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Design and Construction of Supramolecular Architectures Consisting of Cyclodextrins and Polymers

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Book cover Metal Complex Catalysts Supercritical Fluid Polymerization Supramolecular Architecture

Part of the book series: Advances in Polymer Science ((POLYMER,volume 133))

Abstract

Cyclodextrins (CDs) interact with various polymers of high specificity to give crystalline inclusion complexes in which CD molecules are threaded by a polymer chain. For example, α-CD forms such complexes with poly(ethylene glycol) (PEG) when the PEG molecular weight is higher than 200, but β-CD does not. On the other hand, for poly(propylene glycol) (PPG), the reverse is the case. Although both α and β-CD fail, γ-CD complexes with poly(methyl vinyl ether) (PMVE). In addition, α and γ-CD complex with oligo(ethylene) (OE) and poly(isobutylene) (PIB), respectively. Three quarters of the present paper describe the synthesis, structure, and properties of these CD-polymer inclusion complexes. The remaining part is concerned with rotaxanes including polyrotaxanes and also catenanes. A particularly detailed description is made concerning the work of the author and his coworkers which led to the synthesis of polyrotaxanes consisting of α-CD and PEG and the making of molecular tubes from them. It is expected that such tubes may find many useful applications in chemistry and biology.

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  1. Department of Macromolecular Science, Faculty of Science, Osaka University, Toyonaka, Osaka, 560, Japan

    Akira Harada

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  1. Akira Harada
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D. A. Canelas J. M. DeSimone A. Harada E. Ihara K. Mashima A. Nakamura Y. Nakayama H. Yasuda

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Harada, A. (1997). Design and Construction of Supramolecular Architectures Consisting of Cyclodextrins and Polymers. In: Canelas, D.A., et al. Metal Complex Catalysts Supercritical Fluid Polymerization Supramolecular Architecture. Advances in Polymer Science, vol 133. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-68442-5_4

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  • DOI: https://doi.org/10.1007/3-540-68442-5_4

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