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Beyond Electrons in a Box: Nanoparticles of Silver, Platinum and Rhodium

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Book cover Novel NMR and EPR techniques

Part of the book series: Lecture Notes in Physics ((LNP,volume 684))

Abstract

This chapter presents a review of NMR in small particles of three elemental metals: the “odd electron” Ag and Rh, and the “even electron” Pt. These experiments on elements close to each other in the periodic system demonstrate the versatility of the NMR technique, detecting several properties that are not captured by the simplest “electrons in a box” approximation. The NMR of Ag particles shows Bardeen-Friedel oscillations in the spatial density of Fermi-level electrons. The case of Pt is dominated by a strong spatial variation in the local density of states of d-like electrons, and Rh shows at low temperatures signs of incipient antiferromagnetism. As an introduction, a summary of relevant NMR theory is presented, and its application to the NMR of bulk Na metal.

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Authors and Affiliations

  1. EPFL, Institut de Physique des Nanostructures, Lausanne, 1015, Switzerland

    J.J. van der Klink

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Editors and Affiliations

  1. Physics Department Faculty of Mathematics and Physics, University Ljubljana, Jadranska 19, Ljubljana, 1000, Slovenia

    Janez Dolinšek Professor Dr.  & Slobodan Žumer Professor Dr.  & 

  2. Jozef Stefan Institute, Jamova 39, Ljubljana, 1000, Slovenia

    Janez Dolinšek Professor Dr. , Marija Vilfan Professor Dr.  & Slobodan Žumer Professor Dr. ,  & 

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van der Klink, J. (2006). Beyond Electrons in a Box: Nanoparticles of Silver, Platinum and Rhodium. In: Dolinšek, J., Vilfan, M., Žumer, S. (eds) Novel NMR and EPR techniques. Lecture Notes in Physics, vol 684. Springer, Berlin, Heidelberg . https://doi.org/10.1007/3-540-32627-8_8

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