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Evaluation of Supercritical Carbon Dioxide as a Tuneable Reaction Medium for Homogeneous Catalysis

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Book cover Regulated Systems for Multiphase Catalysis

Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 23))

Abstract

The present contribution highlights the relationship between scCO 2properties, its solubilization power, and its use as a reaction medium for homogeneous catalysis.Current research activities under the lighthouse project “Smart Solvents, Smart Ligands”are presented, the focus being on criteria of conducting catalyzed processes in future applications.

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Abbreviations

ρ:

Density

CESS:

Catalysis and extraction using supercritical solutions

cod:

1,5-cyclooctadiene

ConNeCat:

Competence network catalysis

EOS:

Equation of state

hfacac:

Hexafluoracetylacetonate

ISI:

ISI Web of Knowledge

p c :

Critical pressure

RTIL:

Room-temperature ionic liquid

S:

Selectivity (in Figs.)

S:

Substrate(s) (in tables)

sc:

Supercritical

scCO2 :

Supercritical carbon dioxide

SCF:

Supercritical fluid

Tc:

Critical temperature

TOF:

Turn-over frequency

XANTPHOS:

4,5-Bis-diphenylphosphanyl-9,9-dimethyl-9,9a-dihydro-4aH-xanthene

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Authors and Affiliations

  1. Institute for Technical Chemistry, Division of Chemical-Physical Processing (ITC-CPV), Forschungszentrum Karlsruhe GmbH, PO Box 3640, 76021, Karlsruhe, Germany

    Stephan Pitter, Eckhard Dinjus, Cezar Ionescu, Constantin Maniut, Piotr Makarczyk & Florian Patcas

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  1. Stephan Pitter
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  2. Eckhard Dinjus
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  3. Cezar Ionescu
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  4. Constantin Maniut
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  5. Piotr Makarczyk
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  6. Florian Patcas
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Correspondence to Stephan Pitter .

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Walter Leitner Markus Hölscher

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Pitter, S., Dinjus, E., Ionescu, C., Maniut, C., Makarczyk, P., Patcas, F. (2006). Evaluation of Supercritical Carbon Dioxide as a Tuneable Reaction Medium for Homogeneous Catalysis. In: Leitner, W., Hölscher, M. (eds) Regulated Systems for Multiphase Catalysis. Topics in Organometallic Chemistry, vol 23. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3418_041

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