Oxidations and Rearrangements

  • Thomas Wirth
Chapter
Part of the Topics in Current Chemistry book series (TOPCURRCHEM, volume 224)

Abstract

Oxidations and rearrangements using hypervalent iodine compounds are summarized in this review with emphasis on synthetic applications of these procedures. New reagents and polymer-supported versions are highlighted which facilitate the use of hypervalent iodine compounds in these reactions. Beside the more traditional oxidation of sulfides to sulfoxides and of alcohols to the corresponding ketones, the functionalization of activated carbon-hydrogen bonds in the oxidation in carbonyl compounds and the functionalization of only slightly activated carbon-hydrogen bonds in benzylic positions are discussed. New rearrangements using hypervalent iodine compounds are finally mentioned.

Keywords

Hypervalent iodine Oxidation Polymer-supported reagents Rearrangement 

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Copyright information

© Springer-Verlag Berlin Heidelberg 2003

Authors and Affiliations

  • Thomas Wirth
    • 1
  1. 1.Department of ChemistryCardiff UniversityCardiffUK

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