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PVA-Iodine complexes: Formation, structure, and properties

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Structure in Polymers with Special Properties

Part of the book series: Advances in Polymer Science ((POLYMER,volume 108))

Abstract

The PVA-Iodine complexes formed in PVA films soaked in iodine-KI aqueous solutions without boric acid are studied from the structural point of view. First, iodine soaking at comparatively low iodine concentrations is studied where iodine sorption takes place mostly in the amorphous phase. There, our interest is concentrated on the following problems: What happens in PVA films during iodine soaking? How does the solid structure of PVA films affect the formation and properties of the complex? How does the chain extension affect the complex formation and properties? What is the structure of the complex formed in the amorphous phase? Then iodine soaking at high iodine concentrations is studied where iodine sorption takes place in the crystal phase as well as in the amorphous phase.

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Authors and Affiliations

  1. Department of Organic and Polymeric Materials, Tokyo Institute of Technology, Meguro-ku, 152, Tokyo, Japan

    Keizo Miyasaka

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  1. Keizo Miyasaka
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H. -G. Zachmann

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© 1993 Springer-Verlag

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Miyasaka, K. (1993). PVA-Iodine complexes: Formation, structure, and properties. In: Zachmann, H.G. (eds) Structure in Polymers with Special Properties. Advances in Polymer Science, vol 108. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-56579-5_3

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  • DOI: https://doi.org/10.1007/3-540-56579-5_3

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-56579-6

  • Online ISBN: 978-3-540-47594-1

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