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Chevrel Phases: Genesis and Developments

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Book cover Ligated Transition Metal Clusters in Solid-state Chemistry

Part of the book series: Structure and Bonding ((STRUCTURE,volume 180))

Abstract

This chapter summarizes the important role played by Marcel Sergent in the discovery in the Rennes Laboratory of the Chevrel Phases, which stimulated considerable interest in the international solid-state chemistry community, because of their remarkable superconducting properties. After a brief general introduction to this topic, the seminal discoveries associated with these phases between 1970 and 1990 are described. After that their initial synthesis and structural determination was discovered, it was necessary to establish their critical superconducting transition temperature, the critical magnetic field, and the critical current density in wires, single crystals, and thin films. More recently their applications as battery materials, in catalysis, and their thermoelectric properties have been studied and are briefly described. These phases opened up the way not only to a rich solid-state chemistry but also to a rich solution chemistry, which complemented the classical field of transition metal carbonyl clusters. The basic cluster units of the Chevrel Phases continue to be studied in the Rennes Laboratory by the heirs of Marcel Sergent and more widely in the international community.

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References

  1. Nakamura R (1998) Serial experiments lain. Manga cartoon, Tokyo

    Google Scholar 

  2. Fischer Ø, Mapple B (eds) (1982) Superconductivity in ternary compounds I. Topics in current physics. Springer, Berlin

    Google Scholar 

  3. Penã O (2015). Physica C 514:95

    Article  CAS  Google Scholar 

  4. Sergent M (1969) Sur des Thiomolybdites, des Thiotungstites et des Thiochromites Alcalins. Thesis dissertation, University of Rennes, in French

    Google Scholar 

  5. Sergent M, Prigent J (1965). CR Acad Sci Paris 261:5135

    CAS  Google Scholar 

  6. Espelund AW (1967). Acta Chem Scand 21:839

    Article  CAS  Google Scholar 

  7. Brosset C (1945). Arkiv Kemi Mineral Geol A 20:16

    Google Scholar 

  8. Schäfer H, von Schnering HG, Tillack J, Kuhnen F, Wöhrle H, Baumann H (1967). Z Anorg Allg Chem 353:281

    Article  Google Scholar 

  9. Chevrel R (1974) Nouveaux composes sulfurés ternaires du molybdène de basse valence, présentant des liaisons molybdène-molybdène sous forme de chaînes ou de clusters octaédriques. Thesis dissertation, University of Rennes, in French

    Google Scholar 

  10. Chevrel R, Sergent M, Prigent J (1971). J Solid State Chem 3:515

    Article  CAS  Google Scholar 

  11. Cotton FA (1964). Inorg Chem 3:1217

    Article  CAS  Google Scholar 

  12. Bars O, Sergent M, Grandjean D (1970). C R Acad Sci Paris Ser C 270:1233

    CAS  Google Scholar 

  13. Sergent M, Chevrel R (1973). J Solid State Chem 6:433

    Article  CAS  Google Scholar 

  14. Fischer Ø, Treyvaud A, Chevrel R, Sergent M (1975). Solid State Commun 17:721

    Article  CAS  Google Scholar 

  15. Sergent M, Chevrel R, Rossel C, Fischer Ø (1978). J Less-Common Met 58:179

    Article  CAS  Google Scholar 

  16. Noël H, Chevrel R, Sergent M (1981) Actinides 1981, Los-Angeles, CA, 10–15 Sept 1981

    Google Scholar 

  17. Fischer Ø (1978). Appl Phys 16:1

    Article  CAS  Google Scholar 

  18. Bars O, Guillevic J, Grandjean D (1973). J Solid State Chem 6:48

    Article  CAS  Google Scholar 

  19. Opalovskii AA, Fedorov VE (1966). Izv Acad Nauk SSSR Neorg Mater 2:443

    CAS  Google Scholar 

  20. Swanson HE, Tatge E (1953). Natl Bur Standards Circ (U S) 539:1–95

    Google Scholar 

  21. Schäfer H, von Schnering HG (1964). Angew Chem 20:833

    Article  Google Scholar 

  22. Bars O, Guillevic J, Grandjean D (1973). J Solid State Chem 6:335

    Article  CAS  Google Scholar 

  23. Guillevic J, Bars O, Grandjean D (1973). J Solid State Chem 7:158

    Article  CAS  Google Scholar 

  24. Marezio M, Dernier PD, Remeika JP, Corenzwit E, Matthias BT (1973). Mater Res Bull 8:657

    Article  CAS  Google Scholar 

  25. Guillevic J, Lestrat H, Grandjean D (1976). Acta Cryst B32:1342

    Article  CAS  Google Scholar 

  26. Yvon K, Paoli A, Flükiger R, Chevrel R (1977). Acta Cryst B33:3066

    Article  CAS  Google Scholar 

  27. Crossman LD, Olsen DP, Duffey GH (1963). J Chem Phys 38:73

    Article  CAS  Google Scholar 

  28. Cotton FA, Hass TE (1964). Inorg Chem 3:10

    Article  CAS  Google Scholar 

  29. Kettle SFA (1965). Theor Chim Acta 3:211

    Article  CAS  Google Scholar 

  30. Guggenberger LJ, Sleight AW (1969). Inorg Chem 8:2041

    Article  CAS  Google Scholar 

  31. Yvon K, Paoli A (1977). Solid State Commun 24:41

    Article  CAS  Google Scholar 

  32. Corbett JD (1981). J Solid State Chem 39:56

    Article  CAS  Google Scholar 

  33. Andersen OK, Klose W, Nohl H (1978). Phys Rev B17:1209

    Article  Google Scholar 

  34. Mattheis LF, Fong CY (1977). Phys Rev B15:1760

    Article  Google Scholar 

  35. Bullett DW (1977). Phys Rev Lett 39:664

    Article  CAS  Google Scholar 

  36. Jarlborg T, Freemann AJ (1980). Phys Rev Lett 44:178

    Article  CAS  Google Scholar 

  37. Hughbanks T, Hoffmann R (1983). J Am Chem Soc 105:1150

    Article  CAS  Google Scholar 

  38. Certain D, Le Beuze A, Lissillour R (1983). Solid State Commun 46:7

    Article  CAS  Google Scholar 

  39. Certain D, Lissillour R (1986). Z Phys D 3:411

    Article  CAS  Google Scholar 

  40. Matthias BT, Marezio M, Corenzwit E, Cooper AS, Barz HE (1972). Science 175:1465

    Article  CAS  PubMed  Google Scholar 

  41. Lawson AC (1972). Mater Res Bull 7:773

    Article  CAS  Google Scholar 

  42. Fischer Ø, Odermatt R, Bongi G, Jones H, Chevrel R, Sergent M (1973). Phys Lett 45A:87

    Article  Google Scholar 

  43. Chevrel R, Sergent M, Fischer Ø (1975). Mater Res Bull 10:1169

    Article  CAS  Google Scholar 

  44. Odermat R, Fischer Ø, Jones H, Bongi G (1974). J Phys C 7:L13

    Article  Google Scholar 

  45. Fischer Ø, Jones H, Bongi G, Sergent M, Chevrel R (1974). J Phys C 7:L450

    Article  CAS  Google Scholar 

  46. Fischer Ø, Descroux M, Roth S, Chevrel R, Sergent M (1975). J Phys C 8:L474

    Article  CAS  Google Scholar 

  47. Descroux M, Fischer Ø, Flükiger R, Seeber B, Delesclefs R, Sergent M (1978). Solid State Commun 25:393

    Article  Google Scholar 

  48. Fischer Ø (1974) Proceedings in the conference of physics in high magnetic fields, Grenoble

    Google Scholar 

  49. Ishikawa M, Fischer Ø (1977). Solid State Commun 23:37

    Article  CAS  Google Scholar 

  50. Chevrel R, Hirrien M, Sergent M (1986). Polyhedron 5:87

    Article  CAS  Google Scholar 

  51. Meul HW, Rossel C, Descroux M, Fischer Ø, Remenyi G, Briggs A (1984). Phys Rev Lett 53:497

    Article  CAS  Google Scholar 

  52. Decroux M, Fischer Ø, Chevrel R (1977). Cryogenics 17:291

    Article  CAS  Google Scholar 

  53. Hirrien M, Chevrel R, Sergent M, Dubots P, Genevey P (1987). Mater Lett 5:173

    Article  Google Scholar 

  54. Chevrel R, Hirrien M, Sergent M, Couach M, Dubots P, Genevey P (1989). Mater Lett 7:425

    Article  CAS  Google Scholar 

  55. Decroux M, Selvam P, Cors J, Seeber B, Fischer Ø, Chevrel R, Rabiller P, Sergent M (1993). IEEE Trans Appl Supercond 3:1502

    Article  Google Scholar 

  56. Cheggour N, Decroux M, Gupta A, Fischer Ø, Perenboom JAAJ, Bouquet V, Sergent M, Chevrel R (1998). J Appl Phys 81:6277

    Article  Google Scholar 

  57. Chevrel R, Sergent M, Le Lay L, Padiou J, Peña O, Dubots P, Genevey P, Couach M, Vallier J-C (1988). Rev Phys Appl 23:1777

    Article  CAS  Google Scholar 

  58. Banks CK, Kammerdiner L, Luo HL (1975). J Solid State Chem 15:271

    Article  CAS  Google Scholar 

  59. Alterovitz SA, Woollam JA, Kammerdiner L, Luo HL (1977). Appl Phys Lett 31:233

    Article  CAS  Google Scholar 

  60. Ohtaki R, Zao BR, Luo HL (1984). J Low Temp Phys 54:119

    Article  CAS  Google Scholar 

  61. Webb RJ, Goldman AM, Kang JH, Maps J, Schmidt MF (1985). IEEE Trans Magn 21:835

    Article  Google Scholar 

  62. Przyslupski P, Horyn R, Szymaszek J, Gren B (1978). Solid State Commun 28:869

    Article  CAS  Google Scholar 

  63. Hertel GB, Orlando TP, Tarascon JM (1985). Physica B 135:168

    Article  CAS  Google Scholar 

  64. Quéré Y, Perrin A, Padiou J, Perrin C, Seignac A, Horyn R, Sergent M (1984). Ann Chim 7-8:1065

    Google Scholar 

  65. Quéré Y, Perrin A, Horyn R, Sergent M (1985). Mater Lett 3:340

    Article  Google Scholar 

  66. Lemée N, Guilloux-Viry M, Padiou J, Sergent M, Lesueur J, Lalu F (1997). Solid State Commun 101:909

    Article  Google Scholar 

  67. Boursicot S, Bouquet V, Péron I, Guizouarn T, Potel M, Guilloux-Viry M (2012). Solid State Sci 14:719

    Article  CAS  Google Scholar 

  68. Hinode H, Yamamoto S, Wakihara M, Taniguchi M (1985). Mater Res Bull 20:611

    Article  CAS  Google Scholar 

  69. Perrin A, Perrin C, Chevrel R, Sergent M, Brochu R, Padiou J (1973) In: Groupe Français de Croissance Cristalline (ed) Cristallogénèse Expérimentale, pp 141–148

    Google Scholar 

  70. Krabbes G, Oppermann H (1981). Z Anorg Allg Chem 481:13

    Article  CAS  Google Scholar 

  71. Horyn R, Peña O, Sergent M (1985). J Less-Common Met 105:55

    Article  CAS  Google Scholar 

  72. Hauck J (1977). Mater Res Bull 12:1015

    Article  CAS  Google Scholar 

  73. Flükiger R, Devantay M, Jorda JL, Muller J (1977). IEEE Trans Magn MAG-13:818

    Article  Google Scholar 

  74. Takei H, Takahashi T, Miura T (1984). Jpn J Appl Phys 23:420

    Article  CAS  Google Scholar 

  75. Govinda Rajan K, Chandra Shekar NV, Viswanath RN, Ramasamy S (1989). J Phys D 22:1205

    Article  Google Scholar 

  76. Holtzberg F, LaPlaca SJ, McGuire TR, Webb RA (1984). J Appl Phys 55:2013

    Article  CAS  Google Scholar 

  77. Horyn R, Peña O, Geantet C, Sergent M (1989). Supercond Sci Technol 2:71

    Article  CAS  Google Scholar 

  78. Peña O, Sergent M (1989). Prog Solid State Chem 19:165

    Article  Google Scholar 

  79. Le Berre F, Hamard C, Peña O, Wojakowski A (2000). Inorg Chem 39:1100

    Article  PubMed  CAS  Google Scholar 

  80. Chevrel R, Sergent M, Prigent J (1974). Mater Res Bull 9:1487

    Article  CAS  Google Scholar 

  81. Schöllhorn R, Kümpers M, Besenhard JO (1977). Mater Res Bull 12:781

    Article  Google Scholar 

  82. Takeda Y, Kanno R, Noda M, Yamamoto O (1985). Mater Res Bull 20:71

    Article  CAS  Google Scholar 

  83. Boulanger C, Lecuire J-M (1987). Electrochim Acta 32:345

    Article  CAS  Google Scholar 

  84. Wakihara M, Uchida T, Suzuki K, Taniguchi M (1989). Electrochim Acta 34:867

    Article  CAS  Google Scholar 

  85. Wakihara M, Uchida T, Morishita T, Wakamatsu H, Taniguchi M (1987). J Power Sources 20:199

    Article  CAS  Google Scholar 

  86. Tarascon JM, Disalvo FJ, Murphy DW, Hull GW, Rietman EA, Waszczak J (1984). J Solid State Chem 54:204

    Article  CAS  Google Scholar 

  87. McKinnon WR, Dahn JR (1984). Solid State Commun 52:245

    Article  CAS  Google Scholar 

  88. Lemée N, Guilloux-Viry M, Ferré V, Perrin A, Sergent M, Lesueur J, Lalu F (1997). J Alloys Compd 262–263:54

    Article  Google Scholar 

  89. Kaidi Z, Boulanger C, Lecuire JM, Lemée N, Guilloux-Viry M, Perrin A (1999). Solid State Sci 1:623

    Article  CAS  Google Scholar 

  90. Aurbach D, Lu Z, Schechter A, Gofer Y, Gizbar H, Turgeman R, Cohen Y, Moshkovich M, Levi E (2000). Nature 407:724

    Article  CAS  PubMed  Google Scholar 

  91. Saha P, Datta MK, Velikokhatnyi OI, Manivannan A, Alman D, Kumta PN (2014). Prog Mater Sci 66:1

    Article  CAS  Google Scholar 

  92. McCarty KF, Schräder GL (1984). Ind Eng Chem Prod Res Dev 29:519

    Article  Google Scholar 

  93. Rabiller-Baudry M, Sergent M, Chevrel R (1991). Mater Res Bull 26:519

    Article  CAS  Google Scholar 

  94. Rabiller-Baudry M, Chevrel R, Sergent M (1992). J Alloys Compd 178:441

    Article  CAS  Google Scholar 

  95. Even-Boudjada S, Burel L, Chevrel R, Sergent M (1998). Mater Res Bull 33:419

    Article  CAS  Google Scholar 

  96. Harel-Michaud V, Pesnel-Leroux G, Burel L, Chevrel R, Geantet C, Cattenot M, Vrinat M (2001). J Alloys Compd 317–318:195

    Article  Google Scholar 

  97. Kamiguchi S, Takeda K, Kajio R, Okumura K, Nagashima S, Chihara T (2013). J Clust Sci 24:559

    Article  CAS  Google Scholar 

  98. Kamiguchi S, Arai K, Okumura K, Iida H, Nagashima S, Chihara T (2015). Appl Catal A 505:417

    Article  CAS  Google Scholar 

  99. Slack GA (1995) In: Rowe DM (ed) CRC handbook of thermoelectrics. Chemical Rubber, Boca Raton. Chap. 34

    Google Scholar 

  100. Umarji AM, Subba Rao GV, Janawadkar MP, Radhakrishnan TS (1980). J Phys Chem Solids 41:421

    Article  CAS  Google Scholar 

  101. Vasudeva Rao V, Rangarajan G, Srinivasan R (1984). J Phys F 14:973

    Article  Google Scholar 

  102. Nunes RW, Mazin II, Singh DJ (1999). Phys Rev B 59:7969

    Article  CAS  Google Scholar 

  103. Roche C, Chevrel R, Jenny A, Pecheur P, Scherrer H, Scherrer S (1999). Phys Rev B 60:16442

    Article  CAS  Google Scholar 

  104. Caillat T, Fleurial J-P (1998). J Phys Chem Solids 59:1139

    Article  CAS  Google Scholar 

  105. Caillat T, Fleurial J-P, Snyder GJ (1999). Solid State Sci 1:535

    Article  CAS  Google Scholar 

  106. Zhou T, Lenoir B, Candolfi C, Dauscher A, Gall P, Gougeon P, Potel M, Guilmeau E (2011). J Electron Mater 40:508

    Article  CAS  Google Scholar 

  107. Masschelein P, Candolfi C, Dauscher A, Gendarme C, Rabih ARAO, Gougeon P, Potel M, Gall P, Gauthier R, Lenoir B (2018). J Alloys Compd 739:360

    Article  CAS  Google Scholar 

  108. Chevrel R, Sergent M, Seeber B, Fischer Ø, Grüttner A, Yvon K (1979). Mater Res Bull 14:567

    Article  CAS  Google Scholar 

  109. Potel M, Chevrel R, Sergent M, Decroux M, Fischer Ø (1979). CR Acad Sci Ser C 288:429

    CAS  Google Scholar 

  110. Gougeon P, Potel M, Sergent M, Monceau P (1985). Physica B 135:386

    Article  CAS  Google Scholar 

  111. Chevrel R, Gougeon P, Potel M, Sergent M (1985). J Solid State Chem 57:25

    Article  CAS  Google Scholar 

  112. Gougeon P, Potel M, Padiou J, Sergent M (1983). CR Acad Sci Ser II 296:351

    CAS  Google Scholar 

  113. Picard S, Gougeon P, Potel M (1999). Angew Chem Int Ed 13–14:2034

    Article  Google Scholar 

  114. Gougeon P, Potel M, Sergent M (1989). Acta Cryst C 45:182

    Article  Google Scholar 

  115. Gougeon P, Potel M, Sergent M (1990). Acta Cryst C 46:2284

    Article  Google Scholar 

  116. Gautier R, Gougeon P, Halet J-F, Potel M, Saillard J-Y (1997). J Alloys Compd 262–263:311

    Article  Google Scholar 

  117. Al Rahal Al Orabi R, Boucher B, Fontaine B, Gall P, Candolfi C, Lenoir B, Gougeon P, Halet JF, Gautier R (2017). J Mater Chem C 5:12097

    Article  CAS  Google Scholar 

  118. Kareem SA, Miranda R (1989). J Mol Catal 53:275

    Article  CAS  Google Scholar 

  119. Armici JC, Decroux M, Fischer Ø, Potel M, Chevrel R, Sergent M (1980). Solid State Commun 33:607

    Article  CAS  Google Scholar 

  120. Tarascon JM, Disalvo FJ, Chen CH, Carroll PJ, Walsh M, Rupp L (1985). J Solid State Chem 58:290

    Article  CAS  Google Scholar 

  121. Gougeon P, Potel M, Sergent M (1990). Acta Cryst C 46:1188

    Article  Google Scholar 

  122. Gall P, Gougeon P (2016). Acta Cryst E 72:995

    Article  CAS  Google Scholar 

  123. Perrin A, Perrin C (2011). Eur J Inorg Chem 26:3848

    Article  CAS  Google Scholar 

  124. Perrin A, Perrin C (2012). C R Chim 15:815

    Article  CAS  Google Scholar 

  125. Sergent M, Fischer Ø, Decroux M, Perrin C, Chevrel R (1977). J Solid State Chem 22:87

    Article  CAS  Google Scholar 

  126. Perrin C, Chevrel R, Sergent M, Fischer Ø (1979). Mater Res Bull 14:1505

    Article  CAS  Google Scholar 

  127. Kimball CW, Weber L, Van Landuyt G, Fradin FY, Dunlap BD, Shenoy GK (1976). Phys Rev Lett 36:412

    Article  CAS  Google Scholar 

  128. Rannou J-P, Sergent M (1967). C R Acad Sci Ser C 265:734

    CAS  Google Scholar 

  129. Opalovski AA, Fedorov VE, Khaldoyanidi KA (1968). Dokl Akad Nauk SSSR 182:1095

    Google Scholar 

  130. Marcoll J, Rabenau A, Mootz D, Wunderlich H (1974). Rev Chim Mineral 11:607

    CAS  Google Scholar 

  131. Perrin C, Sergent M, Le Traon F, Le Traon A (1978). J Solid State Chem 25:197

    Article  CAS  Google Scholar 

  132. Pilet JC, Le Traon F, Le Traon A, Perrin C, Perrin A, Leduc L, Sergent M (1985). Surf Sci 156:359

    Article  CAS  Google Scholar 

  133. Perrin C, Sergent M (1983). J Chem Res 2:38

    Google Scholar 

  134. Perrin C, Sergent M (1983). J Chem Res 38:449

    Google Scholar 

  135. Perrin C, Potel M, Sergent M (1983). Acta Cryst 39C:415

    Google Scholar 

  136. Perrin A, Sergent M, Fischer Ø (1978). Mater Res Bull 13:259

    Article  CAS  Google Scholar 

  137. Perrin A, Chevrel R, Sergent M, Fischer Ø (1980). J Solid State Chem 33:43

    Article  CAS  Google Scholar 

  138. Perrin A, Sergent M (1980). Bull Soc Chim Fr 11–12:66

    Google Scholar 

  139. Leduc L, Perrin A, Sergent M (1983). C R Acad Sci Paris Ser II 296:961

    Google Scholar 

  140. Leduc L, Padiou J, Perrin A, Sergent M (1983). J Less-Common Met 95:73

    Article  CAS  Google Scholar 

  141. Le Nagard N, Perrin A, Sergent M, Levy-Clement C (1985). Mater Res Bull 20:835

    Article  Google Scholar 

  142. Slougui A, Perrin A, Sergent M (1992). Acta Cryst C 48:1917

    Article  Google Scholar 

  143. Slougui A, Ferron S, Perrin A, Sergent M (1996). Eur J Solid State Inorg Chem 33:1001

    CAS  Google Scholar 

  144. Pilet G, Perrin A (2005). C R Chim 8:1728

    Article  CAS  Google Scholar 

  145. Gabriel J-CP, Boubekeur K, Uriel S, Batail P (2001). Chem Rev 101:2037

    Article  CAS  PubMed  Google Scholar 

  146. Kirakci K, Cordier S, Hernandez O, Roisnel T, Paul F, Perrin C (2005). J Solid State Chem 178:3117

    Article  CAS  Google Scholar 

  147. Kirakci K, Cordier S, Perrin C (2005). Z Anorg Allg Chem 631:411

    Article  CAS  Google Scholar 

  148. Perrin A (1990). New J Chem 14:561

    CAS  Google Scholar 

  149. Ouahab L, Batail P, Perrin C, Garrigou-Lagrange C (1986). Mater Res Bull 21:1223

    Article  CAS  Google Scholar 

  150. Batail P, Ouahab L, Penicaud A, Lenoir C, Perrin A (1987). C R Acad Sci Ser II 304:1111

    CAS  Google Scholar 

  151. Hilsenbeck SJ, Young Jr VG, McCarley RE (1994). Inorg Chem 33:1822

    Article  CAS  Google Scholar 

  152. Zheng Z, Long JR, Holm RH (1997). J Am Chem Soc 119:2163

    Article  CAS  Google Scholar 

  153. Mironov YV, Virovets AV, Fedorov VE, Podberezkaya NY, Shishkin OV, Struchkov YT (1995). Polyhedron 14:3171

    Article  CAS  Google Scholar 

  154. Slougui A, Mironov Y, Perrin A, Fedorov V (1995). Croat Chem Acta 68:885

    CAS  Google Scholar 

  155. Cordier S, Naumov NG, Salloum D, Paul F, Perrin C (2004). Inorg Chem 43:219

    Article  CAS  PubMed  Google Scholar 

  156. Yarovoi SS, Mironov YV, Naumov DY, Gatilov YV, Kozlova SG, Kim SJ, Fedorov VE (2005). Eur J Inorg Chem 2005:3945

    Article  CAS  Google Scholar 

  157. Kim Y, Fedorov VE, Kim SJ (2009). J Mater Chem 19:7178

    Article  CAS  Google Scholar 

  158. Fedin VP, Virovets AA, Sykes AG (1998). Inorg Chim Acta 271:228

    Article  CAS  Google Scholar 

  159. Cordier S, Kirakci K, Pilet G, Méry D, Astruc D, Perrin A, Perrin C (2005). Prog Solid State Chem 33:81

    Article  CAS  Google Scholar 

  160. Chevrel R, Sergent M, Prigent J (1968). C R Acad Sci 267:1135

    CAS  Google Scholar 

  161. Perrin C, Chevrel R, Sergent M (1975). C R Acad Sci Ser C 281:23

    CAS  Google Scholar 

  162. Perrin C, Chevrel R, Sergent M (1975). C R Acad Sci Ser C 280:949

    CAS  Google Scholar 

  163. Ben Yaich H, Jegaden JC, Potel M, Sergent M, Rastogi AK, Tournier R (1984). J Less-Common Met 102:9

    Article  CAS  Google Scholar 

  164. Guérin R, Sergent M, Prigent J (1972). CR Acad Sci 274:1278

    Google Scholar 

  165. Geng L, Scheifers JP, Zhang J, Bozhilov KN, Fokwa BPT, Guo J (2018). Chem Mater 30:8420

    Article  CAS  Google Scholar 

  166. Agiorgousis ML, Sun Y-Y, West D, Zhang S (2018). ACS Appl Energy Mater 1:440

    Article  CAS  Google Scholar 

  167. Mao M, Gao T, Hou S, Wang C (2018). Chem Soc Rev 47:8804

    Article  CAS  PubMed  Google Scholar 

  168. Ojha K, Banerjee S, Sharma M, Dagar P, Ganguli AK (2018). Bull Mater Sci 41:119

    Article  CAS  Google Scholar 

  169. Richard J, Benayad A, Colin J-F, Martinet S (2017). J Phys Chem C 121:17096

    Article  CAS  Google Scholar 

  170. Yue J, Zhu X, Han F, Fan X, Wang L, Yang J, Wang C (2018). ACS Mater Interfaces 10:39645

    Article  CAS  Google Scholar 

  171. Zhong X, Lee K, Choi B, Meggiolaro D, Liu F, Nuckolls C, Pasupathy A, De Angelis F, Batail P, Roy X, Zhu X (2018). Nano Lett 18:1483

    Article  CAS  PubMed  Google Scholar 

  172. Boursicot S, Bouquet V, Bombard A, Langer M, Boulanger C, Guilloux-Viry M (2017). Electrochem Acta 257:436

    Article  CAS  Google Scholar 

  173. Gannon L, Boeri L, Howard CA, Gougeon P, Gall P, Potel M, Salloum D, Petrovic AP, Hoesch M (2018). Phys Rev B 98:014104

    Article  CAS  Google Scholar 

  174. Camerel F, Kinloch F, Jeannin O, Robin M, Nayak SK, Jacques E, Brylev KA, Naumov NG, Molard Y (2018). Dalton Trans 47:10884

    Article  CAS  PubMed  Google Scholar 

  175. Guy K, Ehni P, Paofai S, Forschner R, Roiland C, Amela-Cortes M, Cordier S, Laschat S, Molard Y (2018). Angew Chem Int Ed 57:11692

    Article  CAS  Google Scholar 

  176. Pellen-Mussi P, Tricot-Doleux S, Neaime C, Nerambourg N, Cabello-Hurtado F, Cordier S, Grasset F, Jeanne S (2018). J Nanosci Nanotechnol 18:3148

    Article  CAS  PubMed  Google Scholar 

  177. Gandubert A, Amela-Cortes M, Nayak SK, Vicent C, Meriadec C, Artzner F, Cordier S, Molard Y (2018). J Mater Chem 6:2556

    CAS  Google Scholar 

  178. Barbosa J, Prestipino C, Hernandez OJ, Paofai S, Dejoie C, Guilloux-Viry M, Boulanger C (2019). Inorg Chem 58:2158

    Article  CAS  PubMed  Google Scholar 

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Acknowledgments

The authors are very grateful to Marie-Jeanne Sergent, spouse of Marcel, and to Prof. Odile Sergent, his daughter, for giving access to helpful documents from their private collection.

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Authors and Affiliations

  1. Institut des Sciences Chimiques de Rennes, UMR CNRS 6226, Université de Rennes 1, Rennes, France

    André Perrin, Christiane Perrin & Roger Chevrel

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  1. André Perrin
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  2. Christiane Perrin
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  3. Roger Chevrel
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Correspondence to André Perrin .

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  1. Institut des Sciences Chimiques de Rennes – UMR 6226, Univ Rennes, CNRS, Rennes, France

    Jean-François Halet

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Perrin, A., Perrin, C., Chevrel, R. (2019). Chevrel Phases: Genesis and Developments. In: Halet, JF. (eds) Ligated Transition Metal Clusters in Solid-state Chemistry . Structure and Bonding, vol 180. Springer, Cham. https://doi.org/10.1007/430_2019_35

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