L.J, Valsaraj, K.T., and Reible, D.D., “Associations of polychlorinated biphenyls with particles in natural waters.” Water Sci. Technol. 28(8):215–221, 1993.Google Scholar
  26. 26.
    Baum, E. J. Chemical Property Estimation: Theory and Application. Lewis Publishers, Boca Raton, FL, 1998.Google Scholar
  27. 27.
    McCutcheon, S.C., and Schnoor, J.L., Overview of phytotransformation and control of wastes. In: McCutcheon, S.C., and Schnoor, J.L., Phytoremediation: Transformation and Control of Contaminants. John Wiley & Sons, New York, pp. 3–58, 2003.Google Scholar
  28. 28.
    Larson, R., Forney, L., Grady Jr., L., Klečka, G. M., Masunanga, S., Peijnenburg, W., and Wolfe L. Quantification of Persistence in Soil, Water, and Sediments. In: Klečka, G, Boethling, B, Franklin, J, Grady, L., Graham, D, Howard, P.H., Kannan, K, Larson, B, Mackay, D, Muir, D, and van de Meent, D., editors, Evaluation of Persistence and Long-Range Transport of Organic Chemicals in the Environment. SETAC Press, Pensacola, FL, pp. 63–130, 2000.Google Scholar
  29. 29.
    Gibson D.T. and Subramanian, V, Microbial degradation of aromatic compounds. In: Gibson, D.T., editor Microbial Degradation of Organic Compounds. Marcel Dekker, New York, 1984.Google Scholar
  30. 30.
    Bedard D.L., and Quensen, J.F., III. Microbial reductive dechlorination of polychlorianted biphenyls. In: Young, L.Y, and Cerniglia, C.E., editors, Microbial Transformation and Degradation of Toxic Organic Chemicals, John Wiley & Sons, Inc., New York, 1995.Google Scholar
  31. 31.
    Fish K.M., and Principe, J.M., Biotransformations of Arochlor 1242 in Hudson River Test Tube Microcosms, Appl Environ. Microbiol, 60(12), 4289–4296, 1994.Google Scholar
  32. 32.
    Ye, D., Quensen III, J.F., Tiedje, J.M, and Boyd, S.A., Evidence for para-dechlorination of polychlorobiphenyls by methanogenic bacteria. Appl. Environ. Microbiol. 61:2166–2171, 1995.Google Scholar
  33. 33.
    Chakrabarty, A.M., Biodegradation and Detoxification of Environmental Pollutants. CRC Press, Boca Raton, FL, 1982.Google Scholar
  34. 34.
    Alexander, M., Biodegradation and Bioremediation. Academic Press, San Diego, 1994.Google Scholar
  35. 35.
    Young, L.Y., and Cerniglia, C.E., Microbial Transformation and Degradation of Toxic Organic Chemicals, Wiley-Liss, New York, 1995.Google Scholar
  36. 36.
    Burken, J.G., Uptake and metabolism of organic compounds: Green liver model. In: McCutcheon, S.C. and Schnoor, J.L., editors. Phytoremediation: Transformation and Control of Contaminants, John Wiley & Sons, New York, pp. 59–84, 2004.Google Scholar
  37. 37.
    Jeffers, P.M., and Wolfe, N.L., Degradation of methyl bromide by green plants. In: Seiber, J.N., editor. Fumigants: Environmental Fate, Exposure and Analysis. American Chemical Society, Washington, DC, 1997.Google Scholar
  38. 38.
    O’Neill, W., Nzengung, V., Noakes, J., Bender, J., and Phillips, P., Biodegradation of tetrachloroehtylene and trichloroethylene using mixed-species microbial mats. In: Wickramanayake, G.B., and Hinchee, R.E., editors. Bioremediation and Phytoremediation, Batelle, Columbus, WA, pp. 233–237, 1998.Google Scholar
  39. 39.
    Hughes, J.B., Shanks, J., Vanderford, M., Lauritzen, J., and Bhadra, R., “Transformation of TNT by aquatic plants and plant tissue cultures.” Environ. Sci. Technol. 31:266–271, 1997.CrossRefGoogle Scholar
  40. 40.
    Vanderford, M., Shanks, J.V, Hughes, J.B., “Phytotransformation of trinitrotoluene (TNT) and distribution of metabolic products in myriphyllum aquaticum.” Biotechnol Lett. 199:277–280, 1997.CrossRefGoogle Scholar
  41. 41.
    Gao, J., Garrison, A.W., Hoehamer, C., Mazur, C., and Wolfe, N.L., Phytotransformations of organophosphate pesticides using axenic plant tissue cultures and tissue enzyme extract. In situ and on-site bioremediation. The Fifth International Symposium, San Diego, 19–22 April 1999.Google Scholar
  42. 42.
    Cunningham, S.D., and Berti, W.R., “The remediation of contaminated soils with green plants: An overview”. In vitro Cell Dev. Biol. Plant 29:207–212, 1993.CrossRefGoogle Scholar
  43. 43.
    Banks, M.K., Schwab, A.P, Govindaraju, R.S., and Kulakow P. Phytoremediation of hydrocarbon contaminated soils. In: Fiorenza, S, Oubre, L.C., and Ward, C.H., editors. Phytoremediation, CRC Press, New York, 1999.Google Scholar
  44. 44.
    Schwartzenbach, R.P, Gschwend, P. M., and Imboden, D.M. Environmental Organic Chemistry. 1st edition. John Wiley & Sons, New York, 1993.Google Scholar
  45. 45.
    Wolfe, N.L., and Jeffers, P.M., Hydrolysis. In: Boethling. R.S., and Mackay, D., editors. Handbooks of Property Estimation Methods for Chemicals: Environmental and Health Science. CRC Press, Boca Raton, FL, pp. 311–334, 2000.Google Scholar
  46. 46.
    Zepp, R.G., Experimental approaches to environmental photochemistry. In: Hutzinger, O., editor. The Handbook of Environmental Chemistry, Vol. 2, Part B. Springer-Verlag, Berlin, Germany, pp. 19–41, 1982.Google Scholar
  47. 47.
    Alebić-Juretić, A., Güsten, H., and Zetzsch, C., “Absorption spectra of hexachlorobenzene adsorbed on SiO2 powders.” Fresenius J. Anal Chem., 340:380–383, 1991.CrossRefGoogle Scholar
  48. 48.
    Bermen, J.M., Graham, J.L., and Dellinger, B., “High temperature UV absorption characteristics of three environmentally sensitive compounds.” J. Photochem. Photobiol A: Chem, 68:353–362, 1992.CrossRefGoogle Scholar
  49. 49.
    Tysklind, M., Lundgren, K., and Rappe, C., “Ultraviolet absorption characteristics of all tetra-to octachlorinated dibenzoftirans,” Chemosphere, 27:535–546, 1993.CrossRefGoogle Scholar
  50. 50.
    Kwok, E.S.C., Arey, J., and Atkinson, R., “Gas-phase atmospheric chemistry of dibenzo-p-dioxin and dibenzofuran, Environ. Sci. Technol., 28:528–533, 1994.CrossRefGoogle Scholar
  51. 51.
    Funk, D.J., Oldenborg, R.C., Dayton, D.P., Lacosse, J.R, Draves, J.A., and Logan, T.J., “Gas-phase absorption and later-induced fluorescence measurements of representative polychlorinated dibenzo-p-dioxins, polychlorinated dibenzoftirans, and a polycyclic aromatic hydrocbon,” Appl. Spectros., 49:105–114, 1995.CrossRefGoogle Scholar
  52. 52.
    Konstantinou, I.K., Zarkdis, A.K., and Albanis, T.A., “Photodegradation of selected herbicides in various natural waters and soils under environmental conditions, J. Environ. Qual. 30:121–130, 2001.CrossRefGoogle Scholar
  53. 53.
    Allen, D.T., and Shonnard, D.R. Green Engineering: Environmental Conscious Design of Chemical Processes, Prentice Hall, Upper Saddle River, NJ, 2002.Google Scholar
  54. 54.
    Windholz, M., Budavara, S., Blumetti, R.F., and Otterbein, E.S., The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologicals. 6th Edition. Merck & Co., Rahway, NJ, 1983.Google Scholar
  55. 55.
    Howard, PH., Boethling, R.S., Jarvis, W.R., Meylan, W.M., and Michalenko, E.M., Handbooks of Environmental Degradation Rates. Lewis Publishers, Chelsea, MI, 1991.Google Scholar
  56. 56.
    Dean, J.A., Lange’s Handbook of Chemistry. 14th Edition. McGraw-Hill, New York, 1992.Google Scholar
  57. 57.
    Lide, D.R., CRC Handbook of Chemistry and Physics. 74th Edition. CRC Press, Boca Raton, FL, 1994.Google Scholar
  58. 58.
    Mackay, D., Shiu, W.Y., and Ma, K.C., Illustrated Handbook of Physical Chemical Properties and Environmental Fate of Organic Chemicals, vols. 1–5, Lewis Publishers, Boca Raton, FL, 1992–1997.Google Scholar
  59. 59.
    Howard, P.H., and Meylan, W.M., Handbook of Physical Properties of Organic Chemicals, CRC Press, Boca Raton, FL, 1997.Google Scholar
  60. 60.
    Tomlin, C.D.S., editor, The Pesticide Manual. 11th Edition, British Crop Protection Council, Farnham, Surrey, UK, 1997.Google Scholar
  61. 61.
    Yaws, C.L., Chemical Properties Handbook, McGraw-Hill, New York, 1999.Google Scholar
  62. 62.
    Verschueren, K., Handbook of Environmental Data on Organic Chemicals. 3rd and 4th editions. Van Nostrand-Reinhold, New York, 1996, 2001.Google Scholar
  63. 63.
    Lyman, W.J., Reehl, W.F., and Rosenblatt, D.H., Handbook of Chemical Property Estimation Methods: Environmental Behavior of Organic Compounds. McGraw-Hill, New York, 1982.Google Scholar
  64. 64.
    Neely, W.B., and Blau, G.E., Environmental Exposure from Chemicals, Vols. I and II. CRC Press, Boca Raton, FL, 1985.Google Scholar
  65. 65.
    Bare, J.C., Norris, G.A., Pennington, D.W., and McKone, T., “TRACI: The tool for the reduction and assessment of chemical and other impacts,” J. Indust. Ecol., 6(3–4), 49–78, 2003.Google Scholar
  66. 66.
    Goedkoop, M., “The Eco-indicator 95, Final Report”, Netherlands Agency for Energy and the Environment(NOVEM) and the National Institute of Public Health and Environmental Protection (RIVM), NOH report 9523, 1995.Google Scholar
  67. 67.
    Heijungs, R., Guinée, J.B., Huppes, G., Lankreijer, R.M., Udo de Haes, H.A., and Wegener Sleeswijk, “Environmental life cycle assessment of products. Guide and backgrounds”, NOH Report Numbers 9266 and 9267, Netherlands Agency for Energy and the Environment (Nov.), 1992.Google Scholar
  68. 68.
    ISO 14040–14049, 1997–2002, Environmental Management — Life Cycle Assessment, International Organization for Standardization, Geneva, Switzerland.Google Scholar
  69. 69.
    SETAC, Society for Environmental Toxicology and Chemistry, “Guidelines for Life-Cycle Assessment: Code of Practice”, Brussels, Belgium, 1993.Google Scholar
  70. 70.
    Douglas, J.M., 1992, Ind. Eng. Chem. Res., 41(25), 2522.Google Scholar
  71. 71.
    PARIS II, 2005, http://www.tds-tds.com/Google Scholar
  72. 72.
    Chen, H. and Shonnard, D.R. “A systematic framework for environmental-conscious chemical process design: Early and detailed design stages, Indust. Eng. Chem. Res., 43(2), 535–552, 2004.CrossRefGoogle Scholar
  73. 73.
    Allen, D.T. and Shonnard, D.R., Green engineering: Environmentally conscious design of chemical processes and products, AIChE J., 47(9), 1906–1910, 2001.CrossRefGoogle Scholar
  74. 74.
    NRC (National Research Council), 1983, Risk Assessment in the Federal Government: Managing the Process, Committee on Institutional Means for Assessment of Risks to Public Health, National Academy Press, Washington, DC.Google Scholar
  75. 75.
    Air CHIEF, accessed 2005, The Air ClearingHouse for Inventories and Emission Factors, CD-ROM, http://www.epa.gov/oppt/greenengineering/sofrware.html.Google Scholar
  76. 76.
    Mackay, D., Shiu, W., and Ma, K., Illustrated Hand book of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, 1st Edition, Vol. 1–4, Lewis ublishers, Chelsea, MI, 1992.Google Scholar
  77. 77.
    Shonnard, D.R. and Hiew, D.S., 2000, “Comparative environmental assessments of VOC recovery and recycle design alternatives for a gaseous waste stream,” Environ. Sci. Technol., 34(24), 5222–5228.CrossRefGoogle Scholar
  78. 78.
    WAR (WAste Reduction Algorithm), http://www.epa.gov/oppt/greenengineering/software.htmlGoogle Scholar
  79. 79.
    SACHE, accessed 2005, Safety and Chemical Engineering Education, American Institute of Chemical Engineers, http://www.sache.orgGoogle Scholar
  80. 80.
    Shonnard, D.R., Tools and Materials for Green Engineering and Green Chemistry Education, Green Chemistry and Engineering Education — a Workshop Organized by the Chemical Sciences Roundtable of the National Research Council, 7–8 November 2005.Google Scholar
  81. 81.
    Genco, J.M., Pulp. In Kirk-Othmer Encyclopedia of Chemical Technology, Vol. 20, J.I. Kroschwitz, Ed. John Wiley and Sons, New York, p. 493, 1991.Google Scholar
  82. 82.
    Collins, T.J., Horwitz, C., and Gordon-Wylie, S.W. Project Title: TAML™ Activators: General activation of hydrogen peroxide for green oxidation processes, provided by Mary Kirchhoff, Green Chemistry Institute, American Chemical Society, 1999.Google Scholar
  83. 83.
    Miller, K., Comments at the panel discussion in the session “Building the Business Case for Sustainability, AIChE Spring Meeting, Atlanta, 12 April, 2005.Google Scholar
  84. 84.
    Schrott, W. and Saling, P., “Eco-efficiency analysis—Testing products for their value to the customer. Melliand Textilberichte 81(3), 190, 192–194, 2000.Google Scholar
  85. 85.
    Landsiedel, R. and Saling, P. “Assessment of toxicological risks for life cycle assessment and eco-efficiency analysis.” Int. J. Life Cycle Assess. 7(5), 261–268, 2002.CrossRefGoogle Scholar
  86. 86.
    Azapagic, A., “Life cycle assessment and its application to process selection, design, and optimization,” Chem. Eng. J., 73,1 (April), 1–21, 1999.CrossRefGoogle Scholar
  87. 87.
    Burgess, A.A. and Brennan, D.J. “Application of life cycle assessment to chemical processes,” Chem. Eng. Sci. 56,8 (April) 2589, 2609, 2001.CrossRefGoogle Scholar
  88. 88.
    Royal Commission on Environmental Pollution, “Best practicable environmental option” Twelfth Report, Cm130, London, England, United Kingdom, 1988.Google Scholar
  89. 89.
    Beaver, E. R., Calculating metrics for acetic acid production, AIChE Sustainability Engineering Conference Proceedings, Austin, TX, November 2004, pp. 7–15.Google Scholar
  90. 90.
    International Organization of Standardization (ISO) 1997. Environmental management — Life cycle assessment — Principles and framework. International Organization of Standardization, Geneva, Switzerland (International Standard ISO 14040:1997(E)).Google Scholar
  91. 91.
    International Organization of Standardization (ISO) 1998. Environmental management — Life cycle assessment — Goal and scope definition and inventory analysis. International Organization of Standardization, Geneva, Switzerland (International Standard ISO14041:1998(E)).Google Scholar
  92. 92.
    International Organization of Standardization (ISO). 2000. Environmental management — Life cycle assessment — Life cycle impact assessment. International Organization of Standardization, Geneva, Switzerland (International Standard ISO14042:2000(E)).Google Scholar
  93. 93.
    International Organization of Standardization (ISO). 2000. Environmental management — Life cycle assessment — Life cycle interpretation. International Organization of Standardization, Geneva, Switzerland (International Standard ISO14043:2000(E)).Google Scholar
  94. 94.
    Ukidwe, N. W. and Bakshi, B. R. Economic versus natural capital flows in industrial supply networks-Implications to sustainability, AIChE Sustainability Engineering Conference Proceedings, Austin, TX, November 2004, pp. 145–153.Google Scholar
  95. 95.
    Graedel, T.E., Streamlined Life-Cycle Assessment, Prentice Hall, Englewood Cliffs, NJ, 1998.Google Scholar
  96. 96.
    Curran, M., ed. Environmental Life-Cycle Assessment, McGraw Hill, New York, 1997.Google Scholar
  97. 97.
    Azapagic, A., Perdan, S., and Clift, R., Sustainable Development in Practice: Case Studies for Engineers and Scientists, John Wiley and Sons Ltd, New York, 2004.Google Scholar
  98. 98.
    Chevalier, J., Rousseaux, P., Benoit, V., and Benadda, B., “Environmental assessment of flue gas cleaning processes of municipal solid waste incinerators by means of the life cycle assessment approach,” Chem. Eng. Sci, 58,10 (May) 2053–2064, 2003.CrossRefGoogle Scholar
  99. 99.
    Ekvall, T. and Finnveden, G. “Allocation in ISO 14041 — A critical review,” J. Cleaner Prod. 9,3 (June) 197–208, 2001.CrossRefGoogle Scholar
  100. 100.
    Bakshi, B. R. and Hau, J.L., A multiscale and multiobjective approach for environmentally conscious process retrofitting, AIChE Sustainability Engineering Conference Proceedings, Austin, TX, November, pp. 229–235, 2004.Google Scholar
  101. 101.
    Ukidwe, N. W. and Bakshi, B.R., A multiscale Bayesian framework for designing efficient and sustainable industrial systems, AIChE Sustainability Engineering Conference Proceedings, Austin, TX, November, pp. 179–187, 2004.Google Scholar
  102. 102.
    Suh, S., Lenzen, M., Treloar, G. J., Hondom, H., Harvath, A., Huppes, G., Jolliet, O., Klann, U., Krewitt, W., Morguchi, Y., Munksgaard, J., and Norris, G., “System boundary selection in life-cycle inventories using hybrid approaches,” Environ. Sci. Technol., 38,3, 657–663, 2004.CrossRefGoogle Scholar
  103. 103.
    Lei, L., Zhifeng, L., and Fung, R., “The Most of the Most”-Study of a New LCA Method, IEEE Proceedings, pp. 177–182, 2003.Google Scholar
  104. 104.
    Bakshi, B.R. and Hau, J. L., Using exergy analysis for improving life cycle inventory databases, AIChE Sustainability Engineering Conference Proceedings, Austin, TX, November pp. 131–134, 2004.Google Scholar
  105. 105.
    Cornelissen, R.L. and Hirs, G.G., “The value of the exergetic life cycle assessment besides the LCA,” Energy Conversion Manage., 43, 1417–1424, 2002.CrossRefGoogle Scholar
  106. 106.
    Becalli, G., Cellura, M., and Mistretta, M., “New exergy criterion in the “multi-criteria” context: a life cycle assessment of two plaster products,” Energy Conserv. Manage. 44, 2831–2838, 2003.Google Scholar
  107. 107.
    Jimenez-Gonzalez, C., Overcash, M.R., and Curzons, A., “Waste treatment modules-a partial life cycle inventory,” J. Chem. Technol Biotechnol. 76, 707–716, 2001.CrossRefGoogle Scholar
  108. 108.
    Jimenez-Gonzalez, C., Kim, S., and Overcash, M. R., “Methodology for developing gate-to-gate life cycle inventory information,” Int. J. Life Cycle Assess., 5, 153–159, 2000.CrossRefGoogle Scholar
  109. 109.
    Xun & High 2004.Google Scholar
  110. 110.
    Shonnard, D. R., Kichere, A., and Saling, P., “industrial applications using BASF eco-efficiency analysis: Perspectives on green engineering principles,” Environ. Sci. Technol., 37, 5340–5348, 2003.CrossRefGoogle Scholar
  111. 111.
    Mueller, J., Griese, H., Schischke, K., Stobbe, I., Norris, G.A., and Udo de Haes, H.A., Life cycle thinking for green electronics: Basics in ecodesign and the UNEP/SETAC life cycle initiative, International IEEE Conference on Asian Green Electronics, pp. 193–199, 2004.Google Scholar
  112. 112.
    Widiyanto, A., Kato, S., Maruyama, N., and Kojima, Y., “Environmental impact of fossil fuel fired co-generation plants using a numerically standardized LCA scheme,” J. Energy Resource Technol., 125, 9–16, 2003.CrossRefGoogle Scholar
  113. 113.
    Goralczyk, M., “Life-cycle assessment in the renewable energy sector,” Appl. Energy, 75, pages 205–211, 2003.CrossRefGoogle Scholar
  114. 114.
    Schleisner, L., “Life cycle assessment of a wind farm and related externalities,” Renewable Energy, 20, 279–288, 2000.CrossRefGoogle Scholar
  115. 115.
    Koroneos, C., Dompros, A., Roumbas, G., and Moussiopoulos, N., Life cycle assessment of hydrogen fuel production processes,” Int. J. Hydrogen Energy, 29, 1443–1450, 2004.CrossRefGoogle Scholar
  116. 116.
    Furuholt, E., “Life cycle assessment of gasoline and diesel,” Resources, Conserv. Recycl., 14, 251–263, 1995.CrossRefGoogle Scholar
  117. 117.
    MacLean, H. L. and Lave, L. B., “Life cycle assessment of automobile/fuel options,” Environ. Sci. Technol. 37, 5445–5452, 2003.CrossRefGoogle Scholar
  118. 118.
    Amatayakul, W. and Ramnas, O., “Life cycle assessment of a catalytic converter for passenger cars,” J. Cleaner Prod., 9, 395–403, 2001.CrossRefGoogle Scholar
  119. 119.
    Baratto, F. and Diwekar, U.M. “Life cycle of fuel cell-based APUs,” J. Power Sources, 139, pages 188–196,2005.CrossRefGoogle Scholar
  120. 120.
    Eagan, P. and Weinberg, L., “Application of analytic hierarchy process techniques to streamlined life-cycle analysis of two anodizing processes,” Environ. Sci. Technol., 33, 1495–1500, 1999.CrossRefGoogle Scholar
  121. 121.
    Tan, R., Khoo, B.H., and Hsien, H., “An LCA study of a primary aluminum supply chain,” J. Cleaner Prod. 13,6 (May) 607–618, 2005.CrossRefGoogle Scholar
  122. 122.
    Jodicke, G. Zenklusen, O., Weidenhaupt, A., and Hungerbuhler, K., “Developing environmentally sound processes in the chemical industry: A case study on pharmaceutical intermediates,” J. Cleaner Prod. 7,2 (March) 159–166, 1999.CrossRefGoogle Scholar
  123. 123.
    Jimenez-Gonzalez, C., Curzons, A.D., Constable, D.J.C., and Cunningham, V.L., “Cradle-to-gate life cycle inventory and assessment of pharmaceutical compounds,” Int Life Cycle Assess., 9, 114–121, 2004.CrossRefGoogle Scholar
  124. 124.
    Jimenez-Gonzalez, C. and Overcash, M. R., “Energy optimization during early drug development and the relationship with environmental burdens,” J. Chem. Technol. Biotechnol. 75, 983–990, 2000.CrossRefGoogle Scholar
  125. 125.
    Wall-Markowski, C. A, Kicherer, A., and Saling, P., “Using eco-efficiency analysis to assess renewable-resource-based technologies,” Environ. Progress 23(4), 329–333, 2004.CrossRefGoogle Scholar
  126. 126.
    Raluy, R.G., Serra, L., Uche, J., and Valero, A., “Life-cycle of desalination technologies integrated with energy production systems,” Desalination, 167, 445–458, 2004.CrossRefGoogle Scholar
  127. 127.
    Pre Consultants, Amersfoot, The Netherlands.Google Scholar
  128. 128.
    Papasavva, Kia, S., Claya, J., and Gunther, R., “Characterization of automotive paints: An environmental impact analysis,” Progress Organic Coatings, 43, 193–206, 2001.CrossRefGoogle Scholar
  129. 129.
    Dobson, I. D., “Life cycle assessment for painting processes, putting the VOC issue in perspective,” Progress Organic Coatings, 27, pages 55–58, 2001.CrossRefGoogle Scholar
  130. 130.
    Lopes, E., Dias, A., Arroja, L., Capela, I., and Pereira, F., “Application of life cycle assessment to the Portuguese pulp and paper industry,” J. Cleaner Prod., 11, 51–59, 2003.CrossRefGoogle Scholar
  131. 131.
    Rios, P., Stuart, J.A., and Grant, E., “Plastics disassembly versus bulk recycling: Engineering design for end-of-life electronics resource recovery” Environ. Sci. Technol. 37, 5463–5470, 2003.CrossRefGoogle Scholar
  132. 132.
    Song, H.-S. and Hyun, J.C., “A study on the comparison of the various waste management scenarios for Pet bottles using life-cycle assessment (LCA) methodology,” Resources, Conserv. Recycl. 27, 267–284, 1999.CrossRefGoogle Scholar
  133. 133.
    Ekvall, T., “Key methodological issues for life cycle inventory analysis of paper recycling,” J. Cleaner Prod., 7, 281–294, 1999.CrossRefGoogle Scholar
  134. 134.
    Shiojiri, K., Yanagisawa, Y, Fujii, M., Kiyono, F., and Yamasaki, A., A life cycle impact assessment study on sulfur hexaflouride as a gas insulator, AIChE Sustainability Engineering Conference Proceedings, Austin, TX, November, 135–143, 2004.Google Scholar
  135. 135.
    Cederberg, C. and Mattson, B., “Life cycle assessment of milk production — A comparison of conventional and organic farming,” J. Cleaner Prod., 8, 49–60, 2000.CrossRefGoogle Scholar
  136. 136.
    Zabaniotou, A. and Kassidi, E., “Life cycle assessment applied to egg packaging made from polystyrene and recycled paper,” J. Cleaner Prod. 11, 549–559, 2003.CrossRefGoogle Scholar
  137. 137.
    Bohlmann, G.M., “Biodegradable packaging life-cycle assessment,” Enviro Progress, 23,4, 342–346.Google Scholar
  138. 138.
    Anderson, K, Ohlsson, T., and Olsson, P., “Screening life cycle assessment of tomato ketchup: A case study,” J. Cleaner Prod. 6, 277–288, 1998.CrossRefGoogle Scholar

Additional Suggested Reading Introduction to Green Chemistry and Green Engineering

  1. Allen, D. and Rosselot, K. Pollution Prevention for Chemical Processes, John Wiley and Sons, New York, 1997.Google Scholar
  2. Allen, D.T and Shonnard, D.R. “Green Engineering: Environmentally Conscious Design of Chemical Processes and Products,” AIChE J. 47(9), 1906–1910, 2001.CrossRefGoogle Scholar
  3. Anastas, P.A. and Zimmerman, J.B. “Design through the twelve principles of green engineering,” Environ. Sci. and Technol. 37(5) (March), 94A–101A, 2003.CrossRefGoogle Scholar
  4. Boethling, R. and Mackay, D. Handbook of Property Estimation Methods for Chemicals. Lewis Publishers, Roca Raton, FL, 2000.CrossRefGoogle Scholar
  5. Byrd, D. and Cothern, R. Introduction to Risk Analysis. Government Institutes, 2000.Google Scholar
  6. Daugherty, J. Assessment of Chemical Exposures. Lewis Publishers, Roca Ratan, FL, 1998.Google Scholar
  7. El-Halwagi, M. Pollution Prevention through Process Integration. Academic Press, San Aeogo, CA, 1997.Google Scholar
  8. EPA Exposure Assessment Web site. www.epa.gov/oppt/exposure.Google Scholar
  9. EPA Pollution Prevention Framework Web site. www.epa.gov/oppt/p2framework/.Google Scholar
  10. Hesketh, R.P., Slater, C.S., Savelski, M.J., Hollar, K., and Farrell, S. “A program to help in designing courses to integrate green engineering subjects,” Intl. J. Eng. Educ. 20(1) 113–128, 2004.Google Scholar
  11. Graedel, T.E. and Allenby, B. R. Industrial Ecology, Prentice Hall, Englewood Cliffs, NJ, 1995.Google Scholar
  12. Martin, A. and Nguyen, N. “Green engineering: Definiting the principles — results from the Sandestin Conference.” Environ. Progress. (December), 233–236, 2003.Google Scholar
  13. Ritter, S. “A green agenda for engineering.” Chem. Eng. News, 81,29 July 21, 30–32, 2003.Google Scholar
  14. Shonnard, D.R., Allen, D.T., Nguyen, N., Austin, S.W., and Hesketh, R., “Green engineering education through a US EPA/academia collaboration,” Environ. Sci. and Technol. 37(23) 5453–5462, 2003.CrossRefGoogle Scholar
  15. Slater, C. S. and R.P. Hesketh, “Incorporating green engineering into a material and energy balance course,” Chem. Eng. Educ. 38(1), 48–53, 2004.Google Scholar
  16. Socolow, R., Andrews, F, Berkhout, F, and Thomas, V. Industrial Ecology and Global Change. Cambridge University Press, New York, 1994.Google Scholar

2.2 Pollution Prevention Heuristics for Chemical Processes

  1. EPA Green Chemistry Web site, Green chemistry expert system: Analysis of existing processes, building new green processes, and design, (www.epa.gov/greenchemistry/tools.htm).Google Scholar
  2. Freeman, H., ed., Industrial Pollution Prevention Handbook, McGraw Hill, New York, April 1994.Google Scholar
  3. Allen, D. T. and Shonnard, D. R., Green Engineering: Environmentally Conscious Design of Chemical Processes, “Prentice-Hall, Upper Saddle River, NJ, 2002.Google Scholar
  4. Dyer, J. A. and Mulholland, K. L., “Prevent pollution via better Reactor design and operation,” CEP (Feb), 1998.Google Scholar
  5. Wynn, C. “Pervaporation comes of age,” CEP (October), 66–72, 2001.Google Scholar

2.3 Understanding and Prediction of the Environmental Fate of Chemicals

  1. Crosby, D.G. and Wong, A.S., “Environmental degradation of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD).” Science, 195:1337–1338, 1977.CrossRefGoogle Scholar
  2. Hansch, C., and Leo, A. Exploring QSAR: Fundamental and Applications in Chemistry and Biology, American Chemical Society, Washington, DC, 1995.Google Scholar
  3. Jeffers, P.M. and Wolfe, NL. “Green plants: A terrestrial sink for atmospheric methyl bromide.” Geophy. Res. Lett. 25:43–46, 1998.CrossRefGoogle Scholar
  4. Mackay, D., Multimedia Environmental Models: The Fugacity Approach. Lewis Publishers, Boca Raton, FL, 1991.Google Scholar
  5. Meylen, W.M., and Howard, P.H., “Atom/fragment contribution method for estimating ocatnol-water partition coefficients.” J. Pharm. Sci., 84:83–92, 1995.CrossRefGoogle Scholar
  6. Syracuse Research Corporation [SRC]. Syracuse, NY. Internet address: http://www.syrres.com, 2005.Google Scholar

2.4 Environmental Performance Assessment for Chemical Process Design

  1. Cano-Ruiz, J.A. and McRae, G.J., “Environmentally conscious chemical process design.” Ann. Rev. Ener. Environ., 23, 499, 1998.CrossRefGoogle Scholar

2.4 Life-Cycle Assessment

  1. Carnegie Mellon University, http://www.eiolca.net/index.html, developed by Green Design Initiative, Carnegie Mellon University, last logon March 21, 2005Google Scholar
  2. Bauman, H. and A-M. Tillman, The Hitch Hiker’s Guide to LCA: An Orientation in Life Cycle Assessment Methodology and Applications. Studentlitteratur AB, 2004.Google Scholar
  3. Graedel, T. E., Streamlined Life-Cycle Assessment, Prentice Hall; 1998.Google Scholar

Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  • David Shonnard
    • 1
  • Angela Lindner
    • 2
  • Nhan Nguyen
    • 3
  • Palghat A. Ramachandran
    • 4
  • Daniel Fichana
    • 5
  • Robert Hesketh
    • 5
  • C. Stewart Slater
    • 5
  • Richard Engler
    • 3
  1. 1.Department of Chemical EngineeringMichigan Technological UniversityUSA
  2. 2.Department of Environmental Engineering SciencesUniversity of Florida at GainesvilleUSA
  3. 3.US EPAUSA
  4. 4.Department of Chemical EngineeringWashington University of St. Louis
  5. 5.Department of Chemical EngineeringRowan UniversityUSA

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