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Natural vibrational Raman optical activity

  • Laurence D. Barron
  • Julian Vrbancich
Conference paper
Part of the Topics in Current Chemistry book series (TOPCURRCHEM, volume 123)

Abstract

This article reviews all the published work concerned with the study of vibrational optical activity in chiral molecules from measurements of a small difference in the intensity of Raman scattering in right and left circularly polarized incident light. The history and basic theory are described briefly, followed by an account of the instrumentation and the precautions that must be observed in order to suppress spurious signals. The various theories that have been proposed in order to relate stereochemical features to the observations are then outlined, this being followed by a survey of all reported Raman optical activity spectra.

Keywords

Circular Dichroism Optical Activity Chiral Molecule Bond Polarizability Optical Rotatory Dispersion 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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8 References

  1. 1.
    Barron, L. D., Buckingham, A. D.: Ann. Rev. Phys. Chem. 26, 381 (1975)CrossRefGoogle Scholar
  2. 2.
    Barron, L. D.: Raman optical activity, in: Advances in Infrared and Raman Spectroscopy, Vol. 4 (eds. Clark, R. J. H., Hester, R. E.) p. 271, London, Heyden 1978Google Scholar
  3. 3.
    Barron, L. D.: Raman optical activity, in: Optical Activity and Chiral Discrimination (ed. Mason, S. F.) p. 219, Dordrecht, Reidel 1979Google Scholar
  4. 4.
    Barron, L. D.: Acc. Chem. Res. 13, 90 (1980)CrossRefGoogle Scholar
  5. 5.
    Barron, L. D.: Molecular Light Scattering and Optical Activity, Cambridge, Cambridge Univ. Press 1982Google Scholar
  6. 6.
    Nafie, L. A., Diem, M.: Acc. Chem. Res. 12, 296 (1979)CrossRefGoogle Scholar
  7. 7.
    Nafie, L. A.: Infrared and Raman vibrational optical activity, in: Vibrational Spectra and Structure, Vol. 10 (ed. Durig, J. R.) p. 153, Amsterdam, Elsevier 1981Google Scholar
  8. 8.
    Polavarapu, P. L.: Recent advances in model calculation of vibrational optical activity, in: Vibrational Spectra and Structure, Vol. 13 (ed. Durig, J. R.), Amsterdam, Elsevier (in the press)Google Scholar
  9. 9.
    Gans, R.: Z. Phys. 17, 353 (1923)CrossRefGoogle Scholar
  10. 10.
    de Malleman, R.: Compt. Rend. 181, 371 (1925)Google Scholar
  11. 11.
    Bhagavantam, S., Venkateswaran, S.: Nature 125, 237 (1930)Google Scholar
  12. 12.
    Kastler, A.: Compt. Rend. 191, 565 (1930)Google Scholar
  13. 13.
    Perrin, F.: J. Chem. Phys. 10, 415 (1942)CrossRefGoogle Scholar
  14. 14.
    Atkins, P. W., Barron, L. D.: Mol. Phys. 16, 453 (1969)Google Scholar
  15. 15.
    Barron, L. D., Buckingham, A. D.: ibid. 20, 1111 (1971)Google Scholar
  16. 16.
    Bosnich, B., Moskovits, M., Ozin, G. A.: J. Am. Chem. Soc., 94, 4750 (1972)CrossRefGoogle Scholar
  17. 17.
    Diem, M., Fry, J. L., Burow, D. F.: ibid. 95, 253 (1973)CrossRefGoogle Scholar
  18. 18.
    Barron, L. D., Bogaard, M. P., Buckingham, A. D.: ibid. 95, 603 (1973)CrossRefGoogle Scholar
  19. 19.
    Barron, L. D., Bogaard, M. P., Buckingham, A. D.: Nature 241, 113 (1973)Google Scholar
  20. 20.
    Barron, L. D., Buckingham, A. D.: J. Chem. Soc., Chem. Commun. 1974, 152Google Scholar
  21. 21.
    Hug, W., Kint, S., Bailey, G. F., Scherer, J. R.: J. Am. Chem. Soc. 97, 5589 (1975)CrossRefGoogle Scholar
  22. 22.
    Diem, M., Diem, M. J., Hudgens, B. A., Fry, J. L., Burow, D. F.: J. Chem. Soc., Chem. Commun. 1976, 1028Google Scholar
  23. 23.
    Boucher, H., Brocki, T. R., Moskovits, M., Bosnich, B.: J. Am. Chem. Soc. 99, 6870 (1977)CrossRefGoogle Scholar
  24. 24.
    Waki, H., Higuchi, S., Tanaka, S., Sakayanag, N.: J. Spectrosc. Soc. Japan 26, 272 (1977)Google Scholar
  25. 25.
    Barron, L. D., Vrbancich, J.: Magnetic Raman optical activity, in: Advances in Infrared and Raman Spectroscopy, (eds. Clark, R. J. H., Hester, R. E.) London, Heyden, in the pressGoogle Scholar
  26. 26.
    Buckingham, A. D.: Adv. Chem. Phys. 12, 107 (1967)Google Scholar
  27. 27.
    Long, D. A.: Raman Spectroscopy, New York, McGraw-Hill 1977Google Scholar
  28. 28.
    Andrews, D. L.: J. Chem. Phys. 72, 4141 (1980)CrossRefGoogle Scholar
  29. 29.
    Bjarnason, J. O., Andersen, H. C., Hudson, B. S.: ibid. 72, 4132 (1980)CrossRefGoogle Scholar
  30. 30.
    Oudar, J. L., Minot, C., Garetz, B. A.: ibid. 76, 2227 (1982)CrossRefGoogle Scholar
  31. 31.
    Barron, L. D.: Rayleigh and Raman scattering of polarized light, in: Molecular Spectroscopy, Vol. 4 (eds. Barrow, R. F., Long, D. A., Sheridan, J.) p. 96, London, The Chemical Society 1976Google Scholar
  32. 32.
    Buckingham, A. D., Longuet-Higgins, H. C.: Mol. Phys. 14, 63 (1968)Google Scholar
  33. 33.
    Polavarapu, P. L., Diem, M., Nafie, L. A.: J. Am. Chem. Soc. 102, 5449 (1980)CrossRefGoogle Scholar
  34. 34.
    Brocki, T., Moskovits, M., Bosnich, B.: ibid. 102, 495 (1980)CrossRefGoogle Scholar
  35. 35.
    Hug, W., Surbeck, H.: Chem. Phys. Letters 60, 186 (1979)CrossRefGoogle Scholar
  36. 36.
    Talmi, Y.: Optoelectronic image detectors in chemistry, in: Multichannel Image Detectors (ed. Talmi, Y.), A.C.S. Symposium series, Vol. 102, p. 3, Washington D.C., Americal Chemical Society 1979Google Scholar
  37. 37.
    Horlick, G.: Appl. Spectrosc. 30, 113 (1976)Google Scholar
  38. 38.
    Hug, W.: Instrumental and theoretical advances in Raman optical activity, in: Raman Spectroscopy (eds. Lascombe, J., Huong, P. V.) p. 3, Chichester, Wiley, 1982Google Scholar
  39. 39.
    Barron, L. D., Torrance, J. F.: Chem. Phys. Letters (in the press)Google Scholar
  40. 40.
    Barron, L. D., Buckingham, A. D.: U.K. Pat. No. 6454 (1971); U.S. Pat. No. 3817634 (1974)Google Scholar
  41. 41.
    Hug, W.: Appl. Spectrosc. 35, 115 (1981)Google Scholar
  42. 42.
    Barron, L. D., Vrbancich, J.: J. Raman Spectrosc. (in the press)Google Scholar
  43. 43.
    Barron, L. D., Buckingham, A. D.: J. Am. Chem. Soc. 96, 4769 (1974)CrossRefGoogle Scholar
  44. 44.
    Barron, L. D., Buckingham, A. D.: ibid. 101, 1979 (1979)CrossRefGoogle Scholar
  45. 45.
    Barron, L. D., Clark, B. P.: Mol. Phys. 46, 839 (1982)Google Scholar
  46. 46.
    Sverdlov, L. M., Kovner, M. A., Krainov, E. P.: Vibrational Spectra of Polyatomic Molecules, Jerusalem, Israel Program for Scientific Translations 1974Google Scholar
  47. 47.
    Gussoni, M.: Infrared and Raman intensities from electro-optical parameters, in: Advances in Infrared and Raman Spectroscopy, Vol. 6 (eds. Clark, R. J. H., Hester, R. E.) p. 61, London, Heyden, 1980Google Scholar
  48. 48.
    Placzek, G.: Rayleigh and Raman scattering, in: Handbuch der Radiologie, Vol. 6, Part 2, (ed. Marx, E.) p. 205, Leipzig, Akademische Verlagsgesellschaft 1934Google Scholar
  49. 49.
    Wilson, E. B., Decius, J. C., Cross, P. C.: Molecular Vibrations, New York, McGraw-Hill 1955Google Scholar
  50. 50.
    Barron, L. D., Clark, B. P.: J. Raman Spectrosc. 13, 155 (1982)CrossRefGoogle Scholar
  51. 51.
    Applequist, J.: Acc. Chem. Res. 10, 79 (1977)CrossRefGoogle Scholar
  52. 52.
    Prasad, P. L., Burow, D. F.: J. Am. Chem. Soc. 101, 800 (1979)CrossRefGoogle Scholar
  53. 53.
    Prasad, P. L., Burow, D. F.: ibid. 101, 806 (1979)CrossRefGoogle Scholar
  54. 54.
    Prasad, P. L., Nafie, L. A.: J. Chem. Phys. 70, 5582 (1979)CrossRefGoogle Scholar
  55. 55.
    Prasad, P. L., Nafie, L. A., Burow, D. F.: J. Raman Spectrosc. 8, 255 (1979)CrossRefGoogle Scholar
  56. 56.
    Polavarapu, P. L., Nafie, L. A.: J. Chem. Phys. 73, 1567 (1980)CrossRefGoogle Scholar
  57. 57.
    Nafie, L. A., Polavarapu, P. L., Diem, M.: ibid. 73, 3530 (1980)CrossRefGoogle Scholar
  58. 58.
    Nafie, L. A., Freedman, T. B.: ibid. 75, 4847 (1981)CrossRefGoogle Scholar
  59. 59.
    Polavarapu, P. L.: ibid. 77, 2273 (1982)CrossRefGoogle Scholar
  60. 60.
    Freedman, T. B., Nafie, L. A.: ibid. 78, 27 (1983)CrossRefGoogle Scholar
  61. 61.
    Komornicki, A., McIver, J. W.: ibid. 70, 2014 (1979)CrossRefGoogle Scholar
  62. 62.
    Barron, L. D.: J. Chem. Soc. A. 1971, 2899Google Scholar
  63. 63.
    Stone, A. J.: Mol. Phys. 29, 1461 (1975)Google Scholar
  64. 64.
    Stone, A. J.: ibid. 33, 293 (1977)Google Scholar
  65. 65.
    Andrews, D. L., Thirunamachandran, T.: Proc. Roy. Soc. A358, 297 (1977)Google Scholar
  66. 66.
    Andrews, D. L., Thirunamachandran, T.: ibid. A358, 311 (1977)Google Scholar
  67. 67.
    Gohin, A., Moskovits, M.: J. Am. Chem. Soc. 10, 1660 (1981)CrossRefGoogle Scholar
  68. 68.
    Barron, L. D., Vrbancich, J.: Mol. Phys. 48, 833 (1983)Google Scholar
  69. 69.
    Barron, L. D., Torrance, J. F., Vrbancich, J.: J. Raman Spectrosc. 13, 171 (1982)CrossRefGoogle Scholar
  70. 70.
    Cuony, B., Hug, W.: Chem. Phys. Letters 84, 131 (1981)CrossRefGoogle Scholar
  71. 71.
    Barron, L. D., Clark, B. P.: J. Chem. Soc., Perkin Trans. II 1979, 1164Google Scholar
  72. 72.
    Barron, L. D., Clark, B. P.: ibid. 1979, 1171Google Scholar
  73. 73.
    Barron, L. D.: Nature 255, 458 (1975)Google Scholar
  74. 74.
    Barron, L. D.: J. Chem. Soc., Perkin Trans. II 1977, 1790Google Scholar
  75. 75.
    Su, C. N., Keiderling, T. A.: Chem. Phys. Letters 77, 494 (1981)CrossRefGoogle Scholar
  76. 76.
    Hug, W., Kamatari, A., Srinivasan, K., Hansen, H.-J., Sliwka, H.-R.: ibid. 76, 469 (1980)CrossRefGoogle Scholar
  77. 77.
    Barron, L. D., Clark, B. P.: J. Chem. Res. (S) 1979, 36Google Scholar
  78. 78.
    Barron, L. D.: J. Chem. Soc., Perkin Trans II 1977, 1074Google Scholar
  79. 79.
    Torrance, J. F.: Ph. D. Thesis, Glasgow Univ. 1983Google Scholar
  80. 80.
    Barron, L. D.: Tetrahedron 34, 607 (1978)CrossRefGoogle Scholar
  81. 81.
    Polavarapu, P. L., Diem, M., Nafie, L. A.: J. Am Chem. Soc. 102, 5449 (1980)CrossRefGoogle Scholar
  82. 82.
    Barron, L. D.: J. Chem. Soc., Chem. Commun. 1977, 305Google Scholar
  83. 83.
    Barron, L. D., Numan, H., Wynberg, H.: ibid. 1978, 259Google Scholar
  84. 84.
    Barron, L. D., Vrbancich, J.: Mol. Phys. 48, 833 (1983)Google Scholar
  85. 85.
    Barron, L. D., Vrbancich, J.: J. Chem. Soc., Chem. Commun. 1981, 771Google Scholar
  86. 86.
    Waki, H., Higuchi, S., Tanaka, S.: Chem. Letters 1981, 147Google Scholar
  87. 87.
    Higuchi, S., Tanaka, K., Tanaka, S.: ibid. 1982, 635Google Scholar

Copyright information

© Springer-Verlag 1984

Authors and Affiliations

  • Laurence D. Barron
    • 1
  • Julian Vrbancich
    • 2
  1. 1.Chemistry DepartmentThe UniversityGlasgowU.K.
  2. 2.Research School of ChemistryAustralian National UniversityCanberraAustralia

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