Abstract
Many photoimaging technologies involve electron-transfer processes in the critical image capture, or light-sensitive, step of the process. This chapter reviews the photochemical and photophysical basis for these processes. The chapter is divided into several major sections: an introduction to basic imaging concepts; a brief discussion of the chemistries and photochemistries involved in conventional silver halide based imaging processes and those involving other semiconductors as primary light absorbers; and sections describing less conventional processes that are based on organic photochemical charge transfer processes (electrophotography, color formation systems, and photopolymerization processes).
This is a preview of subscription content, log in via an institution.
Preview
Unable to display preview. Download preview PDF.
References
Mattes S, Farid S (1984) Science 226: 917
Mattes S, Farid S (1983) in: Padwa A (ed) Organic Photochemistry. Marcel Dekker, New York
Kirmaier C, Holten D (1987) Photosynthesis 13: 225
Govindjee (1982) Photosynthesis: Energy conversion by plants and bacteria. Academic, New York
Deisenhofer J, Epp O, Miki K, Huber R, Michel H (1985) Nature 318: 618
Michel H. Deisenhoffer J (1987) in: Biggins J (ed) Progress in Photosynthesis Research. Martinus Nijhoff, Boston
Cohen SG, Parola A, Parson Jr AJ (1973) Chem. Rev. 73: 141
Roth HD, Schilling MLM (1979) J. Am. Chem. Soc. 101: 1898
Majima T, Pac C, Sakurai H (1979) Chem. Lett. 1133
Wong PC, Arnold DR (1979) Tet. Letts. 2101
Murov SL, Cole RS, Hammond GS (1968) J. Am. Chem. Soc. 90: 2957
Roth HD, Schilling MLM, Jones IIG (1981) J. Am. Chem. Soc. 103: 1246
Evans TR, Wake RW, Sifain MM (1973) Tet. Letts. 701
Foote CS, Ericksen J (1980) J. Am. Chem. Soc. 102: 6083
Schaap AP, Zaklika KA, Kaskar B, Fung LWM (1980) J. Am. Chem. Soc. 102: 389
Mattes SL, Farid S (1980) J. Chem. Soc. Chem. Commun. 457
Brinkman E, Delzenne G, Poot A, Willems J (1978) Unconventional Imaging Processes. Focal Press, London
Jacobson KI, Jacobson RE (1976) Imaging Systems. Wiley, New York
James TH (ed) (1977) The theory of the photographic process, Macmillan, New York
Haist G (1979) Modern photographic processing. Wiley, New York
Meier H (1968) Spectral sensitization, Focal Press, New York
Vogel WH (1873) Ber. dtsch. chem. Ges. 6: 1302
Becquerel C (1874) Compte Rend. Hebd. Séances Acad. Sci. 79: 185
Gurney RW, Mott N (1938) Proc. Roy. Soc. (London) Ser. A 164: 151
Gilman PB (1974) Photog. Sci. Engg. 18: 475
Costa L F, Gilman PB (1975) Photog. Sci. Engg. 19: 207
Penner TL, Gilman PB (1975) Photog. Sci. Engg. 19: 102
Carroll BH (1977) Photog. Sci. Engg. 21: 151
Kuhn H, Mobius D (1971) Angew. Chem., Int. Ed. 10: 620
v Szentpaly L, Mobius D, Kuhn H (1970) J. Chem. Phys. 52: 4618
McLeod GJ (1969) Photog. Sci. Engg. 13: 93
DeLorenzo EJ, Case LK, Stickles EM, Stamoulis WA (1969) Photog. Sci. Engg. 13: 95
Lehner H (1969) Photog. Sci. Engg. 13: 103
Addiss Jr RR, Wakim FG (1969) Photog. Sci. Engg. 13: 111
Vohl P (1969) Photog. Sci. Engg. 13: 120
Kraeutler B, Bard AJ (1978) J. Am. Chem. Soc. 100: 2239
Lehn JM, Sauvage JP (1980) Nouv. J. Chim. 4: 623
Kalyanasundaram K, Borgarello E, Gratzel M (1981) Helv. Chim. Acta 64: 362
Hada H, Tanemura H, Yonezawa Y (1978) Bull. Chem. Soc. Japan 51: 3154
Eaton DF (1981) US Patent 4, 257, 915 Photopolymer initiating system containing a semiconductor, a reducing agent, and an oxidizing agent
Eaton DF (1984) Pure Appl. Chem. 56: 1191
Neta P, Behar D (1980) J. Am. Chem. Soc. 102: 4798
Neta P, Behar D (1981) J. Phys. Chem. 85: 690
Masuda H, Shimidzu N, Ohno S (1984) Chem. Letts. 1701
Brinkman EM (1971) Proc 3rd Symp. Society of Photographic Scientists and Engineers on Unconventional Photographic Systems, Oct 20–23, 1971, Washington DC, p 13
Levy B, Lindsey M (1972) Photog. Sci. Engg. 16: 389
Levy B, Lindsey M (1973) Photog. Sci. Engg. 17: 135, 423
Carlson CF (1942) US Patent 2, 297, 691 Electrophotography
Carlson CF (1965) in: Dessauer JH, Clark HE (eds) Xerography and related processes. Focal Press, New York (historical introduction to the invention of xerography)
Scharfe ME, Pai DM, Gruber RJ (1989) in: Sturge JM, Walrath V, Shepp A (eds) Imaging processes and materials, Neblette's Eighth Edition, Van Nostrand Reinhold, New York, p 135
Schaffer RL (1975) Electrophotography Focal Press, New York
Pfister G (1984) La Researche 16: 204
Gill WD (1972) J. Appl. Phys. 43: 5052
Melz PJ (1972) J. Chem. Phys. 57: 1694
Goliber TE, Perlstein JH (1982) Photogr. Sci. Engg. 26: 236
Dulmage WJ, Light WA, Marino SJ, Salzberger CD, Smith DL, Studenmeyer (1978) J. Appl. Phys. 49: 5543
Borsenberger PM, Chowdry A, Hoesterey DC, May W (1978) J. Appl. Phys. 49: 5555
Light WA (1971) US Patent 3, 615, 414 Photoconductive compositions and elements and method of preparation
Terenin A (1961) Proc. Chem. Soc. 321
Heilmeir GH, Warfield G (1963) J. Chem. Phys. 38: 163, 897
Bornmann J (1957) J. Chem. Phys. 27: 604
Loutfy RO, Hor AM, Di Paola-Baranyl G, Hsiao CK (1985) J. Imag. Sci. 29: 116: 148
Schlosser G (1978) J. Appl. Photogr. Eng. 4: 118
Loutfy RO, Hsiao CK, Kazmeier G (1983) Photogr. Sci. Engg. 27: 5
Khe NC, Takenouchi T, Kawara T, Tanaka H, Yokada S (1984) Photogr. Sci. Engg. 28: 195
Law KY (1987) J. Phys. Chem. 91: 5184
Law KY (1987) J. Imag. Sci. 31: 172
Mort J, Pflister G, (1978) Polym. Technol. 12: 89
Andrievsky AM (1985) Elektron. Org. Mater. 256 (in Russian)
US Patent 4, 474, 865 (1988) Layered photoresponsive device having electron transport layer containing derivatives of fluorenylidene methane (Xerox Corp.)
Loutfy RO, Ong SS, Tadros J (1985) J. Imag. Sci. 29: 69
Kruder JE, Limburg WW, Pochan J M, Wychick D (1977) J. Chem. Soc., Perkin Trans. II: 1643
Melz PJ, Champ RB, Chang LS, Chiou C, Keller GS, Liclican LC, Nelman RR, Schattuck MD (1977) Photogr. Sci. Engg. 21: 73
Baltazzi ES (1980) J. Appl. Photogr. Engg. 6: 147
Schlosser G (1978) J. Appl. Photogr. Engg. 4: 118
Dessauer R, Looney CE (1989) in: Sturge JM, Walrath V, Shepp A (eds) Imaging processes and materials, Neblette's Eighth Edition, Van Nostrand Reinhold, New York, p 263
Sprague RH, Fletcher HL, Wainer E (1961) Photgr. Sci. Engg. 5: 98
Stevenson DP, Coppinger GM (1962) J. Amer. Chem. Soc. 84: 149
MacLachlan A (1967) J. Phys. Chem. 71: 718
Cescon LA, Coraor GR, Dessauer R, Silversmith EF, Urban EJ (1971) J. Org. Chem. 36: 2262
Cescon LA, Coraor GR, Dessauer R, Deutsch AS, Jackson HL, MacLachlan A, Marcali K, Potrafke EM, Read RE, Silversmith EF, Urban EJ (1971) J. Org. Chem. 36: 2267
Looney CE, Gordon MD, Laird JP, James EW (1972) Photogr. Sci. Engg. 16: 433
Cohen RL (1971) J. Org. Chem. 36: 2280
DoMinh T (1981) US Patent 4, 308, 341, Non-silver Imaging Compositions Having Improved Speeds and Processing Temperature (Eastman Kodak); also US 4, 243, 737
DoMinh T (1977) J. Org. Chem. 42: 4217
Ledwith A, Purbrick MD (1973) Polymer 14: 521
Davidson RS, Lambeth PF (1967) J. Chem. Soc., Chem. Commun. 1265
Cohen SG, Baumgarten RJ (1967) J. Amer. Chem. Soc. 89: 3471
Osborne CL (1976) J. Radiat. Curing 2 (July)
Chang CT (E. I du Pont de Nemours & Co., Imaging Systems Department), personal communication
Eaton DF, unpublished results for a photopolymer composition containing 5 wt% initiator, 35 wt% difunctional acrylate monomer, and a polymethacrylate binder. The composition was washed out after exposure to ultraviolet light through a step wedge; that is, the photopolymer functioned as a negative resist
Hammond GS, Wamser CC, Chang CT, Baylor C (1970) J. Amer. Chem. Soc. 92: 6362
Cohen AB, Walker P (1989) in: Sturge JM, Walrath V, Shepp A (eds) Imaging Processes and Materials, Neblette's Eighth Edition, Van Nostrand Reinhold, New York, p 226
Eaton DF, Gaffney AP, Horgan JP (1975) unpublished observations
Crivello JV, Lam JHW (1977) Macromol. 10: 1307
Pappas SP (1985) J. Imag. Technol. 11: 146
De Voe RJ, Sahyun MRV, Schmidt E (1989) J. Imaging Sci. 33: 39
Tilley M, Pappas B, Pappas SP, Yagci Y, Schnabel W, Thomas JK (1989) J. Imaging Sci. 33: 62
Eaton DF (1986) Adv. Photochem. 13: 427
Chen C (1965) J. Polym. Sci., A 3: 1107, 1127, 1137, 1155
Miller RJ, Margerum JD, Rust JB, Brault RG, Lackner AM (1974) Macromol. 7: 179
Delzenne GA, Laridon UL (1971) US Patent 3, 597, 343 (Agfa Gevaert)
Chaberek S, Allen RJ, Goldberg G (1965) J. Phys. Chem. 69: 2834
Eaton DF (1979) Photogr. Sci. Engg. 23: 150
Eaton DF (1981) J. Amer. Chem. Soc. 103: 7235
Sanders FW (1983) US Patent 4, 399, 203 (Mead Corp)
Gottschalk P, Neckers DC, Schuster GB (1988) US Patent 4, 772, 530 (Mead Corp)
Diamond AS (1985) Electron. Imaging (October), 35
Arney J (1987) J. Imag. Sci. 31: 27
Arney J (1989) J. Imag. Sci. 33: 1
See Chemical and Engineering News (1988) January 11, p 23 for a description of this interesting system
Chatterjee S, Gottschalk P, Davis PD, Schuster GB (1988) J. Amer. Chem. Soc., 110: 2326
Lan JY, Schuster GB (1985) J. Amer. Chem. Soc. 107: 6710
Lan JY, Schuster GB (1986) Tet. Letts. 27: 4261
Author information
Authors and Affiliations
Editor information
Rights and permissions
Copyright information
© 1990 Springer-Verlag
About this paper
Cite this paper
Eaton, D.F. (1990). Electron transfer processes in imaging. In: Mattay, J. (eds) Photoinduced Electron Transfer I. Topics in Current Chemistry, vol 156. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-52379-0_7
Download citation
DOI: https://doi.org/10.1007/3-540-52379-0_7
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-540-52379-6
Online ISBN: 978-3-540-46976-6
eBook Packages: Springer Book Archive