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Nanocasting and Nanocoating

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Colloid Chemistry I

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 226))

Abstract

The use of organic templates for the controlled structuring of inorganic materials is being widely explored. Two processes, nanocasting and nanocoating, will be discussed in this chapter for the formation of porous metal oxide structures with an emphasis on silica and titania. The difference between the two techniques is that casting is a filling of the porous structure of the organic material whereas coating results in a layer of the inorganic substance on the polymer structure. Following formation of the hybrid, the organic template can be removed, yielding a structured inorganic material. Either an inverse replica of the initial structure is obtained after nanocasting or a hollow replica of the organic results with the nanocoating procedure. The initial organic molds considered here are “rigid”, preformed matrices or discrete entities that do not require the presence of the inorganic material for producing or maintaining their structure. These range from monolithic materials, including porous polymer gels and colloidal crystals, to organic fibers, crystals, and latex particles. The fabrication methods discussed that are used to obtain the metal oxide structures include sol-gel procedures and the use of preformed metal oxide nanoparticles.

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Authors and Affiliations

  1. School of Chemistry, The University of Melbourne, Victoria, 3010, Australia

    Rachel A. Caruso

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  1. Rachel A. Caruso
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Editors and Affiliations

  1. Max Planck Institute of Colloids and Interfaces, 14424, Potsdam, Germany

    Markus Antonietti

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© 2003 Springer-Verlag Berlin Heidelberg

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Caruso, R.A. (2003). Nanocasting and Nanocoating. In: Antonietti, M. (eds) Colloid Chemistry I. Topics in Current Chemistry, vol 226. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-36408-0_4

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  • DOI: https://doi.org/10.1007/3-540-36408-0_4

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-00415-8

  • Online ISBN: 978-3-540-36408-5

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