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Quantitative structure-reactivity analysis of the inclusion mechanism by cyclodextrins

  • Yoshihisa Matsui
  • Takaaki Nishioka
  • Toshio Fujita
Chapter
Part of the Topics in Current Chemistry book series (TOPCURRCHEM, volume 128)

Abstract

The applications of quantitative structure-reactivity analysis to cyclodextrin complexation and cyclodextrin catalysis, mostly from our laboratories, as well as the experimental and theoretical backgrounds of these approaches, are reviewed. These approaches enable us to separate several intermolecular interactions, acting simultaneously, from one another in terms of physicochemical parameters, to evaluate the extent to which each interaction contributes, and to predict thermodynamic stabilities and/or kinetic rate constants experimentally undetermined. Conclusions obtained are mostly consistent with those deduced from experimental measurements.

Keywords

Inclusion Complex Guest Molecule Rate Acceleration Phenyl Acetate Cyclodextrin Complex 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag 1985

Authors and Affiliations

  • Yoshihisa Matsui
    • 1
  • Takaaki Nishioka
    • 2
  • Toshio Fujita
    • 2
  1. 1.Department of Agricultural ChemistryShimane UniversityMatsueJapan
  2. 2.Department of Agricultural ChemistryKyoto UniversityKyotoJapan

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