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Alkene Metathesis in Organic Synthesis pp 155–181Cite as

Cross-Metathesis

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Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 1))

Abstract

During the past 4 years the transition metal catalysed alkene cross-metathesis reaction has enjoyed increasing attention from organic chemists as a method for carbon-carbon bond formation. The impetus behind this was undoubtedly the development of well-defined functional group tolerant molybdenum and ruthenium alkylidene catalysts by Schrock and Grubbs respectively. In light of these recent advances, we review herein the cross-metathesis reactions of functionalised alkenes catalysed by well-defined metal carbene complexes. Acyclic cross-metathesis reactions are presented in a chronological order and are accompanied by discussion of mechanistic and selectivity issues. The formation of monomeric products from the related ring-opening cross-metathesis reaction is also covered and presented similarly.

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Authors
  1. Susan E. Gibson
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  2. Stephen P. Keen
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Editor information

Editors and Affiliations

  1. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470, Mülheim an der Ruhr, Germany

    Alois Fürstner

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© 1998 Springer-Verlag Berlin Heidelberg

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Gibson, S.E., Keen, S.P. (1998). Cross-Metathesis. In: Fürstner, A. (eds) Alkene Metathesis in Organic Synthesis. Topics in Organometallic Chemistry, vol 1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-69708-X_6

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  • DOI: https://doi.org/10.1007/3-540-69708-X_6

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-64254-1

  • Online ISBN: 978-3-540-69708-4

  • eBook Packages: Springer Book Archive

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