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Magnetic properties of actinide solids

  • J. M. Fournier
Conference paper
Part of the Structure and Bonding book series (STRUCTURE, volume 59/60)

Abstract

The various magnetic properties observed in actinide solids are largely determined by the degree the unsaturated 5 f shells retain an atomic localized character or lose it in an itinerant mode. Hence the investigation of magnetism (and of related properties such as low temperature electrical resistivity) has played a central role in understanding bonding in actinide solids. Between clear cut cases of “localization” or “itineracy” intermediate situations are observed (leading for instance to spin fluctuating behaviour) which have made actinide magnetic research a rich but also controversial field.

A short exposition of the basic concepts of actinide magnetic research and of the different aspects of magnetic ordering in actinide solids is followed by a discussion of experimental and interpretational aspects, in particular the difficulty always encountered of separating the different contributions.

A number of examples have been chosen to illustrate the variety of magnetic behaviour and its meaning in establishing a unified picture of actinide solid state physics.

One of the aims of the chapter is to inspire new research in actinide magnetism. To this purpose, tables collecting the main magnetic data for a large number of actinide binary compounds are provided.

Keywords

Magnetic Property Electrical Resistivity Crystal Field Spin Fluctuation Magnetic Phase Diagram 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag 1985

Authors and Affiliations

  • J. M. Fournier
    • 1
  1. 1.University of Grenoble and Centre d'Etudes Nucléaires de GrenobleGrenobleFrance

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