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A Pincer Motif Etched into a meta-Benziporphyrin Frame

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Metal-Ligand Co-operativity

Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 68))

Abstract

The incorporation of a meta-phenylene moiety into a β-alkylated or meso-tetraarylporphyrin framework resulted in the formation of m-benziporphyrins. Their molecular design preserves all the essential virtues of the original tetrapyrrolic architecture of regular porphyrin, including the perfect match between the ionic radii of the inserted metal cation and the size of the macrocyclic (CNNN) core, and steric protection provided by thoughtfully chosen β-alkyl or meso-aryl substituents. The analogous incorporation of a pyridine moiety yielded a class of pyriporphyrins. The organometallic derivatives of m-benziporphyrins and pyriporphyrins are reminiscent of the large family of pincer ligand complexes, in which the metal–arene bond is supported by two amine or phosphine arms. This chapter relates the chemistry of the pincer ligand and that of the m-benziporphyrin (aza-m-benziporphyrin) emphasizing the fact that both groups have been structurally and functionally based on common dominators, i.e., on m-phenylene (aza-m-phenylene) rings.

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References

  1. Berlin K, Breitmaier E (1994) Angew Chem Int Ed Engl 33:1246

    Google Scholar 

  2. Stępień M, Latos-Grażyński L (2001) Chem A Eur J 7:5113

    Google Scholar 

  3. Stępień M, Latos-Grażyński L (2009) Aromaticity and tautomerism in porphyrins and porphyrinoids. In: Krygowski TM (ed) Aromaticity in heterocyclic compounds. Springer, Berlin, p 83. Chap 3

    Google Scholar 

  4. Pawlicki M, Latos-Grażyński L (2010) Carbaporphyrinoids – synthesis and coordination properties. In: Kadish KM, Smith KM, Guilard R (eds) Handbook of porphyrin science: with applications to chemistry, physics, materials science, engineering, biology and medicine. World Scientific Publishing, Singapore, p 104. Chap 8

    Google Scholar 

  5. Stępień M, Latos-Grażyński L (2005) Acc Chem Res 38:88

    PubMed  Google Scholar 

  6. Latos-Grażyński L, Rachlewicz K, Wojaczyński J (1999) Coord Chem Rev 190–192:109

    Google Scholar 

  7. Lash TD (2015) Org Biomol Chem 13:7846

    CAS  PubMed  Google Scholar 

  8. Lash TD (2014) Chem Asian J 9:682

    CAS  PubMed  Google Scholar 

  9. Lash TD (2017) Chem Rev 117:2313

    CAS  PubMed  Google Scholar 

  10. Berlicka A, Latos-Grażyński L (2020) J Porphyrins Phtalocyanines 24:1

    CAS  Google Scholar 

  11. Lee CH, Roznyatovskiy V, Hong SJ, Sessler JL (2011) Porphyrins and porphyrin analogs bearing double bonds at one or more meso-positions. In: Kadish KM, Smith KM, Guilard R (eds) Handbook of porphyrin science: with applications to chemistry, physics, materials science, engineering, biology and medicine. World Scientific Publishing, Singapore, p 197. Chap 13

    Google Scholar 

  12. Chmielewski PJ, Latos-Grażyński L, Rachlewicz K, Głowiak T (1994) Angew Chem Int Ed Engl 33:779

    Google Scholar 

  13. Furuta H, Asano T, Ogawa T (1994) J Am Chem Soc 116:767

    CAS  Google Scholar 

  14. Garbicz M, Latos-Grażyński L (2019) Angew Chem Int Ed 58:6089

    CAS  Google Scholar 

  15. Stępień M, Latos-Grażyński L (2002) J Am Chem Soc 124:3838

    PubMed  Google Scholar 

  16. Stępień M, Latos-Grażyński L, Szterenberg L, Panek J, Latajka Z (2004) J Am Chem Soc 126:4566

    PubMed  Google Scholar 

  17. Szyszko B, Latos-Grażyński L, Szterenberg L (2011) Angew Chem Int Ed 50:6587

    CAS  Google Scholar 

  18. Idec A, Szterenberg L, Latos-Grażyński L (2015) Chem A Eur J 21:12481

    CAS  Google Scholar 

  19. Idec A, Skonieczny J, Latos-Grażyński L, Pawlicki M (2016) Eur J Org Chem 2016:3691

    CAS  Google Scholar 

  20. Idec A, Pawlicki M, Latos-Grażyński L (2019) Chem A Eur J 25:200

    CAS  Google Scholar 

  21. Myśliborski R, Latos-Grażyński L (2005) Eur J Org Chem:5039

    Google Scholar 

  22. Myśliborski R, Latos-Grażyński L, Szterenberg L (2006) Eur J Org Chem:3064

    Google Scholar 

  23. Hurej K, Pawlicki M, Szterenberg L, Latos-Grażyński L (2016) Angew Chem Int Ed 55:1427

    CAS  Google Scholar 

  24. Hurej K, Pawlicki M, Latos-Grażyński L (2017) Chem A Eur J 23:2059

    CAS  Google Scholar 

  25. Hurej K, Pawlicki M, Latos-Grażyński L (2018) Chem A Eur J 23:115

    Google Scholar 

  26. Hung CH, Chang FC, Lin CY, Rachlewicz K, Stępień M, Latos-Grażyński L, Lee GH, Peng SM (2004) Inorg Chem 43:4118

    CAS  PubMed  Google Scholar 

  27. Casitas A, Canta M, Sola M, Costas M, Ribas X (2011) J Am Chem Soc 133:19386

    CAS  PubMed  Google Scholar 

  28. Bergbreiter DE, Osburn PL, Liu YS (1999) J Am Chem Soc 121:9531

    CAS  Google Scholar 

  29. Kraatz HB, Milstein D (1995) J Organomet Chem 488:223

    CAS  Google Scholar 

  30. Canty AJ, Minchin NJ, Skelton BW, White AH (1987) J Chem Soc Dalton Trans:1477

    Google Scholar 

  31. Albrecht M, van Koten G (2001) Angew Chem Int Ed 40:3750

    CAS  Google Scholar 

  32. van der Boom ME, Milstein D (2003) Chem Rev 103:1759

    PubMed  Google Scholar 

  33. Benito-Garagorri D, Kirchner K (2008) Acc Chem Res 41:201

    CAS  PubMed  Google Scholar 

  34. Whited MT, Grubbs RH (2009) Acc Chem Res 42:1607

    CAS  PubMed  Google Scholar 

  35. Choi J, MacArthur AH, Brookhart M, Goldman AS (2011) Chem Rev 111:1761

    CAS  PubMed  Google Scholar 

  36. Gunanathan C, Milstein D (2011) Acc Chem Res 44:588

    CAS  PubMed  Google Scholar 

  37. van Koten G, Gebbink R (2011) Dalton Trans 40:8731

    PubMed  Google Scholar 

  38. van Koten G (2013) The Monoanionic ECE-pincer ligand: a versatile privileged ligand platform-general considerations. Topics in organometallic chemistry. Springer, Cham, p 1

    Google Scholar 

  39. Lawrence MAW, Green KA, Nelson PN, Lorraine SC (2018) Polyhedron 143:11

    CAS  Google Scholar 

  40. Gorgas N, Kirchner K (2018) Acc Chem Res 51:1558

    CAS  PubMed  PubMed Central  Google Scholar 

  41. van Koten G (2019) NCN-pincer organometallics in bioorganometallic chemistry. Advances in bioorganometallic chemistry. Elsevier, Amsterdam, p 113. Chap 6

    Google Scholar 

  42. Valdes H, Rufino-Felipe E, Morales-Morales D (2019) J Organomet Chem:898

    Google Scholar 

  43. Alig L, Fritz M, Schneider S (2019) Chem Rev 119:2681

    CAS  PubMed  Google Scholar 

  44. Haque A, Xu LL, Al-Balushi RA, Al-Suti MK, Ilmi R, Guo ZL, Khan MS, Wong WY, Raithby PR (2019) Chem Soc Rev 48:5547

    CAS  PubMed  Google Scholar 

  45. Li J, Siegler M, Lutz M, Spek AL, Gebbink RJ, van Koten G (2010) Adv Synth Catal 352:2474

    CAS  Google Scholar 

  46. Bonnet S, van Lenthe JH, van Dam HJ, van Koten G, Gebbink RJ (2011) Dalton Trans 40:2542

    CAS  PubMed  Google Scholar 

  47. Gagliardo M, Snelders DJ, Chase PA, Gebbink RJ, van Klink GR, van Koten G (2007) Angew Chem Int Ed 46:8558

    CAS  Google Scholar 

  48. Kohl SW, Weiner L, Schwartsburd L, Konstantinovski L, Shimon LJ, Ben-David Y, Iron MA, Milstein D (2009) Science 324:74

    CAS  PubMed  Google Scholar 

  49. Kickham JE, Loeb SJ (1995) Inorg Chem 34:5656

    CAS  Google Scholar 

  50. Font M, Ribas X (2016) Pincerlike cyclic systems for unraveling fundamental coinage metal redox processes. Topics in organometallic chemistry. Springer, Cham, p 269

    Google Scholar 

  51. Casitas A, King AE, Parella T, Costas M, Stahl SS, Ribas X (2010) Chem Sci 1:326

    CAS  Google Scholar 

  52. Ribas X, Calle C, Poater A, Casitas A, Gomez L, Xifra R, Parella T, Benet-Buchholz J, Schweiger A, Mitrikas G, Sola M, Llobet A, Stack T (2010) J Am Chem Soc 132:12299

    CAS  PubMed  PubMed Central  Google Scholar 

  53. Lash TD, Chaney ST, Richter DT (1998) J Org Chem 63:9076

    CAS  Google Scholar 

  54. Darrow WT, Lash TD (2017) J Porphyrins Phtalocyanines 21:532

    CAS  Google Scholar 

  55. Lash TD, Yant VR (2009) Tetrahedron 65:9527

    CAS  Google Scholar 

  56. Stępień M, Latos-Grażyński L, Szterenberg L (2004) Inorg Chem 43:6654

    PubMed  Google Scholar 

  57. Lash TD, Toney AM, Castans KM, Ferrence GM (2013) J Org Chem 78:9143

    CAS  PubMed  Google Scholar 

  58. Fosu SC, Ferrence GM, Lash TD (2014) J Org Chem 79:11061

    CAS  PubMed  Google Scholar 

  59. Hung CH, Chang GF, Kumar A, Lin GF, Luo LY, Ching WM, Diau EWG (2008) Chem Commun:978

    Google Scholar 

  60. Chang GF, Kumar A, Ching WM, Chu HW, Hung CH (2009) Chem Asian J 4:164

    CAS  PubMed  Google Scholar 

  61. Chang GF, Wang CH, Lu HC, Kan LS, Chao I, Chen WH, Kumar A, Lo LY, dela Rosa MAC, Hung CH (2011) Chem A Eur J 17:11332

    CAS  Google Scholar 

  62. Huang CS, Li YL, Yang JE, Cheng N, Liu HB, Li YJ (2010) Chem Commun 46:3161

    CAS  Google Scholar 

  63. Singh K, Abebayehu A, Mulugeta E, Sareen D, Lee CH (2016) J Porphyr Phthalocyanines 20:21

    CAS  Google Scholar 

  64. Jeong SD, Nowak-Krol A, Kim Y, Kim SJ, Gryko DT, Lee CH (2010) Chem Commun 46:8737

    CAS  Google Scholar 

  65. Park D, Jeong SD, Ishida M, Lee CH (2014) Chem Commun 50:9277

    CAS  Google Scholar 

  66. Abebayehu A, Park D, Hwang S, Dutta R, Lee CH (2016) Dalton Trans 45:3093

    CAS  PubMed  Google Scholar 

  67. Jeong SD, Hong SJ, Park KJ, Ham S, Sessler JL, Lynch V, Lee CH (2007) J Org Chem 72:6232

    CAS  PubMed  Google Scholar 

  68. Brückner C, Akhigbe J, Samankumara LP (2014) Porphyrin analogs containing non-pyrrolic heterocycles. In: Kadish KM, Smith KM, Guilard R (eds) Handbook of porphyrin science: with applications to chemistry, physics, materials science, engineering, biology and medicine. World Scientific Publishing, Singapore, p 4. Chap 164

    Google Scholar 

  69. Lash TD, Pokharel K, Serling JM, Yant VR, Ferrence GM (2007) Org Lett 9:2863

    CAS  PubMed  Google Scholar 

  70. Berlin K, Breitmaier E (1994) Angew Chem Int Ed Engl 33:219

    Google Scholar 

  71. Sim EK, Jeong SD, Yoon DW, Hong SJ, Kang Y, Lee CH (2006) Org Lett 8:3355

    CAS  PubMed  Google Scholar 

  72. Szyszko B, Latos-Grażyński L (2015) Chem Soc Rev 44:3588

    CAS  PubMed  Google Scholar 

  73. Stępień M, Latos-Grażyński L (2003) Org Lett 5:3379

    PubMed  Google Scholar 

  74. Stępień M, Latos-Grażyński L (2003) Inorg Chem 42:6183

    PubMed  Google Scholar 

  75. Stępień M, Latos-Grażyński L, Szterenberg L (2007) J Org Chem 72:2259

    PubMed  Google Scholar 

  76. El-Beck JA, Lash TD (2006) Org Lett 8:5263

    CAS  PubMed  Google Scholar 

  77. Lash TD (1995) Angew Chem Int Ed Engl 34:2533

    CAS  Google Scholar 

  78. Richter DT, Lash TD (2001) Tetrahedron 57:3657

    CAS  Google Scholar 

  79. Stępień M, Latos-Grażyński L, Lash TD, Szterenberg L (2001) Inorg Chem 40:6892

    PubMed  Google Scholar 

  80. Lash TD, Szymanski JT, Ferrence GM (2007) J Org Chem 72:6481

    CAS  PubMed  Google Scholar 

  81. Szymanski JT, Lash TD (2003) Tetrahedron Lett 44:8613

    CAS  Google Scholar 

  82. Ryppa C, Niedzwiedzki D, Morozowich NL, Srikanth R, Zeller M, Frank HA, Bruckner C (2009) Chem A Eur J 15:5749

    CAS  Google Scholar 

  83. Kozyrev AN, Alderfer JL, Dougherty TJ, Pandey RK (1999) Angew Chem Int Ed 38:126

    CAS  Google Scholar 

  84. Toganoh M, Furuta H (2010) Synthesis and metal coordination of N-confused and N-fused porphyrinoids. In: Kadish KM, Smith KM, Guilard R (eds) Handbook of porphyrin science: with applications to chemistry, physics, materials science, engineering, biology and medicine. World Scientific Publishing, Singapore, p 295. Chap 8

    Google Scholar 

  85. Chmielewski PJ, Latos-Grażyński L (2005) Coord Chem Rev 249:2510

    CAS  Google Scholar 

  86. Pacholska-Dudziak E, Latos-Grażyński L (2007) Eur J Inorg Chem:2594

    Google Scholar 

  87. Ishizuka T, Ikeda S, Toganoh M, Yoshida I, Ishikawa Y, Osuka A, Furuta H (2008) Tetrahedron 64:4037

    CAS  Google Scholar 

  88. Toganoh M, Furuta H (2012) Chem Commun 48:937

    CAS  Google Scholar 

  89. Myśliborski R, Rachlewicz K, Latos-Grażyński L (2007) J Porphyrins Phtalocyanines 11:172

    Google Scholar 

  90. Lash TD, Young AM, Rasmussen JM, Ferrence GM (2011) J Org Chem 76:5636

    CAS  PubMed  Google Scholar 

  91. Lash TD, Rasmussen JM, Bergman KM, Colby DA (2004) Org Lett 6:549

    CAS  PubMed  Google Scholar 

  92. Adams KR, Bonnett R, Burke PJ, Salgado A, Valles MA (1993) J Chem Soc Chem Commun:1860

    Google Scholar 

  93. Adams KR, Bonnett R, Burke PJ, Salgado A, Valles MA (1997) J Chem Soc Perkin Trans:11769

    Google Scholar 

  94. Myśliborski R, Rachlewicz K, Latos-Grażyński L (2006) Inorg Chem 45:7828

    PubMed  Google Scholar 

  95. Ellis D, McKay D, Macgregor SA, Rosair GM, Welch AJ (2010) Angew Chem Int Ed 49:4943

    CAS  Google Scholar 

  96. Kaplan L, Wendling LA, Wilzbach KE (1971) J Am Chem Soc 93:3819

    CAS  Google Scholar 

  97. Krempner C, Reinke H, Wustrack R (2007) Inorg Chem Comm 10:239

    CAS  Google Scholar 

  98. Pope RM, VanOrden SL, Cooper BT, Buckner SW (1992) Organometallics 11:2001

    CAS  Google Scholar 

  99. Sattler A, Parkin G (2009) Nature 463:523

    Google Scholar 

  100. Hu S, Shima T, Hou Z (2014) Nature 512:413

    CAS  PubMed  Google Scholar 

  101. Kvaskoff D, Lueerssen H, Bednarek P, Wentrup C (2014) J Am Chem Soc 136:15203

    CAS  PubMed  Google Scholar 

  102. Jakoobi M, Sergeev AG (2019) Chem Asian J 14:2181

    CAS  PubMed  Google Scholar 

  103. Hicks J, Vasko P, Goicoechea JM, Aldridge S (2019) J Am Chem Soc 141:11000

    CAS  PubMed  Google Scholar 

  104. Zhang XX, Parks GF, Wayland BB (1997) J Am Chem Soc 119:7938

    CAS  Google Scholar 

  105. Hurej K (2017) PhD thesis, University of Wrocław

    Google Scholar 

  106. Frech CM, Shimon LJ, Milstein D (2007) Chem A Eur J 13:7501

    CAS  Google Scholar 

  107. Frech CM, Milstein D (2006) J Am Chem Soc 128:12434

    CAS  PubMed  Google Scholar 

  108. Gandelman M, Konstantinovski L, Rozenberg H, Milstein D (2003) Chem A Eur J 9:2595

    CAS  Google Scholar 

  109. Vigalok A, Rybtchinski B, Shimon LJW, Ben-David Y, Milstein D (1999) Organometallics 18:895

    CAS  Google Scholar 

  110. Chevrier B, Weiss R, Chottard JC, Lange M, Mansuy D (1981) J Am Chem Soc 103:2899

    CAS  Google Scholar 

  111. Szyszko B, Kupietz K, Szterenberg L, Latos-Grażyński L (2014) Chem A Eur J 20:1376

    CAS  Google Scholar 

  112. Stępień M, Latos-Grażyński L, Sprutta N, Chwalisz P, Szterenberg L (2007) Angew Chem Int Ed 46:7869

    Google Scholar 

  113. Stępień M, Szyszko B, Latos-Grażyński L (2010) J Am Chem Soc 132:3140

    PubMed  Google Scholar 

  114. Grzegorzek N, Pawlicki M, Szterenberg L, Latos-Grażyński L (2009) J Am Chem Soc 131:7224

    CAS  PubMed  Google Scholar 

  115. Pawlicki M, Kańska I, Latos-Grażyński L (2007) Inorg Chem 46:6575

    CAS  PubMed  Google Scholar 

  116. Stępień M, Sprutta N, Latos-Grażyński L (2011) Angew Chem Int Ed 50:4288

    Google Scholar 

  117. Singh R, Mukherjee A (2019) ACS Catal 9:3604

    CAS  Google Scholar 

  118. Che CM, Lo VKY, Zhou CY, Huang JS (2011) Chem Soc Rev 40:1950

    CAS  PubMed  Google Scholar 

  119. Niino T, Toganoh M, Andrioletti B, Furuta H (2006) Chem Commun:4335

    Google Scholar 

  120. Fields KB, Engle JT, Sripothongnak S, Kim C, Zhang XP, Ziegler CJ (2011) Chem Commun 47:749

    CAS  Google Scholar 

  121. Rachlewicz K, Wang SL, Ko JL, Hung CH, Latos-Grażyński L (2004) J Am Chem Soc 126:4420

    CAS  PubMed  Google Scholar 

  122. Pawlicki M, Latos-Grażyński L (2005) J Org Chem 70:9123

    CAS  PubMed  Google Scholar 

  123. Chmielewski MJ, Pawlicki M, Sprutta N, Szterenberg L, Latos-Grażyński L (2006) Inorg Chem 45:8664

    CAS  PubMed  Google Scholar 

  124. Pacholska-Dudziak E, Skonieczny J, Pawlicki M, Szterenberg L, Ciunik Z, Latos-Grażyński L (2008) J Am Chem Soc 130:6182

    CAS  PubMed  Google Scholar 

  125. Idec A, Pawlicki M, Latos-Grażyński L (2017) Inorg Chem 56:10337

    CAS  PubMed  Google Scholar 

  126. Grzegorzek N, Nojman E, Szterenberg L, Latos-Grażyński L (2013) Inorg Chem 52:2599

    CAS  PubMed  Google Scholar 

  127. Grocka I, Latos-Grażyński L, Stępień M (2013) Angew Chem Int Ed 52:1044

    CAS  Google Scholar 

  128. Białek MJ, Chmielewski PJ, Latos-Grażyński L (2019) Chem A Eur J 25:14536

    Google Scholar 

  129. Lash TD, Colby DA, Szczepura LF (2004) Inorg Chem 43:5258

    CAS  PubMed  Google Scholar 

  130. Szyszko B, Latos-Grażyński L (2011) Organometallics 30:4354

    CAS  Google Scholar 

  131. Szyszko B, Latos-Grażyński L, Szterenberg L (2012) Chem Commun 48:5004

    CAS  Google Scholar 

  132. Gao RX, AbuSalim DI, Lash TD (2017) J Org Chem 82:6680

    CAS  PubMed  Google Scholar 

  133. Szyszko B, Szterenberg L, Białońska A, Latos-Grażyński L (2015) Angew Chem Int Ed 54:4932

    CAS  Google Scholar 

  134. Myśliborski R, Latos-Grażyński L, Szterenberg L, Lis T (2006) Angew Chem Int Ed 45:3670

    Google Scholar 

  135. Carré FH, Corriu RJP, Bolin G, Moreau JJE, Vernhet C (1993) Organometallics 12:2478

    Google Scholar 

  136. Corriu RJP, Bolin G, Moreau JJE, Vernhet C (1991) J Chem Soc Chem Commun:211

    Google Scholar 

  137. Abebayehu A, Dutta R, Lee CH (2016) Chem A Eur J 22:13850

    CAS  Google Scholar 

  138. Jeong SD, Sessler JL, Lynch V, Lee CH (2008) J Am Chem Soc 130:390

    CAS  PubMed  Google Scholar 

  139. Sengupta R, Thorat KG, Ravikanth M (2018) J Org Chem 83:11794

    CAS  PubMed  Google Scholar 

  140. Brewster JT, He Q, Anguera G, Moore MD, Ke XS, Lynch VM, Sessler JL (2017) Chem Commun 53:4981

    CAS  Google Scholar 

  141. Brewster JT, Mangel DN, Gaunt AJ, Saunders DP, Zafar H, Lynch VM, Boreen MA, Garner ME, Goodwin CAP, Settineri NS, Arnold J, Sessler JL (2019) J Am Chem Soc 141:17867

    CAS  PubMed  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, University of Wrocław, Wrocław, Poland

    Karolina Hurej & Lechosław Latos-Grażyński

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  1. Karolina Hurej
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  2. Lechosław Latos-Grażyński
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Correspondence to Lechosław Latos-Grażyński .

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Editors and Affiliations

  1. Organic Chemistry & Catalysis, Utrecht University, Utrecht, The Netherlands

    Gerard van Koten

  2. Institute of Applied Synthetic Chemistry, Vienna University of Technology, Vienna, Austria

    Karl Kirchner

  3. Organic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, Utrecht, The Netherlands

    Marc-Etienne Moret

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Hurej, K., Latos-Grażyński, L. (2020). A Pincer Motif Etched into a meta-Benziporphyrin Frame. In: van Koten, G., Kirchner, K., Moret, ME. (eds) Metal-Ligand Co-operativity. Topics in Organometallic Chemistry, vol 68. Springer, Cham. https://doi.org/10.1007/3418_2020_61

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