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Preparation of Layered Double Hydroxides

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Layered Double Hydroxides

Part of the book series: Structure and Bonding ((STRUCTURE,volume 119))

Abstract

Layered double hydroxides (LDHs) comprise an extensive class of materials that are very easy to synthesize in the laboratory, albeit not always as pure phases. In this chapter, we review the wide variety of methods that are available for the synthesis of LDHs and focus on the way in which the physicochemical properties of the materials (such as phase purity, crystallinity and surface area) vary with synthesis method. The flexibility of the different methods is also discussed: some methods can be used to synthesize LDHs containing a wide range of constituent cations and anions, whilst others are more limited in scope. In some cases, the potential for scale-up of a method to produce larger quantities of material is also noted.

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Abbreviations

CSC:

4′-chloro-4-stilbenecarboxylic acid

DNA:

Deoxyribonucleic acid

edta:

Ethylenediamine tetraacetate

EG:

Ethylene glycol

LDH:

Layered double hydroxide

HTLc:

Hydrotalcite-like compounds

ICTA:

Indole-2-carboxylate

MAS:

Magic angle spinning

NMR:

Nuclear magnetic resonance

Phe:

Phenylalanine

PXRD:

Powder X-ray diffraction

SEM:

Scanning electron microscope

TEM:

Transmission electron microscope

THF:

Tetrahydrofuran

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X. Duan David G. Evans

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He, J., Wei, M., Li, B., Kang, Y., Evans, D.G., Duan, X. Preparation of Layered Double Hydroxides. In: Duan, X., Evans, D.G. (eds) Layered Double Hydroxides. Structure and Bonding, vol 119. Springer, Berlin, Heidelberg. https://doi.org/10.1007/430_006

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