Advertisement

Phase and structure behaviour of fluorinated nonionic surfactant systems

Conference paper
Part of the Progress in Colloid & Polymer Science book series (PROGCOLLOID, volume 73)

Abstract

“New Trends in Colliod Science” contains the proceedings of the foundation meeting of the European Colloid and Interface Society (ECIS), October 1–3, 1986. Representatives from the major European groups working in this field contributed to the conference. The volume contains an up-to-date account of present developments in Colloid Science. The contributions cover a wide scope of subjects, and provide encouragement that structures and transport processes in dense colloidal systems can be understood on basic principles. The main subjects are include:
  • phase diagrams of new surfactant systems

  • microemulsions and their applications

  • vesicles and bilayers

  • transport properties of colloidal systems.

Abstract

The phase behaviour of many (apolar and aqueous) binary and ternary systems with series of polyoxyethylene perfluoroalcohols are presented. Emphasis is put on their relation to the structures of the micellar and microemulsion aggregates. The influence of the fluorocarbon tail on the hydrophily properties of the EO chain is discussed, as compared to hydrogenated compounds, whether aqueous binaryor ternary systems are concerned. In particular, the evolution of the L2 and L3 phases is studied as a function of the chemical composition of the surfactant, bringing out the enhanced stability of lamellar liquid crystals.

Key words

Fluorinated surfactants nonionic surfactants microemulsions micelles phase diagram 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Ravey JC, Stébé M-J, Oberthur R (1987) In: Mittal KL, Bothorell P (eds) Surfactants in Solution, Plenum Press, New York 6:1421–1430Google Scholar
  2. 2.
    Ravey JC, Stébé MJ (1986) In: Mittal KL (ed) Proceedings of 6th International Symposium on Surfactants in Solution, New Dehli, Inde, submitted for publicationGoogle Scholar
  3. 3.
    Mathis G, Leempoel P, Ravey JC, Selve C, Delpuech JJ (1984) J Am Chem Soc 106:6162–6171CrossRefGoogle Scholar
  4. 4.
    Mathis G (1982) Thesis University of Nancy I, FranceGoogle Scholar
  5. 5.
    Mathis G, Ravey JC, Buzier M (1982) In: Robb ID (ed) Microemulsions, Plenum Press, New York 85–102Google Scholar
  6. 6.
    Ravey JC, Buzier M, Picot C (1984) J Coll Interf Sci 97:9–25CrossRefGoogle Scholar
  7. 7.
    Ravey JC, Buzier M, Dupont G (1987) In: Rosano H, Dekker M (ed) Microemulsions, Surfactant Science Series, New York 24:163–182Google Scholar
  8. 8.
    Ravey JC, Buzier M (1984) In: Shah O (ed) Emulsion and Microemulsion, ACS Symposium Series 272, American Chemical Society, Washington 253–263Google Scholar
  9. 9.
    Nilsson PG, Lindman BJ (1982) Phys Chem 86:271–279CrossRefGoogle Scholar
  10. 10.
    Selve C, Castro B, Leempoel P, Mathis G, Gartiser T, Delpuech JJ (1983) Tetrahedron 39:1313–1316CrossRefGoogle Scholar
  11. 11.
    Gartiser T, Selve C, Mansuy L, Robert A, Delpuech JJ (1984) Chem Res (S) 292–293Google Scholar
  12. 12.
    Ravey JC, Buzier M (1984) In: Mittal KL, Lindman B (eds) Surfactants in Solutions, Plenum Press, New York 3:1759–1779Google Scholar
  13. 13.
    Baxter RJ (1968) J Chem Phys 49:2770–2774CrossRefGoogle Scholar
  14. 14.
    Mitchell DJ, Tiddy GJT, Waring L, Bostock T, McDonald MP (1983) J Chem Soc, Faraday Trans 1, 79:975–1000Google Scholar
  15. 15.
    Shinoda K, Masakatsu H, Hayaski T (1972) J Phys Chem 76:909–914CrossRefGoogle Scholar
  16. 16.
    Kunieda H, Shinoda K (1976) J Phys Chem 80:2468–2470CrossRefGoogle Scholar
  17. 17.
    Shinoda K (1974) Principles of Solution and Solubility, Dekker M, Inc, New YorkGoogle Scholar
  18. 18.
    Becher P (1967) In: Schick MJ (ed) Nonionic Surfactants, M Dekker Inc, New York 478–515Google Scholar
  19. 19.
    Ravey J-C (1983) Coll Interf Sci 94:289–291CrossRefGoogle Scholar
  20. 20.
    Ravey J-C, Stébé M-J, Oberthur R, to be publishedGoogle Scholar
  21. 21.
    Stébé M-J, Serratrice G, Delpuech J-J (1985) J Phys Chem 89:2837–2843CrossRefGoogle Scholar
  22. 22.
    Shinoda K, Kunieda H (1977) In: Prince LM (ed) Microemulsions, Theory and Practice, Academic Press 57–89Google Scholar
  23. 23.
    Friberg S, Buraczewska I, Ravey J-C (1977) In: Mittal KL (ed) Micellization Solubilization and Microemulsions, Plenum Press, New York 2:901–911Google Scholar
  24. 24.
    Stébé M-J, Serratrice G, Ravey J-C, Delpuech J-J (19??) In: Mittal KL, Bothrel P (eds) Surfactants in Solution, Plenum Press, New York, in pressGoogle Scholar
  25. 25.
    Kunieda H, Shinoda K (1982) J Dispersion Sci and Techn 3:233–244CrossRefGoogle Scholar
  26. 26.
    Robert A, Tondre C (1984) J Coll Interf Sci 98:515–522Google Scholar
  27. 27.
    Buzier M (1984) Thesis University of Nancy I, FranceGoogle Scholar
  28. 28.
    Ravey J-C, Buzier M (1986) In: Mittal KL (ed) Proceedings of 6th International Symposium on Surfactants in Solution, New Dehli, Inde, submitted for publicationGoogle Scholar
  29. 29.
    Bostock TA, McDonald MP, Tiddy GJT (1984) In: Mittal KL, Lindman B (eds) Surfactants in Solution, Plenum Press, New York 3:1805–1820Google Scholar
  30. 30.
    Zulauf M, Weckstrom K, Hayter JB, Degiorgio V, Corti M (1985) J Phys Chem 89:3411–3417CrossRefGoogle Scholar

Copyright information

© Dr. Dietrich Steinkopff Verlag GmbH & Co. KG 1987

Authors and Affiliations

  1. 1.Laboratoire de Physico-Chimie des Colloides UA 406 CNRS LESOCUniversité de Nancy I Faculte des SciencesVandoeuvre-lès-Nancy CedexFrance

Personalised recommendations