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Thermodiffusion in Ionic Solids —Model Experiments and Theory

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Thermal Nonequilibrium Phenomena in Fluid Mixtures

Part of the book series: Lecture Notes in Physics ((LNP,volume 584))

Abstract

The current state of theory and experimental work on thermotransport (diffusion in a temperature gradient) in solids and the heat of transport is reviewed and the results of the authors’ own studies are summarized. Results from molecular dynamical simulations of vacancy migration in solid noble gases suggest that the heat of transport is temperature dependent and that it differs substantially from the migration enthalpy of the mobile point defect, in disagreement with some pre-existing models. Experimental results on mixed conducting solids support the theoretical results. The difficulties of thermal diffusion experiments are analysed, and possible experimental strategies are discussed.

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Author information

Authors and Affiliations

  1. Physikalisch-Chemisches Institut der Justus-Liebig-Universität Gieβen, Heinrich-Buff-Ring 58, 35392, Gieβen, Germany

    Jürgen Janek & Carsten Korte

  2. The J.J. Thomson Physical Laboratory, University of Reading, Whiteknights, RG6 6AF, Reading, UK

    Alan B. Lidiard

Authors
  1. Jürgen Janek
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  2. Carsten Korte
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  3. Alan B. Lidiard
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Editors and Affiliations

  1. Physikalisches Institut, Universiät Bayreuth, 95440, Bayreuth, Germany

    Werner Köhler

  2. Max-Planck-Institut für Polymerforschung, Ackermannweg 10, 55128, Mainz, Germany

    Simone Wiegand

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Janek, J., Korte, C., Lidiard, A.B. (2002). Thermodiffusion in Ionic Solids —Model Experiments and Theory. In: Köhler, W., Wiegand, S. (eds) Thermal Nonequilibrium Phenomena in Fluid Mixtures. Lecture Notes in Physics, vol 584. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-45791-7_8

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  • DOI: https://doi.org/10.1007/3-540-45791-7_8

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