Abstract
The precipitation of an insulating layer of scaling on the walls of the water distribution pipes has serious technical and economic consequences. Various methods were used to prevent the scale formation in water such as the chemical methods in which the germination of the CaCO3 crystals is blocked using the inhibitor. In recent years, a few studies have been focused on the aspects of the surface scaling so that the different mechanisms were proposed to explain the differences between the scaling precipitation in bulk solution and scale deposition at the surface. The water distribution of some Algerian town resulting from the drilling water is supersaturated with respect to calcium carbonate. This causes reducing heat transfer in heat exchanger systems, limiting the efficiency of these devices (valves and taps) by decreasing the flow rate in the pipes; this phenomenon is more prevalent at high heating temperature. In this book chapter, we aim to give an overview of the different antiscaling properties in hard water. We also provide the inhibitors used and the researches done on Algerian water.
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References
Leroy P (1995) Mechanism of precipitation of calcium carbonate. Tribune de l’eau 573:31–46. (translated from French)
Ketrane R, Leleyter L, Baraud F, Jeannin M, Gil O, Saidani B (2010) Characterization of natural scale deposits formed in southern Algeria groundwater. Effect of its major ions on calcium carbonate precipitation. Desalination 262:21–30
Franck HUI (2011) Research on performance evaluation and anti-scaling mechanism of green scale inhibitors by static and dynamic methods, PhD thesis, Paris University, Paris
Amjad Z, Demadis ND (2015) Mineral scales and deposits (scientific and technological approaches). Elsevier, Amsterdam
Stumm W, Morgan JJ (1996) Aquatic chemistry, chemical equilibria and rates in natural waters. Wiley, New York
Antony A, Low JH, Gray S, Childress AE, Le-Clech P, Leslie G (2011) Scale formation and control in high pressure membrane water treatment systems: a review. J Membr Sci 383:1–16
Günther C, Becker A, Wolf G, Epple M (2005) In-vitro synthesis and structural characterization of amorphous calcium carbonate. Z Anorg Allg Chem 631:2830–2835
Pascal P (1958) New mineral chemistry treaty. Tome IV, Masson, Paris (translated from French)
Zidoune M (1996) Contribution to the knowledge of scaling mechanisms by various electrochemical methods. PhD thesis, Paris VI University, p 160 (translated from French)
Dugniolle E (1994) The general scale problem in pipes. Tribune de l’eau 567:6–8. (translated from French)
Grasby S (2003) naturally precipitating vaterite (μ-CaCO3) spheres: unusual carbonates formed in an extreme environment. Geochim Cosmochim Acta 67:1659–1666
Al Omari MMH, Rashid IS, Qinna NA, Jaber AM, Badwan AA (2016) Calcium carbonate. In: Profiles of drug substances. Excipients and related methodology, vol 41. Elsevier, Amsterdam, pp 31–132
Patel S, Finan MA (1999) New antifoulants for deposit control in MSF and MED plants. Desalination 124:63–74
Smith C, Coetzee PP, Meyer JP (2003) The effectiveness of a magnetic physical water treatment device on scaling in domestic hot-water storage tanks. Water SA 29:231–236
Bansal B, Müller-Steinhagen H (1993) Crystallization fouling in plate heat exchangers. J Heat Transfer 115:584–591
Trivedi TJ, Shukla J, Kumar A (2014) Effect of nitrate salts on solubility behaviour of calcium sulfate dehydrate (gypsum) in the aqueous sodium chloride system and physicochemical solution properties at 308.15 K. J Chem Eng Data 59:832–838
Amjad Z (2013) Gypsum scale formation on heated metal surfaces: the influence of polymer type and polymer stability on gypsum inhibition. Desalin Water Treat 51:4709–4718
Muryanto S, Bayuseno AP, Sedion W, Mangestiyono W (2013) Influence of flow rates and copper (II) ions on the kinetics of gypsum scale formation in pipes. Int J Technol 3:217–223
Strauss SD, Puckorius PR (1984) Cooling-water treatment for control of scaling, fouling, corrosion. Power 128:S1–S24
Shih WY, Rahardianto A, Lee RW, Cohen Y (2005) Morphometric characterization of calcium sulfate dihydrate (gypsum) scale on reverse osmosis membranes. J Membr Sci 252(1–2):253–263
Glade H, Kromer K, Will S, Loisel K, Nied S, Detering J, Kempter A (2013) Scale formation and mitigation of mixed salts in horizontal tube falling film evaporators for seawater desalination. Proceedings of international conference on heat exchanger fouling and cleaning, Budapest, Hungry, June 9–14, 2013
Glade A, Ulrich J (2003) Influence of solution composition on the formation of crystalline scales. Chem Eng Technol 26:277–281
Andrews A, Davé B, López-Serrano P, Tsai SP, Frank R, Wilk M, Koutsakos E (2008) Effective scale control for sea water RO operating with high feed water pH and temperature. Desalination 220:295–304
Hermosilla D, Ordóñez R, Blanco L, De la Fuente E, Blanco A (2012) pH and particle structure effects on silica removal by coagulation. Chem Eng Technol 35:1632–1640
Ning RY (2010) Reactive silica in natural waters e a review. Desalin Water Treat 21:79–86
Vidojkovic S, Onjia A, Matovic B, Grahovac N, Maksimovic V, Nastasovic A (2013) Extensive feedwater quality control and monitoring concept for preventing chemistry-related failures of boiler tubes in a subcritical thermal power plant. Appl Therm Eng 59:683–694
Nishida A, Shimada Y, Saito T, Okaue Y, Yokoyama T (2009) Effect of aluminium on the deposition of silica scales in cooling water systems. J Colloid Interface Sci 335:18–23
Amjad Z, Koutsoukos PG (2014) Evaluation of maleic acid based polymers as scale as scale inhibitors and dispersants for industrial water applications. Desalination 335:55–63
García AV, Thomsen K, Stenby EH (2005) Prediction of mineral scale formation in geothermal and oilfield operations using the extended UNIQUAC model, part I. Sulfate scaling minerals. Geothermics 34:61–97
Dávilla-Pulido GI, Uribe-Salas A (2014) Effect of calcium, sulfate and gypsum on copper activated and non-activated sphalerite surface properties. Miner Eng 55:147–153
Lin W, Colin C, Rosset R (1990) Caractérisation du pouvoir incrustant d’une eau par chronoampérométrie au potentiel optimal d’entartrage. TSM-L’eau 12:613–620
Rosset R, Sok P, Poindessous G, Ben Amor M, Welha K (1998) Characterization of the compactness of calcium carbonate deposits in geothermal waters of southern Tunisia by impedancemetry. C R Acad Sci Paris t.1:751–759. (translated from French)
Tlili MM, Elfil H, Ben Amor M (2001) Chemical inhibition of scaling. Cahiers Eur Sci Assoc Water Health 6:29–39. (translated from French)
Trade Association of Research and Production (1993) Oil and natural gas commits technicians circuits seawater treatment and materials, vol 95. Editions Tech, Paris, pp 99–195. (translated from French)
Roques H (1989) Theoretical foundations of chemical treatment of water, vol 1, Edition lavoisier TEC et DOC 217–508. (translated from French)
Geffroy C, Persello J, Foissy A, Cabane B, Tournilhac F (1997) The frontier between adsorption and precipitation of polyacrylic acid on calcium carbonate. Rev Institut Fr pétrole 52:183–190
Guofeng C, Yao N, Aksay LA, Groves JT (1998) Biomimetic synthesis of macroscopic-scale calcium carbonate thin films, evidence for a multistep assembly process. J Am Chem Soc 120:11977–11985
Boggavarapu S, Chang J, Calvert P (2000) A test for mineralization inhibition for calcium salts using agarose hydrogels. Sci Eng C 11:47–49
Ghizellaoui S, Lédion J, Chibani A (2004) Study of the inhibition of the scaling power of Hamma waters by rapid controlled precipitation and an accelerated scaling test. Desalination 166:315–327. (translated from French)
Lédion J, François B, Vienne J (1998) Characterization of the scaling power of water by fast controlled precipitation. J Eur Hydrol 28:15–35. (translated from French)
Urion E, Lejeune G (1950) The role of zinc in inhibiting scaling. Revue de l’Eau 37(2):23–28. (translated from French)
Peters RW, Stevens JD (1982) Effect of iron as a trace imurity on the water softening process. AICHE Sympos Ser 78:46–67
Katz JL, Parsiegla IK (1995) Calcite growth inhibition by ferrous and ferric ions. In: Amjad Z (ed) Mineral scale formation and inhibition. Plenium Press, New York, pp 11–21
Katz JL, Reick MR, Herzog RE, Parsiegla KI (1993) Calcite growth inhibition by iron. Langmiur 9:1423–1430
Pernot B, Euvard M, Simo P (1998) Effet of iron and manganese on the scaling potentiality of water. J Water SRT-Aqua 47:21–29
Rosset R, Mercier D, Douville S (1997) La mesure du pouvoir entartant des eaux par méthodes électrochimiques et les procédés antitartre. Ann Fasl Exp Chim 90:41–65
Nancollas G, Kzmierczak G, Schuttringer E (1981) A controlled composition study of calcium carbonate crystal growth: the influence of scale inhibitors. Corrosion 37:76–81
Rosset R, Douville S, Ben Amor M, Welha K (1999) Inhibition of scaling by the geothermal waters of southern Tunisia. Rev Sci Eau 12(4):753–764. (translated from French)
Xu G, Yao N, Aksay LA, Groves JT (1998) Biomimetic synthesis of macroscopic-scale calcium carbonate thin films, evidence for a multistep assembly process. J Am Chem Soc 120:11977–11985
Shiliang H, Amy T, Thompson MB (1999) Inhibition of calcium carbonate precipitation in NaCl brines from 25 to 90 °C. Appl Geochem 14:17–25
Zidoune M, Khalil A, Sakaya P, Colin C, Rosset R (1992) Demonstration of the anti-encrusting effect of aminotri-(methylenephosphonic acid) by chronoamperometry and chronoelectrogrovimetry. C R Aca Sci Paris 315:795–799. (translated from French)
Ladel J, Leroy P (1997) Demonstration of the inhibitory effect of planktonic algae metabolites on the precipitation of calcium carbonate in natural waters of superficial origin. J Eur Hydrol 28:69–86. (translated from French)
Bailly JR, Couffin N, Lebugle A, Domingueza M, Revel JC, Roque H (1998) Contribution to the study of phenomena of scaling. Tribune de l’eau 592:3–36. (translated from French)
Abd-El-Khalek DE, Abd-El-Nabey BA (2013) Evaluation of sodium hexametaphosphate as scale and corrosion inhibitor in cooling water using electrochemical techniques. Desalination 311:227–233
Abd-El-Khalek DE, Abd-El-Nabey BA, Mervat A-KMA, Ramadan SR (2016) Investigation of a novel environmentally friendly inhibitor for calcium carbonate scaling in cooling water. Desalin Water Treat 57:2870–2876
Gao Y, Fan L, Ward L, Liu Z (2015) Synthesis of polyaspartic acid derivative and evaluation of its corrosion and scale inhibition performance in seawater utilization. Desalination 365:220–226
Touir R, Dkhireche N, Touhami ME, Bakri ME, Rochdi AH, Belakhmima RA (2014) Study of the mechanism action of sodium gluconate used for the protection of scale and corrosion in cooling water system. J Saudi Chem Soc 18:873–881
Huang H, Yao Q, Jiao Q, Liu B, Chen H (2018) Polyepoxysuccinic acid with hyper-branched Structure as an environmentally friendly scale inhibitor and its scale inhibition mechanism. J Saudi Chem Soc 23:61–74
Lui D (2011) Research on performances evaluation and anti-scaling mechanism of green scale inhibitors by static and dynamic methods. PhD thesis, Ecole nationale supérieur d’Arts et Métiers, Paris, pp 19–20
Hasson D, Shemer H, Sher A (2011) State of the art of friendly “green” scale control inhib itors: a review article. Ind Eng Chem Res 50:7601–7607
Sun Y, Xiang W, Wang Y (2009) Study on polyepoxysuccinic acid reverse osmosis scale inhibitor. J Environ Sci Suppl 21:S73–S75
Liu D, Dong W, Li F, Hui F, Lédion J (2012) Comparative performance of polyepoxysuccinic acid and polyaspartic acid on scaling inhibition by static and rapid controlled precipitation methods. Desalination 304:1–10
Schweinsberg M, Hater W, Verdes J (2003) New stable biodegradable scale inhibitor formulations for cooling water: development and field tests. 64th International Water Conference, Pittsburgh, PA, Oct 19–23
Girasa W, De Wispelaere M (2004) Polyaspartate, an New Alternative for the Conditioning of Cooling Water. 14th International Conference on the Properties of Water and Steam, Kyoto, Japan, Aug 29–Sep 3
Thombre SM, Sarwade BD (2005) Synthesis and biodegradability of polyaspartic acid: a critical review. J Macromol Sci 42:1299–1315
Gao Y, Liu Z, Zhang L, Wang Y (2010) Synthesis and performance research of biodegradable modified polyaspartic acid. Third international conference on bioinformatics and biomedical engineering, Beijing, China, Jun 11–12
Johannsen FR (2003) Toxicology profile of carboxymethyl inulin. Food Chem Toxicol 14:49–59
Verraest DL, Peters JA, Bekkum H, Rosmalen GM (1996) Carboxymethyl inulin: a new inhibitor for calcium carbonate precipitation. J Am Oil Chem Soc 73:55–62
Stevenson FJ (1994) Humus chemistry: genesis, composition, reactions. Wiley, New York
Hoch AR, Reddy MM, Aiken GR (2000) Calcite crystal growth inhibition by humic substances with emphasis on hydrophobic acids from the Florida Everglades. Geochim Cosmochim Acta 64:61–72
Kumar T, Vishwanatham S, Kundu SS (2010) A laboratory study on pteroyl-L-glutamic acid as a scale prevention inhibitor of calcium carbonate in aqueous solution of synthetic produced water. J Pet Sci Eng 71:1–7
NACE Standard TM 0197-97 (1997) Laboratory Screening Test to Determine the Ability of Scale Inhibitors to prevent the Precipitation of Barium Sulfate and/or Strontium Sulfate from Solution (for Oil and Gas Production Systems), Item No 21228, NACE International
Amjad Z (1995) Mineral scale formation and inhibition. Plenum Press, New York
Gauthier G, Chao Y, Horner O, Alos-Ramos O, Hui F, Lédion J, Perrot H (2012) Application of the fast controlled precipitation method to assess the scale-forming ability of raw river waters. Desalination 299:89–95
Reddy MM, Hoch AR (2001) Calcite crystal growth rate inhibition by polycarboxylic acids. J Colloid Interface Sci 235:365–370
Abdel-Gaber AM, Abd-El-Nabey BA, Khamis E, Abd-El-Khaled DE (2011) A natural extract as scale and corrosion inhibitor for steel surface in brine solution. Desalination 278:337–342
Bonoli M, Bendini A, Cerretani L, Lercker G, Tosci TG (2004) Qualitative and semiquantitative analysis of phenolic compounds in extra virgin olive oils as a function of the ripening degree of olive fruits by different analytical techniques. J Agric Food Chem 52:7026–7032
Maciejewska G, Zierkiewicz W, Adach A, Kopacz M, Zapala I, Bulik I, Cies’lak-Golonka M, Grabowski T, Wietrzyk J (2009) A typical calcium coordination number: physico-chemical study, cytotoxicity, DFT calculations and in silico pharmacokinetic characteristics of calcium caffeates. J Inorg Biochem 103:1189–1195
Lee OH, Lee BY, Lee J, Lee HB, Son JY, Park CS, Shetty K, Kim YC (2009) Assessment of phenolics-enriched extract and fractions of olive leaves and their antioxidant activities. Bioresour Technol 100:6107–6113
Abdel-Gaber AM, Abd-El-Nabey BA, Khamis E, Abd-El-Rhmann H, Aglan H, Ludwick A (2012) Green anti-scalant for cooling water systems. Int J Electrochem Sci 7:11930–11940
Castillo LA, Torin EV, Garcia JA, Carrasquero MA, Navas M, Ailoria A (2009) New product for inhibition of calcium carbonate scale in natural gas and oil facilities based on Aloe Vera: application in Venezuelan oilfields. Latin American and Caribbean Petroleum Engineering Conference, Cartagena de Indias, Colombia, 31 May–3 June
Viloria A, Castillo L, Garcia JA, Carrasquero Ordaz MA,Torin EV (2011) Process using Aloe for inhibiting scale. US Patent US 8039421 B2
Woodward C, Davidson EA (1968) Structure-function relationships of protein polysaccharide complexes: specific ion-binding properties. Proc Natl Acad Sci U S A 60:201–205
Menzri R, Ghizellaoui S (2012) Chronoamperometry study of the Inhibition of groundwater scaling deposits in Fourchi. Energy Procedia 18:1523–1532
Labiod K, Ghizelloui S (2012) Contribution to the inhibitors methods study of the scaling: chemical, electrochemical processes in the presence of Ca(OH)2, Na2CO3 and KH2PO4. Energy Procedia 18:1541–1556
Belarbi Z, Gamby J, Makhloufi L, Sotta B, Tribollet B (2014) Inhibition of calcium carbonate precipitation by aqueous extract of Paronychia Argentea. J Crys Growth 386:208–214
Aidoud R, Kahoul A, Naamoune F (2017) Inhibition of calcium carbonate deposition on stainless steel using olive leaf extract as a green inhibitor. Environ Technol 3:14–22
Karar A, Naamoune F, Kahoul A, Belattar N (2016) Inhibitory effect of glutamic acid on the scale formation process using electrochemical methods. Environ Technol 37:1996–2002
Karar A, Naamoune F, Kahoul A (2016) Chemical and electrochemical study of the inhibition of calcium carbonate precipitation using citric acid and sodium citrate. Desalin Water Treat 57:16300–16309
Karar A, Naamoune F (2018) Inhibition of calcium carbonate precipitation by citric acid. Mater Biomater Sci 1:019–023
Bendaoud YB, Ghizellaoui S, Tlili M (2012) Inhibition of CaCO3 scale formation in ground waters using mineral phosphates. Desalin Water Treat 38:271–277
Labraoui-Djallal K, Bounoughaz M (2016) Evaluation efficiency of barium sulfate scale inhibitors by electrochemical impedance spectroscopy. Int J Electrochem Sci 11:1777–1788
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Karar, A., Henni, A. (2020). Scale Inhibition in Hard Water System. In: Negm, A.M., Bouderbala, A., Chenchouni, H., Barceló, D. (eds) Water Resources in Algeria - Part I. The Handbook of Environmental Chemistry, vol 97. Springer, Cham. https://doi.org/10.1007/698_2020_530
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DOI: https://doi.org/10.1007/698_2020_530
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