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Transition Metal σ-Borane Complexes

  • Zhenyang LinEmail author
Chapter
Part of the Structure and Bonding book series (STRUCTURE, volume 130)

Abstract

A variety of structural types of transition metal complexes containing σ-borane ligands are reviewed. Their structure and bonding are discussed. Compared with other types of σ-complexes, σ-borane complexes display quite different structural and bonding properties because of the electron unsaturated boron center in the σ-borane ligands in the precoordination state. The availability of an sp3-hybridized orbital at the boron center allows stronger back-donation interaction without breaking the coordinated B-H bond. The role played by σ-borane complexes in hydroboration and borylation reactions has also been reviewed.

Borylation Hydroboration σ-Borane complexes Structure and bonding 

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Copyright information

© Springer-Verlag Berlin Heidelberg 2007

Authors and Affiliations

  1. 1.Department of ChemistryThe Hong Kong University of Science and TechnologyHong KongChina

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