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Synthesis of ruthenium(II) complexes of aromatic chelating heterocycles: Towards the design of luminescent compounds

  • Ronald A. Krause
Conference paper
Part of the Structure and Bonding book series (STRUCTURE, volume 67)

Abstract

The majority of ruthenium(II) compounds which have been observed to be luminescent are complexes of aromatic heterocyclic chelating ligands. Methods of synthesizing such complexes are reviewed and recommendations made (where considered possible) as to the best procedures.

Models for the emitting excited state are reviewed, particularly with regard to the effects of molecular structure on excited state behavior. Data are tabulated for known emitting complexes. While a wide variety of luminescent ruthenium(II) complexes cannot be designed at present, some guidelines are beginning to emerge.

In the future we look for continued development of the excited state model. Further structure-emission efficiency correlations and correlation with solvent properties are seen as bein important.

Keywords

Excited State Quantum Yield Emission Energy Mixed Complex Tridentate Ligand 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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© Springer-Verlag 1987

Authors and Affiliations

  • Ronald A. Krause
    • 1
  1. 1.Department of ChemistryUniversity of ConnecticutStorrsUSA

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