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Luminescent Lanthanide Metal–Organic Frameworks

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Book cover Lanthanide Metal-Organic Frameworks

Part of the book series: Structure and Bonding ((STRUCTURE,volume 163))

Abstract

More and more attention has been paid to the design and synthesis of the lanthanide metal–organic frameworks (LnMOFs). Their physicochemical properties were investigated deeply, especially in terms of the luminescent properties. Lanthanide ions, used as luminescence centers, in MOFs enable tuning options that exceed all other metals of the periodic table of the elements. This chapter explains the basic principles of lanthanide luminescence in advance, which will help the readers to understand the luminescent properties of the subsequent LnMOFs. Single-Ln3+ LnMOFs show fundamental luminescent phenomenon and law. Furthermore, mixed-Ln3+ LnMOFs exhibit significant ability of tunable white light emission and temperature measurement. Representative publication of LnMOFs with NIR luminescence and upconversion luminescence is also important to discuss here. Furthermore, bulk LnMOFs have been scaled down to the nanoregime to form nanoscale LnMOFs, which will enable their use in a broad range of applications, including drug delivery, bioimaging, and molecular sense.

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Abbreviations

1,3,5-BTC:

1,3,5-Benzenetricarboxylate

1,4-NDC:

1,4-Naphthalenedicarboxylate

ad:

Adeninate

BPDC:

Biphenyldicarboxylate

BTB:

1,3,5-Tris(4-carboxyphenyl)benzene

BTPCA:

1,1′,1″-(Benzene-1,3,5-triyl)tripiperidine-4-carboxylate

CPs:

Coordination polymers

CTAB:

Cetyltrimethylammonium bromide

DEF:

N,N′-Diethylformamide

DMA:

Dimethylammonium

DMAc:

N,N′-Dimethylacetamide

DMBDC:

2,5-Dimethoxy-1,4-benzenedicarboxylate

DMF:

N,N′-Dimethylformamide

DPA:

Dipicolinic acid

dpdc:

2,2′-Diphenyldicarboxylate

H2bidc:

Benzimidazole-5,6-dicarboxylic acid

H2L4:

3,3′-(4-Amino-4H-1,2,4-triazole-3,5-diyl)dibenzoic acid

H2oba:

4,4′-Oxybis(benzoic acid)

H2ox:

Oxalic acid

H2PIA:

5-(Pyridin-4-yl)isophthalic acid

H2PVDC:

4,4′-[(2,5-Dimethoxy-1,4-phenylene)di-2,1-ethenediyl]bisbenzoic acid

H3BPT:

Biphenyl-3,4′,5-tricarboxylic acid

H3cpda:

5-(4-Carboxyphenyl)-2,6-pyridinedicarboxylic acid

H3DSB:

3,5-Disulfobenzoic acid

H3L2:

4,4′-((2-((4-Carboxyphenoxy)methyl)-2-methylpropane-1,3-diyl)bis(oxy))dibenzoic acid

H4L3:

N-phenyl-N′-phenyl bicyclo[2,2,2]-oct-7-ene-2,3,5,6-tetracarboxdiimide tetracarboxylic acid

H4MDIP:

Methylenediisophthalic acid

H4pdca:

Pyridine-2,3-dicarboxylic acid

H4ptptc:

p-Terphenyl-3,3″,5,5″-tetracarboxylic acid

H4tpabn:

N,N′,N′-Tetrakis[(6-carboxypyridin-2-yl)methyl]butylenediamine

H5L5:

3,5-Bis(1-methoxy-3,5-benzene dicarboxylic acid)benzoic acid

HL1:

4-(Dipyridin-2-yl)aminobenzoic acid

IP:

1H-imidazo[4,5-f][1,10]-phenanthroline

LnMOFs:

Lanthanide metal–organic frameworks

m-bdc:

1,3-Benzenedicarboxylate

MOFs:

Metal–organic frameworks

MRI:

Magnetic resonance imaging

NIR:

Near infrared

NMOFs:

Nanoscale metal–organic frameworks

p-BDC:

1,4-Benzenedicarboxylate

p-BDC-F4 :

Tetrafluoroterephthalate or 2,3,5,6-tetrafluoro-1,4-benzenedicarboxylate

phen:

1,10-Phenanthroline

PVP:

Polyvinylpyrrolidone

UC:

Upconversion

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Acknowledgements

The authors are grateful to the financial aid from the National Natural Science Foundation of China (Grant Nos. 91122030, 21210001, 21221061, and 51372242) and the National Key Basic Research Program of China (No. 2014CB643802).

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Authors and Affiliations

  1. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, 130022, P.R. China

    Xue-Zhi Song, Shu-Yan Song & Hong-Jie Zhang

  2. University of Chinese Academy of Sciences, Beijing, 100049, China

    Xue-Zhi Song

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Correspondence to Shu-Yan Song or Hong-Jie Zhang .

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  1. Department of Chemistry, Nankai University, Tianjin, China

    Peng Cheng

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© 2014 Springer-Verlag Berlin Heidelberg

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Song, XZ., Song, SY., Zhang, HJ. (2014). Luminescent Lanthanide Metal–Organic Frameworks. In: Cheng, P. (eds) Lanthanide Metal-Organic Frameworks. Structure and Bonding, vol 163. Springer, Berlin, Heidelberg. https://doi.org/10.1007/430_2014_160

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