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Structure and dynamics of polymer-like reverse micelles

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Surface and Colloid Science

Part of the book series: Progress in Colloid and Polymer Science ((PROGCOLLOID,volume 116))

Abstract

We present pulsed-field-gradient NMR and time-resolved small-angle neutron scattering experimental data to bear out the polymer-like nature of long, flexible micelles in the lecithin—water—cyclohexane system. The molecular transport of lecithin is described in terms of curvilinear lateral diffusion along the contour length of unbranched entangled cylindrical micelles. Moreover, an isotropic-to-nematic phase transition is induced under shear, characterized by a certain degree of alignment of the micelles. As a final result the lecithin micelles appear to be more polymer-like than wormlike micellar systems in general.

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Author information

Authors and Affiliations

  1. DISTAAM, Università del Molise v. De Sanctis, 86100, Campobasso, Italy

    R. Angelico, L. Ambrosone & A. Ceglie

  2. Dipartimento di Chimica, Università di Bari, v. Orabona 4, 70126, Bari, Italy

    G. Palazzo

  3. Condensed Matter Physics and Chemistry Department, Risø National Laboratory, 4000, Roskilde, Denmark

    K. Mortensen

  4. Physical Chemistry 1, Center for Chemistry and Chemical Engineering, Lund University, P.O. Box 124, 22100, Lund, Sweden

    U. Olsson

Authors
  1. R. Angelico
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  2. L. Ambrosone
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  3. A. Ceglie
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  4. G. Palazzo
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  5. K. Mortensen
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  6. U. Olsson
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Editor information

Valdemaras Razumas Björn Lindman Tommy Nylander

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© 2000 Springer-Verlag

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Angelico, R., Ambrosone, L., Ceglie, A., Palazzo, G., Mortensen, K., Olsson, U. (2000). Structure and dynamics of polymer-like reverse micelles. In: Razumas, V., Lindman, B., Nylander, T. (eds) Surface and Colloid Science. Progress in Colloid and Polymer Science, vol 116. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-44941-8_7

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  • DOI: https://doi.org/10.1007/3-540-44941-8_7

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-67814-4

  • Online ISBN: 978-3-540-44941-6

  • eBook Packages: Springer Book Archive

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