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Fluoroaluminate Chemistry

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Group 13 Chemistry II

Part of the book series: Structure and Bonding ((STRUCTURE,volume 104))

Abstract

Salts of the tetrafluoroaluminate (TFA) anion have been known for many years. Yet aqueous routes to pure materials have not been established despite the substantial amount of literature available on the subject. The present review will discuss the various synthetic methods that have been employed and will demonstrate a revised method for preparing pure TFA salts. These materials are important because TFA is able to stimulate various guanosine nucleotide-binding proteins (G-proteins) and inhibit P-type ATPases by serving as a non-hydrolyzing phosphate mimic. Additionally, various TFA salts serve as precursors to aluminum trifluoride, which is used as a catalyst for chlorofluorocarbon isomerizations and fluorinations.

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Author information

Authors and Affiliations

  1. Department of Chemistry, University of Kentucky, Lexington, KY, 40506, USA

    B. Conley & D. A. Atwood

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  1. B. Conley
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  2. D. A. Atwood
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Editors and Affiliations

  1. Institut für Anorganische Chemie der Universität Göttingen, Tammannstr. 4, 37077, Göttingen, Germany

    Herbert W. Roesky

  2. Department of Chemistry, University of Kentucky, Lexington, Kentucky, 40506 0055, USA

    David A. Atwood

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© 2002 Springer-Verlag Berlin Heidelberg

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Conley, B., Atwood, D.A. (2002). Fluoroaluminate Chemistry. In: Roesky, H.W., Atwood, D.A. (eds) Group 13 Chemistry II. Structure and Bonding, vol 104. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-45425-X_6

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  • DOI: https://doi.org/10.1007/3-540-45425-X_6

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-43807-6

  • Online ISBN: 978-3-540-45425-0

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