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The Synthesis and Structural Properties of Aluminium Oxide, Hydroxide and Organooxide Compounds

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Group 13 Chemistry III

Part of the book series: Structure and Bonding ((STRUCTURE,volume 105))

Abstract

By virtue of the oxophilicity of aluminium, many compounds exist in which at least one of the metal’s formal valencies is occupied by oxygen or, alternatively, where the coordination state of the metal is raised to 4, 5 or 6 by the donation of electron density from oxygen. This review presents aluminium oxides first and thereafter aluminium hydroxides and organooxides. Although the discussion concentrates on the solid-state structural properties of such systems, solution structural, theoretical and reactivity studies are also presented.

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  1. Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, UK

    David J. Linton & Andrew E. H. Wheatley

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  1. Institut für Anorganische Chemie der Universität Göttingen, Tammannstr. 4, 37077, Göttingen, Germany

    Herbert W. Roesky

  2. Department of Chemistry, University of Kentucky, Lexington, Kentucky, 40506 0055, USA

    David A. Atwood

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Linton, D.J., Wheatley, A.E.H. (2003). The Synthesis and Structural Properties of Aluminium Oxide, Hydroxide and Organooxide Compounds. In: Roesky, H.W., Atwood, D.A. (eds) Group 13 Chemistry III. Structure and Bonding, vol 105. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-46110-8_3

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