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Structural and chemical modifications of cellulose by graft copolymerization

  • B. P. Morin
  • I. P. Breusova
  • Z. A. Rogovin
Conference paper
Part of the Advances in Polymer Science book series (POLYMER, volume 42)

Abstract

Studies concerning the following problems are reviewed;
  1. 1.

    Influence of the cellulose structure and of the chemical structure of the grafted polymer on the kinetics of graft copolymerization of cellulose, on the composition, and the structure of the cellulose products.

     
  2. 2.

    Kinetics of chemically initiated graft polymerization onto cellulose and its peculiarities connected with the heterogeneity of the process.

     
  3. 3.

    Specificities of grafting in the heterogenious medium and use of some effects in technology.

     
  4. 4.

    Basic trends in the development of the commercial process of graft polymerization on cellulose.

     
  5. 5.

    Polymer-analoguous conversion of polymer chains grafted to cellulose.

     

Keywords

Graft Copolymerization Chain Termination Viscose Fibre Staple Fibre Ethyl Acrylate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

List of Symbols

[c]

effective concentration of cellulose proportional to its mass

D

coefficient of monomer diffusion into the film

l

film width

kg

constant of chain growth

kct

constant of chain termination

kt

constant of transfer to monomer

krf

rate constant of the formation of cellulose radicals

k′o

rate constant of the decomposition of cellulose radicals

M

monomer concentration in the film

\(\bar P\)

average degree of polymerization

\(\bar R\)

averge grafting rate over the entire width of the film

Ri

initiations rate

t

reaction time

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Copyright information

© Springer-Verlag 1982

Authors and Affiliations

  • B. P. Morin
    • 1
  • I. P. Breusova
    • 1
  • Z. A. Rogovin
    • 1
  1. 1.Moscow Textile Institute, M. Kaluskaja IMoscowUSSR

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