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Photochemistry in micelles

  • Nicholas J. Turro
  • G. Sidney Cox
  • Mark A. Paczkowski
Conference paper
Part of the Topics in Current Chemistry book series (TOPCURRCHEM, volume 129)

Abstract

Organic photochemical reactions conducted in micellar solutions are reviewed from the standpoint of systematizing and correlating published results. Five common effects are found to distinguish and characterize micellar photochemistry relative to conventional solution photochemistry: “super” cage effects, local concentration effects, viscosity effects, polarity effects, and electrostatic effects. These effects can contribute to the occurence of enhanced selectivity and efficiency of photoreactions relative to those in conventional homogeneous solution.

Keywords

Sodium Dodecyl Sulfate Critical Micellar Concentration Radical Pair Micellar Solution Micellar System 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abbreviations

SDS

sodium dodecyl sulfate

HDTCl

hexadecyltrimethylammonium chloride

HDTBr

hexadecyltrimethylammonium bromide

Brij 35

polyoxyethylene (23) lauryl ether

DTAC

dodecyltrimethylammonium chloride

TTACl

tetradecyltrimethylammonium chloride

HDPB

hexadecylpyridinium bromide

KDC

potassium decanoate

SPFO

sodium perfluorooctanoate

KTC

potassium tetradecanoate

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Copyright information

© Springer-Verlag 1985

Authors and Affiliations

  • Nicholas J. Turro
    • 1
  • G. Sidney Cox
    • 1
  • Mark A. Paczkowski
    • 1
  1. 1.Department of ChemistryColumbia UniversityNew YorkUSA

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