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Emerging Brominated Flame Retardants in the Environment

  • Cynthia A. de WitEmail author
  • Amelie Kierkegaard
  • Niklas Ricklund
  • Ulla Sellström
Chapter
Part of the The Handbook of Environmental Chemistry book series (HEC, volume 16)

Abstract

A number of new brominated flame retardants (BFRs) are being found in the environment but the amount of data is still very small. The best studied emerging BFRs are 1,2-bis(2,4,6-tribromophenoxy)ethane and decabromodiphenyl ethane, with some data for hexabromobenzene, pentabromoethylbenzene, pentabromotoluene, tetrabromobisphenol A derivatives, bis(2-ethylhexyl) tetrabromophthalate, 2-ethylhexyltetrabromobenzoate, 1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane, and 2,4,6-tribromophenol. Very little data are available for 2,4,6-tribromophenyl allyl ether, 2,3-dibromopropyl-2,4,6-tribromophenyl ether, hexachlorocyclopentadienyldibromocyclooctane, tris(2,3-dibromopropyl) isocyanurate, tetrabromophthalic anhydride, 1,2,5,6-tetrabromocyclooctane, and octabromo-1,3,3-trimethyl-1-phenylindane. Indoor air concentrations are generally higher than outdoor air concentrations, indicating emissions from flame-retarded products. Their presence in indoor air and dust indicates possible human exposure from this pathway, but there are little human data available to determine this. The presence of several of these BFRs in fish, birds, and mammals indicates that they are bioavailable and can be absorbed and bioaccumulated. Their presence in outdoor air and in the Arctic indicates that several are capable of long range atmospheric transport. More data on these new BFRs are needed in order to determine if they pose unacceptable risks to the environment and to human health.

Graphical Abstract

Keywords

1,2,5,6-Tetrabromocyclooctane 1,2-Bis(2,4,6-tribromophenoxy)ethane 1,2-Dibromo-4-(1,2-dibromoethyl)cyclohexane 2,3-Dibromopropyl-2,4,6-tribromophenyl ether 2,4,6-Tribromophenol 2,4,6-Tribromophenyl allyl ether 2-Ethylhexyltetrabromobenzoate Bis(2-ethylhexyl) tetrabromophthalate Decabromodiphenyl ethane Hexabromobenzene Hexachlorocyclopentadienyldibromocyclooctane Octabromo-1,3,3-trimethyl-1-phenylindane Pentabromoethylbenzene Pentabromotoluene Tetrabromobisphenol A derivatives Tetra bromophthalic anhydride Tris(2,3-dibromopropyl) isocyanurate 

Abbreviations

ATE

2,4,6-Tribromophenyl allyl ether

BFR

Brominated flame retardant

BTBPE

1,2-Bis(2,4,6-tribromophenoxy)ethane

DBDPE

Decabromodiphenyl ethane

DPTE

2,3-Dibromopropyl-2,4,6-tribromophenyl ether

HBBz

Hexabromobenzene

HBCD

Hexabromocyclododecane

HCDBCO

Hexachlorocyclopentadienyldibromocyclooctane

OBIND

Octabromo-1,3,3-trimethyl-1-phenylindane

PBDE

Polybrominated diphenyl ether

PBEB

Pentabromoethylbenzene

PBT

Pentabromotoluene

TBB

2-Ethylhexyltetrabromobenzoate

TBBPA

Tetrabromobisphenol A

TBBPA-DAE

Tetrabromobisphenol A bis(allyl ether)

TBBPA-DBPE

Tetrabromobisphenol A (2,3-dibromopropyl ether)

TBBPA-DHEE

Tetrabromobisphenol A dihydroxyethyl ether

TBC

Tris(2,3-dibromopropyl) isocyanurate

TBCO

1,2,5,6-Tetrabromocyclooctane

TBECH

1,2-Dibromo-4-(1,2-dibromoethyl)cyclohexane

TBP

2,4,6-Tribromophenol

TBPA

Tetrabromophthalic anhydride

TBPH

Bis(2-ethylhexyl) tetrabromophthalate

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Copyright information

© Springer-Verlag Berlin Heidelberg 2010

Authors and Affiliations

  • Cynthia A. de Wit
    • 1
    Email author
  • Amelie Kierkegaard
    • 1
  • Niklas Ricklund
    • 1
  • Ulla Sellström
    • 1
  1. 1.Department of Applied Environmental Science (ITM)Stockholm UniversityStockholmSweden

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