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The luminescence of closed-shell transition-metal complexes. New developments

  • George Blasse
Conference paper
Part of the Structure and Bonding book series (STRUCTURE, volume 42)

Abstract

This chapter describes new developments in the understanding of the luminescence of complexes consisting of a central highly-charged transition metal ion without d electrons surrounded by a number of oxygen ions (usually 4 or 6 in a tetrahedral or octahedral arrangement, respectively). Examples are titanates, vanadates, molybdates and tungstates. Recently results from low-temperature measurements have become available. On the other hand reliable molecular-orbital calculations have been performed. These are compared with each other. It is possible to obtain from the luminescence data information on the splitting of energy levels due to crystal-field and spin-orbit interactions. It is stressed that still a lot of data are lacking and that considerable effort has to be made to obtain a complete picture. Also the influence of ions with s2 configuration (Pb2+ Bi3+) on these complexes is considered.

Keywords

Decay Time Green Emission Host Lattice Stokes Shift Octahedral Complex 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag 1980

Authors and Affiliations

  • George Blasse
    • 1
  1. 1.Physical LaboratoryState UniversityTA UtrechtThe Netherlands

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