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The chemistry of lanthanide ions in solution and in biological systems

  • Robert Joseph P. Williams
Conference paper
Part of the Structure and Bonding book series (STRUCTURE, volume 50)

Abstract

An examination of the structure of lanthanide(III) ion complexes in solution using nuclear magnetic resonance is made in considerable detail. The importance of hydration in both the inner and outer spheres is stressed. The structural data are then used in an attempt to understand the stability constants and the rates of exchange of bound ligands. Fluctional properties are also analysed. Finally, the importance of the structures, the stability constants and the kinetic properties are related to the effects of Ln(III) ions, and through them Ca(II) ions, in biological systems.

Keywords

Nuclear Magnetic Resonance Stability Constant Phosphatidyl Choline Nuclear Magnetic Resonance Study Outer Sphere 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag 1982

Authors and Affiliations

  • Robert Joseph P. Williams
    • 1
  1. 1.Inorganic Chemistry LaboratoryOxford UniversityOxfordEngland

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