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Polyoxometalate-Based Photo-Sensitive Functional Hybrid Materials

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Polyoxometalate-Based Assemblies and Functional Materials

Part of the book series: Structure and Bonding ((STRUCTURE,volume 176))

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Abstract

The photochemical behaviors of polyoxometalates (POMs) have been extensively studied and widely used in various photo-redox reactions. Incorporating photo-sensitive organic molecules onto the POM platform not only allows the rational design and fine-controlled synthesis of novel organic–inorganic hybrids but also gives the possibility to explore their potential applications in diverse areas such as photochromics, optical switching, and smart self-assemblies. Herein, we summarize the latest progress of photo-sensitive POM hybrids with a particular focus on the photo-induced reversible coloration, polymerization, and supramolecular self-assembly. The mechanisms and the crucial roles of POM clusters in such reversible processes are also considered.

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Acknowledgements

This research was supported by the National Basic Research Program of China (973 program, 2014CB932104), the National Nature Science Foundation of China (U1407127, U1507102, 21521005, 21625101), and Fundamental Research Funds for the Central Universities. C.-G.L. appreciates financial support from the China Postdoctoral Science Foundation (2016M591048).

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Authors and Affiliations

  1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, 100029, P. R. China

    Chang-Gen Lin, Wei Chen & Yu-Fei Song

  2. Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029, P. R. China

    Chang-Gen Lin & Yu-Fei Song

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  1. Chang-Gen Lin
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  2. Wei Chen
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Correspondence to Yu-Fei Song .

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  1. Beijing University of Chemical Technology, Beijing, China

    Yu-Fei Song

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Lin, CG., Chen, W., Song, YF. (2017). Polyoxometalate-Based Photo-Sensitive Functional Hybrid Materials. In: Song, YF. (eds) Polyoxometalate-Based Assemblies and Functional Materials. Structure and Bonding, vol 176. Springer, Cham. https://doi.org/10.1007/430_2017_1

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