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Electroinitiated polymerization on electrodes

  • R. V. Subramanian
Conference paper
Part of the Advances in Polymer Science book series (POLYMER, volume 33)

Abstract

Electroinitiated polymerization reactions leading to the formation of polymer on electrode surfaces — as distinguished from that in the bulk of the electrolytic solution — are discussed here. The structure and morphology of the polymer, and its bonding and adhesion to the electrode surface are examined in addition to the mechanisms of polymerization. The formation of adherent coatings on electrodes discussed in this manner is that of polymers from not only vinyl monomers, but also from phenols, acrolein, benzonitrile, polyimide intermediates and phenylacetylene. The novel use of carbon fiber electrodes in electroinitiated polymerization is introduced and its significance to interphase modification in carbon fiber composites is brought out. With continuing advances in techniques for the study of the formation, control, and properties of polymer films on electrodes, concurrent progress in investigation of surface coatings and graphite composites is indicated.

Keywords

Polymer Coating Methacrylic Acid Nitrile Group Vinyl Monomer Graphite Fiber 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag 1979

Authors and Affiliations

  • R. V. Subramanian
    • 1
  1. 1.Department of Materials Science and EngineeringWashington State UniversityPullman

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