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Crystal and magnetic structures of ternary metal hydrides: A comprehensive review

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Hydrogen in Intermetallic Compounds I

Part of the book series: Topics in Applied Physics ((TAP,volume 63))

Abstract

The crystal and magnetic structures of hydrides and deuterides of binary metal compounds as determined by neutron diffraction analysis are reviewed. Emphasis is placed on the distribution of hydrogen (deuterium) atoms in the metal atom host structure. At room temperature these distributions are characterized by thermal disorder and preferential occupation of large interstices which are surrounded by atoms belonging to hydride forming elements. The metal atom arrangements are usually similar to those of the binary metal compounds, except that their lattices are generally expanded and their symmetries reduced. At low temperatures the hydrogen (deuterium) atoms tend to order, thus inducing structural phase transitions and further symmetry lowering. Efforts to rationalize observed hydrogen (deuterium) site occupancies and maximum hydrogen (deuterium) contents in terms of empirical models are reviewed. The influence of hydrogenation (deuteration) on the magnetic structures is discussed.

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  1. Klaus Yvon
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Louis Schlapbach

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Yvon, K., Fischer, P. (1988). Crystal and magnetic structures of ternary metal hydrides: A comprehensive review. In: Schlapbach, L. (eds) Hydrogen in Intermetallic Compounds I. Topics in Applied Physics, vol 63. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3540183337_11

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