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Nitrogen Fixation pp 215–234Cite as

Catalytic Transformations of Molecular Dinitrogen by Iron and Cobalt–Dinitrogen Complexes as Catalysts

Part of the Topics in Organometallic Chemistry book series (TOPORGAN,volume 60)

Abstract

This chapter describes the recent advances of the iron and cobalt-catalyzed transformations of molecular dinitrogen into not only silylamine but also ammonia and hydrazine under mild reaction conditions. In both reaction systems, reaction pathways are proposed based on the experimental and theoretical studies on iron and cobalt–dinitrogen complexes.

Keywords

  • Ammonia
  • Catalyst
  • Cobalt
  • Dinitrogen
  • Iron
  • Reduction
  • Silylamine

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Authors and Affiliations

  1. Department of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan

    Shogo Kuriyama & Yoshiaki Nishibayashi

Authors
  1. Shogo Kuriyama
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  2. Yoshiaki Nishibayashi
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Corresponding author

Correspondence to Yoshiaki Nishibayashi .

Editor information

Editors and Affiliations

  1. The University of Tokyo, Department of Systems Innovation, School of Engineering, Hongo, Tokyo, Japan

    Yoshiaki Nishibayashi

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Kuriyama, S., Nishibayashi, Y. (2017). Catalytic Transformations of Molecular Dinitrogen by Iron and Cobalt–Dinitrogen Complexes as Catalysts. In: Nishibayashi, Y. (eds) Nitrogen Fixation. Topics in Organometallic Chemistry, vol 60. Springer, Cham. https://doi.org/10.1007/3418_2016_5

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