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The preparation of high purity actinide metals and compounds

  • W. Müller
  • J. C. Spirlet
Conference paper
Part of the Structure and Bonding book series (STRUCTURE, volume 59/60)

Abstract

Considerable progress has been possible in the determination of chemical and physical properties of actinide solids as a result of improved preparation and purification methods.

The growing demands for well characterized samples have given the incentive to overcome the difficulties presented to the actinide chemist by the high radioactivity hazard and comparative rarity of the actinide elements.

In this chapter, preparation and purification methods are reviewed. In view of the expected role of 5 f electrons in the metallic bond of actinides, methods for the preparation of metals have been particularly studied. There has also been important progress in the preparation of simple binary compounds. Special emphasis has been given to the growth of single crystals, particularly needed for the most refined physical techniques.

The chapter underlines the interdisciplinary nature of actinide solid state research.

Keywords

Molten Salt Thermal Dissociation Transuranium Element Chemical Vapour Transport Volatile Impurity 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Müller, W.: in: Lanthanide and Actinide Chemistry and Spectroscopy (ed. Edelstein, N.), ACS Symp. series 131, p. 183 (1980)Google Scholar
  2. 2.
    Weigel, F.: in: Handbuch der Präparativen Anorganischen Chemie (ed. Brauer, G.), Band II, Ferdinand Enke Verlag, p. 1117, Stuttgart 1978Google Scholar
  3. 3.
    Lesser, R., Peterson, J. R.: in: Transurane (ed. Koch, G.), Band 31, Teil B 1, Gmelin Handbuch der Anorganischen Chemie, Springer Verlag, Berlin, Heidelberg, New York 1976Google Scholar
  4. 4.
    Haire, R. G.: in: Actinides in Perspective (ed. Edelstein, N.), Pergamon Press, Oxford, p. 309 (1982)Google Scholar
  5. 5.
    Spirlet, J. C.: in: Actinide in Perspective (ed. Edelstein, N.), Pergamon Press, Oxford, p. 361 (1982)Google Scholar
  6. 6.
    Spirlet, J. C., Müller, W.: J. Less-Common Metals 31, 35 (1973)CrossRefGoogle Scholar
  7. 7.
    Haire, R. G., Baybarz, R. D.: J. Inorg. Nucl. Chem. 36, 1295 (1974)CrossRefGoogle Scholar
  8. 8.
    Baybarz, R. D. et al.: in: Transplutonium 1975 (eds. Müller, W., Lindner, R.), North-Holland Publishing Comp., p. 69, Amsterdam 1976Google Scholar
  9. 9.
    Spirlet, J. C.: J. Phys. (Paris), Coll., C4, 40, 87 (1979)Google Scholar
  10. 10.
    Erdmann, B., Keller, C.: Inor. Nucl. Chem. Letters 7, 675 (1971)CrossRefGoogle Scholar
  11. 11.
    Müller, W., Reul, J., Spirlet, J. C.: Atomwirtschaft 17, 415 (1972)Google Scholar
  12. 12.
    Lorenz, R. et al.: J. Nucl. Mat. 37, 203 (1970)CrossRefGoogle Scholar
  13. 13.
    Brown, D., Tso, T. C., Whittacker, B.: AERE-R 8638 (1976)Google Scholar
  14. 14.
    Bohet, J., Müller, W.: J. Less-Common Metals 57, 185 (1978)CrossRefGoogle Scholar
  15. 15.
    Jones, D. W. et al.: in: Rare Earths and Actinides 1977, Internat. Conf. on Rare Earths and Actinides, Durham, Inst. Phys. Conf. Series 37, 11 (1978)Google Scholar
  16. 16.
    Müller, W., Reul, J., Spirlet, J. C.: Revue de Chimie Minérale 14, 212 (1977)Google Scholar
  17. 17.
    Chauvin, G., Corion, H., Hure, J.: Industries 439, 1 (1962)Google Scholar
  18. 18.
    Mullins, C., Leary, J. A.: Nuclear Applications 6, 287 (1969)Google Scholar
  19. 19.
    Schmidt, F. A., Outlaw, R. A., Lunde, B. K.: Report 15-M 171 (1979)Google Scholar
  20. 20.
    Müller, W.: Chem. Ztg. 160, 105 (1982)Google Scholar
  21. 21.
    Brown, D.: Halides of the Lanthanides and Actinides, Wiley Interscience Publishers, New York 1968Google Scholar
  22. 22.
    Brown, D.: in: Transurane (ed. Koch, G.), Teil C, Verbindungen, Gmelins Handbuch der Anorganischen Chemie, Ergänzungswerk zur achten Auflage, Band 4, Verlag Chemie, Weinheim 1972Google Scholar
  23. 23.
    Baybarz, R. D. et al.: J. Inorg. Nucl. Chem. 34, 3427 (1972)CrossRefGoogle Scholar
  24. 24.
    Peterson, J. R. et al.: J. Phys. (Paris) Coll., C4, 40, 111 (1979)Google Scholar
  25. 25.
    Hussonois, M. et al.: J. Crystal Growth 51, 11 (1981)CrossRefGoogle Scholar
  26. 26.
    Akimoto, Y.: J. Inorg. Nucl. Chem. 29, 2650 (1969)CrossRefGoogle Scholar
  27. 27.
    Leger, J. M., Yacoubi, N., Loriers, J.: J. Solid State Chem. 36, 261 (1981)CrossRefGoogle Scholar
  28. 28.
    Henrick, C. C., Behrens, R. G.: J. Crystal Growth 51, 183 (1981)CrossRefGoogle Scholar
  29. 29.
    Finch, C. B., Clark, G. W.: J. Appl. Phys. 36, 2143 (1965)CrossRefGoogle Scholar
  30. 30.
    Finch, C. B., Clark, G. W.: J. Crystal Growth 6, 246 (1970)Google Scholar
  31. 31.
    Martinot, L. et al.: Bull. Soc. Chim. Belges 79, 250 (1962)Google Scholar
  32. 32.
    Van Lierde, W. et al.: J. Nucl. Mat. 5, 250 (1962)CrossRefGoogle Scholar
  33. 33.
    Spirlet, J. C. et al.: J. Phys. (Paris) Coll., C4, 40, 108 (1979)Google Scholar
  34. 34.
    Spirlet, J. C. et al.: J. Crystal Growth 49, 171 (1980)CrossRefGoogle Scholar
  35. 35.
    Nomura, Y., Kamegashira, N., Naito, K.: ibid. 52, 279 (1981)CrossRefGoogle Scholar
  36. 36.
    Suski, W.: in: Uranium Chalcogenides, Wroclwaska Drukania Naukowa 1976Google Scholar
  37. 37.
    Damien, D.: Synthèse et Cristallochimie des Chalcogénures de Transuraniens, Dissertation, Clermont-Ferrand 1976Google Scholar
  38. 38.
    Hery, Y.: Synthèse, Cristallochimie et Propriétés Magnétique des Pnictures de Protactinium, Dissertation, Strasbourg 1978Google Scholar
  39. 39.
    Damien, D., Haire, R. G., Peterson, J. R.: J. Less-Common Metals 68, 159 (1979)CrossRefGoogle Scholar
  40. 40.
    Damien, D., Haire, R. G., Peterson, J. R.: J. Inorg. Nucl. Chem. 42, 955 (1980)CrossRefGoogle Scholar
  41. 41.
    Damien, D., Haire, R. G., Peterson, J. R.: Inorg. Nucl. Chem. Lett. 16, 537 (1980)CrossRefGoogle Scholar
  42. 42.
    Endebrock, R. W., Forster, E. L., Keller, D. L.: Compounds of Interest in Nuclear Reactor Technology, Proc. of a Symp., AIME, Nucl. Mat. 10, 557 (1964)Google Scholar
  43. 43.
    Henkie, Z.: Technologia Monocrystalow, Polish Scientific Publishers, Warszawa 2, 56 (1974)Google Scholar
  44. 44.
    Henkie, Z., Misiuk, A.: Kristall and Technik 14, 539 (1979)CrossRefGoogle Scholar
  45. 45.
    Charvillat, J. P., Damien, D., Wojakowski, A.: Revue de Chimie Minérale 14, 178 (1977)Google Scholar
  46. 46.
    Vogt, O.: in: Actinides in Perspective (ed. Edelstein, N.), Pergamon Press, Oxford, p. 289 (1982)Google Scholar
  47. 47.
    Spirlet, J. C. et al.: Journée des Actinides, Orsay 1982Google Scholar
  48. 48.
    Eberle, A. R. et al.: NBC-252 (1970)Google Scholar
  49. 49.
    Charvillat, J. P.: Cristallochimie des Pnictures de Transuraniens, Dissertation, Clermont-Ferrand 1977Google Scholar
  50. 50.
    Henkie, Z., Markowski, P. J.: J. Crystal Growth 41, 303 (1977)CrossRefGoogle Scholar
  51. 51.
    Calestani, G., Spirlet, J. C., Müller, W.: J. Phys. (Paris), Coll., C4, 40, 106 (1979)Google Scholar
  52. 52.
    Calestani, G.: Herstellung, Kristallzüchtung und Charakterisierung von Thorium-, Uran-und Protactiniumpnictiden, Dissertation, Saarbrücken 1980Google Scholar
  53. 53.
    Haschke, J. M., Hodges, A. E.: Actinides 1981, LBL 12441, p. 229 (1981)Google Scholar
  54. 54.
    Ward, J. W. et al.: Actinides 1981, LBL-12441, p. 86 (1981)Google Scholar
  55. 55.
    Ward, J. W., Bartscher, W.: 12ème Journée des Actinides, Orsay 1982Google Scholar
  56. 56.
    Arko, A. J., Weber, L. W.: Actinides 1981, LBL-12441, p. 57 (1981)Google Scholar
  57. 57.
    Spirlet, J. C.: 1980 World Conf. of the Internat. Target Development Society, Gatlinburg, Tenn. 1980Google Scholar
  58. 58.
    Leider, F.: Thèse de Doctorat, University of Liège (Belgium) 1983Google Scholar
  59. 59.
    Naegele, J. R.: J. Phys. (Paris) C2, 841 (1984)Google Scholar
  60. 60.
    Gandolfi, G.: Miner. Petrog. Acta 10, 149 (1964)Google Scholar

Copyright information

© Springer-Verlag 1985

Authors and Affiliations

  • W. Müller
    • 1
  • J. C. Spirlet
    • 1
  1. 1.Commission of the European Communities, Joint Research Centre, Karlsruhe EstablishmentEuropean Institute for Transuranium ElementsKarlsruheF. R. G.

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