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Subhalides of tellurium

  • Rüdiger Kniep
  • Albrecht Rabenau
Conference paper
Part of the Topics in Current Chemistry book series (TOPCURRCHEM, volume 111)

Abstract

The tellurium subhalides represent a group of recently discovered compounds which have been investigated by the methods of solid-state and structural chemistry. Because of their high tellurium content and their crystal structures containing homonuclear tellurium connections they have attained significance as “modified tellurium structures”. As a consequence, tellurium subhalides have been the subject of various investigations in the fields of solid-state and chemical physics.

In this paper a short survey of the group of tellurium halides is followed by detailed information on phase relations, preparation, crystal growth, and crystal structures of tellurium subhalides. Mössbauer investigations as well as optical, photoelectric, and electrical properties of the respective compounds are discussed. Solid-state galvanic cells containing tellurium subhalides have enabled the precise determination of relevant thermodynamic data.

Keywords

Mixed Crystal Iodine Atom Crystal Structure Analysis Vitreous Phase Tellurium Atom 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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XI References

  1. 1.
    Rose, A.: Pogg. Ann. 21, 443 (1831)Google Scholar
  2. 2.
    Berzelius, J. J.: Ann. Chim. Phys. (1835)Google Scholar
  3. 3.
    Jaeger, F. M., Menke, J. B.: Z. Anorg. Chem. 75, 241 (1912)Google Scholar
  4. 4.
    Damiens, A.: Bull. Soc. Chim. France 29, 512 (1921)Google Scholar
  5. 5.
    Damiens, A.: Ann. Chim. 19, 44 (1923)Google Scholar
  6. 6.
    Ivashin, S. A., Petrov, E. S.: Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Chim. Nauk 5, 48 (1970)Google Scholar
  7. 7.
    Rabenau, A., Rau, H.: Z. Anorg. Allg. Chem. 395, 273 (1973)Google Scholar
  8. 8.
    Ivashin, S. A., Petrov, E. S.: Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Chim. Nauk 1, 149 (1970)Google Scholar
  9. 9.
    Kniep, R., Rabenau, A., Rau, H.: J. Less-Common Met. 35, 325 (1974)Google Scholar
  10. 10.
    Safonov, V. V., Kuklina, N. F., Korshunov, B. G.: Russ. J. Inorg. Chem. 20, 309 (1975)Google Scholar
  11. 11.
    Rabenau, A., Rau, H.: Proc. 6th Intern. Symp. Reactivity of Solids, Schenectady, USA, 25 (1968); (eds.) Mitchell, J. W., et al. p. 763 (1968)Google Scholar
  12. 12.
    Buss, B., Krebs, B.: Angew. Chem. 82, 446 (1970); Angew. Chem. Int. Ed. Engl. 9, 463 (1970)Google Scholar
  13. 13.
    Buss, B., Krebs, B.: Inorg. Chem. 10, 2795 (1971)Google Scholar
  14. 14.
    Krebs, B., Paulat, V.: Acta Cryst. B32, 1470 (1976)Google Scholar
  15. 15.
    Brink Shoemaker, C., Abrahams, S. C.: Acta Cryst. 18, 296 (1965)Google Scholar
  16. 16.
    Khodadad, P.: Ann. Chim. 3/4, 83 (1965)Google Scholar
  17. 17.
    Blackmore, W. R., Abrahams, S. C., Kalnajs, J.: Acta Cryst. 9, 295 (1956)Google Scholar
  18. 18.
    Kniep, R.: Thesis, Universität Braunschweig (1973)Google Scholar
  19. 19.
    Kniep, R.: in preparationGoogle Scholar
  20. 20.
    Prince, D. J., Corbett, J. D., Garbisch, B.: Inorg. Chem. 9, 2731 (1970)Google Scholar
  21. 21.
    Ivashin, S. A., Petrov, E. S., Samsonova, T. I.: Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk 6, 51 (1969)Google Scholar
  22. 22.
    Dharmatti, W.: Proc. Indian Acad. Sci. 12A, 212 (1940)Google Scholar
  23. 23.
    Aynsley, E. E.: J. Chem. Soc. 3016 (1953)Google Scholar
  24. 24.
    Safonov, V. V., Konov, A. V., Korshunov, B. G.: Izv. Vysshikh. Uchebn. Zaved. Tsvetn. Met. 12, 83 (1969)Google Scholar
  25. 25.
    Safonov, V. V., Korshunov, B. G., Pervushkin, V. V.: Izv. Vysshikh. Uchebn. Zaved. Tsvetn. Met. 13, 97 (1970)Google Scholar
  26. 26.
    Mahmud, Y., et al.: J. Phys. Coll. C6, 227 (1974)Google Scholar
  27. 27.
    Wehrili, M., Gutzwiller, N.: Helv. Phys. Acta 14, 307 (1941)Google Scholar
  28. 28.
    Voigt, A., Biltz, W.: Z. Anorg. Allg. Chem. 133, 277 (1924)Google Scholar
  29. 29.
    Christensen, G. C., Alstad, J.: Radiochem. Radional. Lett. 13, 227 (1973)Google Scholar
  30. 30.
    Kniep, R., Katryniok, D.: J. Chem. Soc., Dalton Trans. 1977, 2048Google Scholar
  31. 31.
    Kniep, R.: in preparationGoogle Scholar
  32. 32.
    Aynsley, E. E., Watson, R. H.: J. Chem. Soc. 2603 (1955)Google Scholar
  33. 33.
    Rogers, M. T., Spurr, R. A.: J. Am. Chem. Soc. 69, 2102 (1947)Google Scholar
  34. 34.
    Wehrli, M.: Helv. Phys. Acta 9, 209 (1936)Google Scholar
  35. 35.
    Ivashin, S. A., Petrov, E. S.: Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk 2, 28 (1971)Google Scholar
  36. 36.
    Opperman, H., Stöver, G., Wolf, E.: Z. Anorg. Allg. Chem. 410, 179 (1974)Google Scholar
  37. 37.
    Opperman, H., Stöver, G., Wolf, E.: Z. Anorg. Allg. Chem. 419, 200 (1976)Google Scholar
  38. 38.
    Kuliev, A. A., Kulieva, S. A., Gadzhiev, S. M.: Inorg. Mater. 8, 717 (1972)Google Scholar
  39. 39.
    Burmeister, J.: Mater. Res. Bull. 6, 219 (1971)Google Scholar
  40. 40.
    Grether, W.: Ann. Phys. 26, 1 (1936)Google Scholar
  41. 41.
    Rabenau, A., Rau, H., Rosenstein, G.: Angew. Chem. 79, 688 (1967); Angew. Chem. Int. Ed. Engl. 6, 706 (1967)Google Scholar
  42. 42.
    Rabenau, A., Rau, H., in: Inorganic Syntheses (eds.) Wold, A., Ruff, E. K., chapter 35, New York, McGraw-Hill 1973Google Scholar
  43. 43.
    Afinogenov, Yu. P., Khaustova, Z. N.: Russ. J. Inorg. Chem. 15, 305 (1970)Google Scholar
  44. 44.
    Kniep, R., Mootz, D., Rabenau, A.: Z. Anorg. Allg. Chem. 422, 17 (1976)Google Scholar
  45. 45.
    Kniep, R., Mootz, D., Rabenau, A.: Angew. Chem. 85, 504 (1973); Angew. Chem. Int. Ed. Engl. 12, 499 (1973)Google Scholar
  46. 46.
    Rabenau, A., Rau, H., Rosenstein, G.: Angew. Chem. 82, 811 (1970); Angew. Chem. Int. Ed. Engl. 9, 802 (1970)Google Scholar
  47. 47.
    Kniep, R., Mootz, D., Rabenau, A.: Angew. Chem. 86, 411 (1974); Angew. Chem. Int. Ed. Engl. 13, 403 (1974)Google Scholar
  48. 48.
    Rabenau, A.: Hydrothermal synthesis in acid solutions, in Crystal Growth — an Introduction (ed.) Hartmann, P., p. 198, Amsterdam, North-Holland Publ. Co. 1973Google Scholar
  49. 49.
    Rabenau, A.: High Temp.-High Press. 6, 601 (1974)Google Scholar
  50. 50.
    Rabenau, A.: Formation and properties of some subhalides of tellurium, in: Reactivity of Solids (ed.) Wood, J., et al., p. 731, New York, Plenum Press 1977Google Scholar
  51. 51.
    Ivashin, S. A., Kanev, A. A., Petrov, E. S.: Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk 3, 28 (1971)Google Scholar
  52. 52.
    Ichikawa, K., Okubo, T., Shimoji, M.: Trans. Farad. Soc. 67, 1426 (1971)Google Scholar
  53. 53.
    Cherin, P., Unger, P.: Acta Cryst. 23, 670 (1967)Google Scholar
  54. 54.
    Shevchik, N. J., Kniep, R.: J. Chem. Phys. 60, 3011 (1974)Google Scholar
  55. 55.
    Ivashin, S. A., Petrov, E. S.: Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk 2, 28 (1971)Google Scholar
  56. 56.
    Ivashin, S. A., Petrov, E. S.: Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk 5, 34 (1970)Google Scholar
  57. 57.
    Wehrli, M.: Helv. Phys. Acta 9, 209 (1936)Google Scholar
  58. 58.
    Oldershaw, G. A., Robinson, K.: Chem. Commun. 1970, 540Google Scholar
  59. 59.
    Oldershaw, G. A., Robinson, K.: J. Molec. Spectrosc. 37, 314 (1971)Google Scholar
  60. 60.
    Rieke, U.: private communication (1970)Google Scholar
  61. 61.
    Kulieva, S. A., Gadzhiev, S. M., Kuliev, A. A.: Izv. Vysshikh. Uchebn. Zaved. Chim. i Chim. Technol. 15, 972 (1972)Google Scholar
  62. 62.
    Safonov, V. V. et al.: Russ. J. Inorg. Chem. 19, 791 (1974)Google Scholar
  63. 63.
    Ivashin, S. A., Petrov, E. S.: Izv. Akad. Nauk SSSR, Neorg. Mater. 10, 575 (1974)Google Scholar
  64. 64.
    Oppermann, H. et al.: Z. Anorg. Allg. Chem. 461, 165 (1980)Google Scholar
  65. 65.
    Oldershaw, G. A., Robinson, K.: Trans. Farad. Soc. 67, 907 (1971)Google Scholar
  66. 66.
    Bauhofer, W., Kniep, R.: Mater. Res. Bull. 8, 989 (1973)Google Scholar
  67. 67.
    Stetter, W., Schönherr, E.: Proc. Dreiländerjahrestagung Kristallwachstum und Kristallzüchtung, p. 17, Jülich (FRG), 1975Google Scholar
  68. 68.
    Schönherr, E.: private communication 1975Google Scholar
  69. 69.
    Schönherr, E., Chen Li Chuan, Stetter, W.: private communication 1980Google Scholar
  70. 70.
    Katryniok, D., Kniep, R.: J. Therm. Anal. 16, 291 (1979)Google Scholar
  71. 71.
    Gillespie, R. J., Nyholm, R. S.: Q. Rev. Chem. Soc. 11, 339 (1957)Google Scholar
  72. 72.
    v. Schnering, H. G.: Angew. Chem. 93, 44 (1981); Angew. Chem. Int. Ed. Engl. 93, 33 (1981)Google Scholar
  73. 73.
    Schäfer, H., Eisenmann, B., Müller, W.: Angew. Chem. 85, 742 (1973); Angew. Chem. Int. Ed. Engl. 12, 694 (1973)Google Scholar
  74. 74.
    Pauling, L.: The Nature of the Chemical Bond, 3rd. edit., Ithaca, N.Y., Cornell University Press 1960Google Scholar
  75. 75.
    Jones, C. N. W., Mauguin, M.: J. Chem. Phys. 68, 3067 (1978)Google Scholar
  76. 76.
    Jung, P., Triftschäuser, W.: Phys. Rev. 175, 512 (1968)Google Scholar
  77. 77.
    Gibb, T. C. et al.: J. Chem. Soc. A. 212 (1970)Google Scholar
  78. 78.
    Takeda, M., Greenwood, N. N.: J. Chem. Soc., Dalton 1976, 631Google Scholar
  79. 79.
    Born, P. et al.: Z. Naturforsch. 36b, 1516 (1981)Google Scholar
  80. 80.
    Born, P., Kniep, R., Mootz, D.: Z. Anorg. Allg. Chem. 451, 12 (1979)Google Scholar
  81. 81.
    Katryniok, D., Kniep, R.: Angew. Chem. 92, 646 (1980); Angew. Chem. Int. Ed. Engl. 19, 645 (1980)Google Scholar
  82. 82.
    Golubkova, B. G., Petrov, E. S.: Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk 2, 114 (1975)Google Scholar
  83. 83.
    Shevchik, N. J., Cardona, M., Tejeda, J.: Phys. Rev. B8, 2833 (1973)Google Scholar
  84. 84.
    Kniep, R.: J. Less.-Common Met. 75, 7 (1980)Google Scholar
  85. 85.
    v. Alpen, U.: Bull. Amer. Phys. Soc. 1975, 495Google Scholar
  86. 86.
    v. Alpen, U., Anastasakis, E.: Verhandlg. DPG VI 10, 375 (1975)Google Scholar
  87. 87.
    v. Alpen, U., Irslinger, C., Richter, W.: 2nd Conf. of the Condensed Matter, Div. Europ. Phys. Soc. on Dielectrics and Phonons, Budapest 1974Google Scholar
  88. 88.
    v. Alpen, U., Kniep, R.: Proc. 12th Int. Conf. on the Physics of Semiconductors, Stuttgart 1974; (ed.) Pilkuhn, M. H., p. 308, Stuttgart, Verlag Teubner 1974Google Scholar
  89. 89.
    Abrikosov, N. Kh., Zobnitsa, A. N.: V. Sb. Vopr. Met. i Fiz. Poluprov., Akad. Nauk SSSR, Moscow 1961, 110Google Scholar
  90. 90.
    v. Alpen, U., Gmelin, E., Kniep, R.: Verhandlg. DPG VI 9, 604 (1974)Google Scholar
  91. 91.
    v. Alpen, U., Kniep, R.: Solid-State Commun. 14, 1033 (1974)Google Scholar
  92. 92.
    Haag, J.: Thesis, Universität Stuttgart 1978Google Scholar
  93. 93.
    v. Alpen, U., Haag, J., Rabenau, A.: Mater. Res. Bull. 11, 793 (1976)Google Scholar
  94. 94.
    Haag, J., et al.: Z. Naturforsch. 34a, 969 (1979)Google Scholar
  95. 95.
    Haag, J., v. Alpen, U., Rabenau, A.: J. Less-Common Met. 76, 109 (1980)Google Scholar
  96. 96.
    Topol, L. E.: Inorg. Chem. 3, 451 (1968)Google Scholar
  97. 97.
    Rickert, H.: Elektrochemie fester Stoffe, Berlin—Heidelberg—New York, Springer 1973Google Scholar
  98. 98.
    Codata Task Group: Recommended Key Values for Thermodynamics 1973, in: J. Chem. Thermodyn. 7, 1 (1975)Google Scholar
  99. 99.
    Barin, B. A., Knacke, O.: Thermodynamic Properties of Inorganic Substances, Berlin—Heidelberg—New York, Springer 1973; Supplement, Berlin, Springer 1977Google Scholar
  100. 100.
    Handbook of Physics and Chemistry, Cleveland, Chemical Rubber Company 1976Google Scholar
  101. 101.
    Oppermann, H., Kunze, G., Wolf, E.: Z. Anorg. Allg. Chem. 432, 182 (1977)Google Scholar
  102. 102.
    Tsvetkov, V. G.: Russ. J. Inorg. Chem. 23, 1086 (1978)Google Scholar
  103. 103.
    Rau, H.: private communication 1979, as calculated from data reported in 11) Google Scholar
  104. 104.
    Walford, L. K., Carron, G. J., Schoeffel, J. A.: Mater. Res. Bull. 3, 911 (1968)Google Scholar
  105. 105.
    de Sobo, W.: J. Chem. Phys. 21, 764 (1953)Google Scholar
  106. 106.
    Berkenblit, M., Reismann, A.: J. Electrochem. Soc. 113, 93 (1966)Google Scholar
  107. 107.
    Reale, C.: Phys. Lett. 74A, 438 (1979)Google Scholar
  108. 108.
    Reski, H. D.: Thesis, Universität Düsseldorf 1981Google Scholar
  109. 109.
    Kniep, R.: unpublishedGoogle Scholar

Copyright information

© Springer-Verlag 1983

Authors and Affiliations

  • Rüdiger Kniep
    • 1
  • Albrecht Rabenau
    • 2
  1. 1.Institut für Anorganische Chemie und StrukturchemieUniversität DüsseldorfDüsseldorfFRG
  2. 2.Max-Planck-Institut für FestkörperforschungStuttgart 80FRG

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