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Rhodium Catalyzed Decarbonylation

  • Eduardo J. García-SuárezEmail author
  • Klara Kahr
  • Anders RiisagerEmail author
Chapter
  • 1.3k Downloads
Part of the Topics in Organometallic Chemistry book series (TOPORGAN, volume 61)

Abstract

Rhodium catalyzed decarbonylation has developed significantly over the last 50 years and resulted in a wide range of reported catalyst systems and reaction protocols. Besides experimental data, literature also includes mechanistic studies incorporating Hammett methods, analysis of kinetic isotope effects as well as computational studies of model systems, which give an indication of the scope of the process. In this chapter, fundamental applications of Rh-catalyzed decarbonylation reactions are surveyed and discussed, including cross-coupling reactions, tandem reactions, and alternative methodologies for process intensification.

Keywords

Aldehydes Aryl-aryl coupling Continuous-flow systems Cross-coupling Decarbonylation Heck coupling Ionic liquids Oppenauer oxidation Pauson–Khand Rhodium Sugars Tandem reaction 

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Copyright information

© Springer International Publishing AG 2017

Authors and Affiliations

  1. 1.Centre for Catalysis and Sustainable Chemistry, Department of ChemistryTechnical University of DenmarkLyngbyDenmark

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