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The Periodic Table II pp 89–120Cite as

The Periodic Table as a Guide to the Construction and Properties of Layered Double Hydroxides

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Part of the book series: Structure and Bonding ((STRUCTURE,volume 182))

Abstract

Layered double hydroxides (LDHs) have received considerable attention in recent years because both the cations incorporated in the layers and the interlayer anions can be varied widely, facilitating the tailored fabrication of a large family of functional LDH materials with specific properties and applications. In this chapter, we focus on understanding how the nature and extent of cation substitution in the layers reflect the position of that cation in the Periodic Table. Our analyses indicate that the electron configurations and coordination properties of the cations in the layers result in periodic variations in the fundamental properties of the resulting LDHs, such as their local coordination geometry, stability, electronegativity, and band structure. These periodic variations directly influence the efficacy of a given LDH in applications such as solid base catalysis and photocatalysis.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (NSFC: 21871021, 21521005 and 21627813), the National Key Research and Development Program (Grant No. 2017YFA0206804), and the Fundamental Research Funds for the Central Universities (buctylkxj01, XK1802-6 and 12060093063).

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Authors and Affiliations

  1. State Key Laboratory of Chemical Resource Engineering, College of Chemistry, Beijing University of Chemical Technology, Beijing, People’s Republic of China

    Hong Yan, Xiao-Jie Zhao, Yu-Quan Zhu, Min Wei, David G. Evans & Xue Duan

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  1. Hong Yan
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  2. Xiao-Jie Zhao
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  3. Yu-Quan Zhu
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  4. Min Wei
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  5. David G. Evans
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  6. Xue Duan
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Correspondence to Hong Yan or David G. Evans .

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  1. Inorganic Chemistry Laboratory, University of Oxford, Oxford, UK

    D. Michael P. Mingos

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Yan, H., Zhao, XJ., Zhu, YQ., Wei, M., Evans, D.G., Duan, X. (2019). The Periodic Table as a Guide to the Construction and Properties of Layered Double Hydroxides. In: Mingos, D. (eds) The Periodic Table II. Structure and Bonding, vol 182. Springer, Cham. https://doi.org/10.1007/430_2019_47

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