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Photoinduced electron transfer polymerization

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Photoinduced Electron Transfer I

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 156))

Abstract

To start polymerization, reactive species which are capable of inducing the spontaneous polymerization of corresponding monomers are necessary. Photoinduced electron transfer can be used in a broad manner for that purpose. The focus of the present review is primarily directed to systems producing neutral or ion radicals, and cations or Lewis acids. Such species are the final products of a photoinduced electron transfer process either between neutral donors and neutral acceptors, or between neutral donors and positively charged acceptors. Among the numerous classes of compounds, monomers bearing electron-repelling or electron-accepting substituents can be involved in the electron transfer process. Very often, the electron transfer takes place between non-polymerizing compounds resulting in initiating species. Sometimes in such cases, the monomer molecules have a detrimental effect on the efficiency of polymerization initiation due to several quenching processes. Also, the termination steps can be influenced through the products of photoinduced electron transfer.

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Timpe, HJ. (1990). Photoinduced electron transfer polymerization. In: Mattay, J. (eds) Photoinduced Electron Transfer I. Topics in Current Chemistry, vol 156. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-52379-0_6

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