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Kinetics and mechanisms of polyesterifications

I. Reactions of diols with diacids
  • Alain Fradet
  • Ernest Maréchal
Conference paper
Part of the Advances in Polymer Science book series (POLYMER, volume 43)

Abstract

In this article we critically review most of the literature concerning non-catalyzed, proton-catalyzed and metal-catalyzed polyesterifications. Kinetic data relate both to model esterifications and polyesterifications. Using our own results we analyze the experimental studies, kinetic results and mechanisms which have been reported until now. In the case of Ti(O Bu)4-catalyzed reactions we show that most results were obtained under experimental conditions which modify the nature of the catalyst. In fact, the true nature of active sites in the case of metal catalysts remains largely unknown.

Keywords

Activation Enthalpy Diethylene Glycol Terephthalic Acid Equal Reactivity Volatile Reactant 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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© Springer-Verlag 1982

Authors and Affiliations

  • Alain Fradet
    • 1
  • Ernest Maréchal
    • 1
  1. 1.Laboratoire de Synthèse MacromoléculaireUniversité Pierre et Marie CurieParis

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