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Analysis of compositional and structural heterogeneities of polymers by non-exclusion HPLC

  • Gottfried Glöckner
Conference paper
Part of the Advances in Polymer Science book series (POLYMER, volume 79)

Abstract

High performance liquid chromatography (HPLC) of polymers is often thought to be synonymous with Size Exclusion Chromatography for separation by molar size. The present article deals with non-exclusion chromatography of polymers which enables separation by differences in the chemical structure and composition.

Keywords

High Performance Liquid Chromatography Hioh Performance Liquid Chromatography Molar Mass Gradient Elution Structural Heterogeneity 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abbreviations

AN

Acrylonitrile

AC

Adsorption chromatography

AcN

Acetonitrile

CF

Cross fractionation

CCF

Chromatographic cross-fractionation

CCD

Chemical-composition distribution

HIC

Hydrophobic interaction chromatography

IEC

Ion exchange chromatography

MEK

Methyl ethyl ketone

MMD

Molar-mass distribution

RP

Reversed phase

RPC

Reversed-phase chromatography

PS

Polystyrene

SAN

Poly(styrene-co-acrylonitrile)

SMA

Poly(styrene-co-methyl acrylate)

SMMA

Poly(styrene-co-methyl methacrylate)

SEC

Size exclusion chromatography

SBR

Styrene-butadiene rubber

THF

Tetrahydrofuran

TLC

Thin-layer chromatography

Symbols

dO

Pore diameter

dP

Particle size of packing materials

P

Degree of polymerization

M

Molar mass

\(\overline M\)n

Number average of M

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Copyright information

© Springer-Verlag 1986

Authors and Affiliations

  • Gottfried Glöckner
    • 1
  1. 1.Sektion ChemieTechnische Universität DresdenDresdenGDR

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