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Unperturbed dimensions of stereoregular polymers

  • Robert Jenkins
  • Roger S. Porter
Conference paper
Part of the Advances in Polymer Science book series (POLYMER, volume 36)

Abstract

Results from numerous studies of unperturbed dimensions for vinyl polymers are tabulated for the first time. A comparison is made between results from theta temperature measurement and those estimated from measurements in good solvents. Data for poly(1-pentene)38 was used by the authors to obtain Figs. 2–5. This data had not previously been used to obtain estimates of the uperturbed dimensions. It is concluded that these estimation procedures are generally quite acceptable, giving values usually within 8% of those determined in theta solvents. Statistical calculations for the dependence of the unperturbed dimensions on stereoregularity are considered in the light of the available data. The calculations predict an increase in the characteristic ratio, C, at intermediate tacticities for vinylidene polymers whereas a decrease is predicted for vinyl polymers. It is shown that little experimental data currently exists to confirm these predictions. It is pointed out that this is not a result of insufficient experimental studies, but rather insufficient characterization of those polymers which were studied.

Keywords

Diphenyl Ether Isoamyl Acetate Characteristic Ratio Vinyl Polymer Monte Carlo Chain 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag 1980

Authors and Affiliations

  • Robert Jenkins
    • 1
  • Roger S. Porter
    • 1
  1. 1.Materials Research Laboratory, Polymer Science and Engineering DepartmentUniversity of MassachusettsAmherstUSA

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