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Investigation of polymers in solution by polarized luminescence

  • Elizaveta V. Anufrieva
  • Yuli Ya. Gotlib
Conference paper
Part of the Advances in Polymer Science book series (POLYMER, volume 40)

Abstract

In recent years, the method of polarized luminescence (PL) has become one of the most valuable methods for the study of macromolecules. It provides detailed information on micro-Brownian motion in polymer chains which is related to various features of the structures and conformational properties of macromolecules.

This review considers the use of PL in the investigation of macromolecules with covalently bonded luminescent markers (LM). This approach is very fruitful in the study of problems of physics and chemistry associated with changes in intra- and inter-macromolecular interactions, structural and conformational transformations in macromolecules and complex polymer systems, relationships between the reactivity of macromolecules and their intramolecular mobility, etc.

The PL method is based on the study of polarization and other parameters of light emitted by luminescent groups (LM) covalently bonded to some parts of the macromolecules or polymer systems.

The PL method can be widely and systematically used for the study of polymers and polymer systems of various classes if it is based on specifically developed methods of covalent bonding of LM to the macromolecules of the polymers investigated. The structure and optical properties of luminescent groups, their amount and type of bonding to the polymer chain should meet certain requirements. Moreover, LM should not effect the investigated properties of macromolecules.

Keywords

Main Chain Methyl Acrylate Carboxy Group Relaxation Spectrum Alkyl Sulfate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

List of abbreviations

PL

Polarized luminescence

LM

luminescent marker

LG

luminescent group

IMM

intramolecular mobility

ADM

9-anthryldiazomethane

PA

polyacid

PAA

polyacrylic acid

PAmA

polyamic acid

PGA

polyglutamic acid

PDME

polydimethoxyethylene

PMAA

polymethacrylic acid

PMA

polymethylacrylate

PMA-n

polyalkylmethacrylate-n

PMMA

polymethylmethacrylate

PPBE

polypropenylbenzyl ether

PS

polystyrene

P(α-CH3S)

poly-α-methylstyrene

PVBE

polyvinylbenzyl ether

PMMAA-n

methyl ester of poly-N-methacryloyl-ω-aminocarboxylic acids

PCMAA-n

cetyl ester of poly-N-methacryloyl-ω-aminocarboxylic acids

PChMAA-n

cholesterol ester of poly-N-methacryloyl-ω-aminocarboxylic acids

PChMAA-n

cholesterol ester of poly-N-methacryloyl-ω-aminocarboxylic acids

PVpD

polyvinylpyrrolidone

VP

vinylpyrrolidone

VNH2

vinylamine

CMC

carboxymethyl cellulose

PMMA-C

crosslinked polymethacrylic acid

PC

polymer-polymer complex

REE

rare earth element

DMF

dimethylformamide

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Copyright information

© Springer-Verlag 1981

Authors and Affiliations

  • Elizaveta V. Anufrieva
    • 1
  • Yuli Ya. Gotlib
    • 1
  1. 1.The Institute of High Molecular CompoundsAcademy of Sciences of the USSRLeningradUSSR

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