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Low-valent silicon

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Silicon Chemistry I

Part of the book series: Topics in Current Chemistry Fortschritte der Chemischen Forschung ((TOPCURRCHEM,volume 50))

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References

  1. Bürger, H.: Die Bindungsverhältnisse am Siliciumatom. In: Fortschr. Chem. Forsch. 9, pp. 1–59. Berlin-Heidelberg-New York: Springer 1967.

    Google Scholar 

  2. Ebsworth, E. A. V.: Physical basis of the chemistry of the group IV elements. In: The bond to carbon (ed. A. E. MacDiamid). New York: M. Dekker INC. 1968.

    Google Scholar 

  3. Herzberg, G.: Molecular spectra and molecular structure I. Spectra of diatomic molecules. New York: Van Nostrand, 1950.

    Google Scholar 

  4. Herzberg, G., Lagerquist, A., McKenzie, B. J.: Absorption spectrum of SiH in vacuum ultraviolet. Can. J. Phys. 47, 1889–97 (1969).

    CAS  Google Scholar 

  5. Appelblad, O., Barrow R. F., Verma, R. D.: Rotational analysis of the γ bands of SiF. J. Phys. B 1, 274–82 (1968).

    Article  Google Scholar 

  6. Singhal, S. R., Verma, R. D.: Rotational analysis of the A-X system of the SiCl molecule. Can. J. Phys. 49, 407–11 (1971).

    CAS  Google Scholar 

  7. Milligan, D. E., Jacox, M. E.: Infrared and ultraviolet spectra of the products of the vacuum-ultraviolet photolysis of silane isolated in an argon matrix. J. Chem. Phys. 52, 2594–08 (1970).

    Article  CAS  Google Scholar 

  8. Khanna, V. M., Hauge, R., Curl, R. F., jr., Margrave, J. L.: Infrared spectrum, force constants, and thermodynamic functions of SiF2. J. Chem. Phys. 47, 5031–37 (1967).

    CAS  Google Scholar 

  9. Maass, G., Hauge, R. H., Margrave, J. L.: The I. R. spectra of matrix-isolated SiBr2 and SiCl2. Z. Anorg. Allgem. Chem. 392, 295–302 (1972).

    Article  CAS  Google Scholar 

  10. Dubois, I., Herzberg, G., Verma, R. D.: Spectrum of SiH2. J. Chem. Phys. 47, 4262–63 (1967).

    Article  CAS  Google Scholar 

  11. Rao, V. M., Curl, R. F., jr., Timms, P. L., Margrave, J. L.: Microwave spectrum of SiF2. J. Chem. Phys. 43, 2557–58 (1965).

    Article  CAS  Google Scholar 

  12. Milligan, D. E., Jacox, M. E., Guillory, W. A.: Matrix-isolation study of the vacuumultraviolet photolysis of trifluorosilane. The infrared spectrum of the free radical SiF3. J. Chem. Phys. 49, 5330–35 (1968).

    Article  CAS  Google Scholar 

  13. Jacox, M. E., Milligan, D. E.: Matrix-isolation study of the vacuum-ultraviolet photolysis of trichlorosilane. The infrared spectrum of the free radical SiCl3. J. Chem. Phys. 49, 3130–35 (1968).

    Article  CAS  Google Scholar 

  14. Siebert, H.: Anwendungen der Schwingungsspektroskopie in der Anorganischen Chemie. Berlin-Heidelberg-New York: Springer 1960.

    Google Scholar 

  15. Jackson, C. V.: The spectrum of silicon hydride, Proc. Roy. Soc. (London) A, 126, 373–92 (1930).

    Article  CAS  Google Scholar 

  16. Rochester, G. D.: Die Banden-Spektren von SiH und SiD. Z. Phys. 101, 769–84 (1936).

    Article  CAS  Google Scholar 

  17. Douglas, A. E.: The spectrum of silicon hydride. Can. J. Phys. 35, 71–77 (1957).

    CAS  Google Scholar 

  18. Verma, R. D.: Spectrum of SiH and SiD. Can. J. Phys. 43, 2136–41 (1965).

    CAS  Google Scholar 

  19. Sauval, A. J.: Identification of SiH lines in the solar disc spectrum. Solar Phys. 10, 319–29 (1969).

    Article  CAS  Google Scholar 

  20. Lambert, D. L., Mallia, E. A.: The SiH A 2δ-X 2 Π (0,0) band in the fraunhofer spectrum. Monthly Notices Roy. Astron. Soc. 148, 313–24 (1970).

    CAS  Google Scholar 

  21. Jordan, P. C.: Lower electronic levels of the radicals SiH, SiH2 and SiH3. J. Chem. Phys. 44, 3400–06 (1966).

    Article  CAS  Google Scholar 

  22. Wirsam, B.: Combined SCF and CI calculation of the spectrum of SiH. Chem. Phys. Lett. 10, 180–82 (1971).

    Article  CAS  Google Scholar 

  23. Cade, P. E., Huo, W. M.: Electric dipole moment for first-and second-row diatomichydride molecules AH. J. Chem. Phys. 45, 1063–65 (1966).

    Article  CAS  Google Scholar 

  24. Douglas, A. E., Lutz, B. L.: Spectroscopic identification of the SiH+ molecule: The A 1π-X 1Σ+ system. Can. J. Phys. 48, 247–253 (1970).

    CAS  Google Scholar 

  25. Grevesse, N., Sauval, A. J.: Identification of SiHin the solar photospheric spectrum. Astron. Astrophys. 9, 232–38 (1970).

    CAS  Google Scholar 

  26. Honig, R. E.: Sublimation studies of silicon in the mass spectrometer. J. Chem. Phys. 22, 1610–11 (1954).

    Article  Google Scholar 

  27. Douglas, A. E.: The spectrum of the Si2 molecule. Can. J. Phys. 33, 801–10 (1955).

    CAS  Google Scholar 

  28. Verma, R. D., Warsop, P. A.: The absorption spectrum of the Si2 molecule. Can. J. Phys. 41, 152–60 (1963).

    CAS  Google Scholar 

  29. Lagerquist, A., Malmberg, C.: New absorption systems of the Si2 molecule in the vacuum ultraviolet region. Phys. Scr. 2, 45–49 (1970).

    Article  Google Scholar 

  30. Dubois, I., Leclercq, H.: Absorption spectrum of Si2 in the visible and near-ultraviolet region. Can. J. Phys. 49, 3053–54 (1971).

    CAS  Google Scholar 

  31. Ballik, E. A., Ramsay, D. A.: An extension of the phillips system of C2 and a survey of C2 states. Astrophys. J. 137, 84–101 (1963).

    Article  CAS  Google Scholar 

  32. Drowart, J., Maria, de, G. de Inghram, M. G.: Thermodynamic study of SiC utilizing a mass spectrometer. J. Chem. Phys. 29, 1015–21 (1958).

    Article  CAS  Google Scholar 

  33. Mc Kellar, A.: The unidentified blue-green bands in certain N-type stellar spectra. J. Roy. Astron. Soc. Can. 61, 147–60 (1947).

    Google Scholar 

  34. Kleman, B.: Laboratory excitation of the blue-green bands observed in the spectra of N-type stars. Astrophys. J. 123, 162–65 (1956).

    Article  CAS  Google Scholar 

  35. Weltner, W. jr., Mc Leod, D. jr.: Spectroscopy of silicon carbide and silicon vapors trapped in neon and argon matrices at 40° and 20° K. J. Chem. Phys. 41, 235–45 (1964).

    Article  CAS  Google Scholar 

  36. Jevons, W.: Spectroscopic investigations in connection with the active modification of nitrogen III. — Spectra developed by the tetrachlorides of silicon and titanium. Proc. Roy. Soc. (London) Ser. A. 89, 187–93 (1914).

    Article  CAS  Google Scholar 

  37. Mulliken, R. S.: The isotope effect in band spectra IV: The spectrum of silicon nitride. Phys. Rev. 26, 319–38 (1925).

    Article  CAS  Google Scholar 

  38. Jenkins, F. A., de Lazlo, H.: Structure of the violet bands of silicon nitride. Proc. Roy. (London) Ser. Soc. A. 122, 103–21 (1929).

    Article  CAS  Google Scholar 

  39. Dunn, E. M., Dunn, T. M.: Violet electronic emission of SiN. Can. J. Phys. 50, 860–61 (1972).

    CAS  Google Scholar 

  40. Nagaraj, S., Verma, R. D.: New spectrum of the SiO+ molecule. Can. J. Phys. 46, 1597–1602 (1968).

    CAS  Google Scholar 

  41. Dunn, T. M., Rao, K. M., Nagaraj, S., Verma, R. D.: New spectrum of the SiO+ molecule-a correction. Can. J. Phys. 47, 2128 (1969).

    CAS  Google Scholar 

  42. Woods, L. H.: On the silicon oxide bands. Phys. Rev. 63, 426–30 (1943).

    Article  CAS  Google Scholar 

  43. Ogilvie, J. F., Cradock, S.: Spectroscopic studies of the photodecomposition of silyl azides in argon matrices near 4° K: Detection of iminosilicon, HNSi. Chem. Commun. 1966, 364–65.

    Google Scholar 

  44. Ogilvie, J. F., Newlands, M. J.: Spectroscopic data and bonding in compounds of silicon and germanium with Nitrogen. Trans. Faraday Soc. 65, 2602–06 (1969).

    Article  CAS  Google Scholar 

  45. Anderson, J. S., Ogden, J. S., Ricks, M. J.: Infrared spectra and structures of matrixisolated disilicon, digermanium, and ditin oxides (Si2 O2, Ge2 O2, Sn2 O2). Chem. Commun. 1968, 1585–86.

    Google Scholar 

  46. Anderson, J. S., Ogden, J. S.: Matrix isolation studies of group-IV oxides. I. Infrared 42c) spectra and structures of SiO, Si2 O2, and Si3 O3. J. Chem. Phys. 51, 4189–96 (1969).

    Article  CAS  Google Scholar 

  47. Hastie, J. W., Hauge, R. H., Margrave, J. L.: Reactions and stuctures of matrix-isolated SiO species at low temperatures from infrared spectra. Inorg. Chim. Acta 3, 601–06 (1969).

    Article  CAS  Google Scholar 

  48. Schaschel, E. T., Gray, D. N., Timms, P. L.: Reactions of SiO with organic compounds. J. Organometal. Chem. 35, 69–79 (1972).

    Article  CAS  Google Scholar 

  49. Heil, T. G., Schaefer, H. F.: Potential curves for the valence-exited states of silicon, monoxide. A theoretical study. J. Chem. Phys. 56, 958–68 (1972).

    Article  CAS  Google Scholar 

  50. Saper, P. G.: Rotational analysis of ultraviolet bands of silicon monoxide. Phys. Rev. 42, 498–508 (1932).

    Article  CAS  Google Scholar 

  51. Barrow, R. F., Robinnson, H. C.: The absorption spectra of the gaseous monoxides of silicon, germanium and tin in the schumann region. Proc. Roy. Soc. (London) Ser. A. 224, 374–88 (1954).

    Article  CAS  Google Scholar 

  52. Lagerquist, A., Uhler, U.: The ultra-violet band — system of silicon monoxide. Arkiv Fysik 6, 95–111 (1953).

    Google Scholar 

  53. Nagaraj, S., Verma, R. D.: A 3ε−3 π transition of the SiO molecule. Can. J. Phys. 48, 1436–40 (1970).

    CAS  Google Scholar 

  54. Cornet, R., Dubois, I.: New electronic transition of SiO. Can. J. Phys. 50, 630–35 (1972).

    CAS  Google Scholar 

  55. Brewer, L., Rosenblatt, G. M.: Advances in high temperature Chemistry, Vol 2. New York: Academic Press 1969.

    Google Scholar 

  56. Hildenbrand, D. L., Murad, E.: Dissociation energy and ionization potential of silicon monoxide. J. Chem. Phy. 51, 807–11 (1969).

    Article  CAS  Google Scholar 

  57. Raymonda, J. W., Muenter, J. S., Klemperer, W. A.: Electric dipole moment of SiO and GeO. J. Chem. Phys. 52, 3458–61 (1970).

    Article  CAS  Google Scholar 

  58. Törring, T.: Das Mikrowellenrotationsspektrum des SiO. Z. Naturforsch. A. 23, 777–78 (1968).

    Google Scholar 

  59. Cornet, R., Dubois, I., Gerkens, M., Tripnaux, E.: B 2Σ+−X 2Σ +transition of the SiO+ ion. Bull. Soc. Roy. Sci. Liege 41, 183–87 (1972).

    CAS  Google Scholar 

  60. Barrow, R. F., Deutsch, J. L., Lagerquist, A., Westerlund, B.: Rotational analysis of the E-X system of silicon monosulphide. Proc. Phys. Soc. (London) 78, 1307–09 (1961).

    Article  CAS  Google Scholar 

  61. Nilheden, G.: The perturbations in the near ultraviolet band-system (D-X) of silicon monosulphide. Arkiv Fysik 10, 19–36 (1956).

    Google Scholar 

  62. Hoeft, J., Lovas, F. J., Tiemann, E., Törring, T.: Elektrisches Dipolmoment und Mikrowellenrotationsspektrum von SiSe. Z. Naturforsch. A 24, 1422–23 (1969).

    CAS  Google Scholar 

  63. Hoeft, J.: Das Mikrowellenrotationsspektrum des SiSe. Z. Naturforsch. A 20, 1122–24 (1965).

    Google Scholar 

  64. Hoeft, J., Lovas, F. J., Tiemann, E., Törring, T.: Dipole moments and hyperfine structure of the group IV/VI. Diatomic molecules. J. Chem. Phys. 53, 2736–43 (1970).

    Article  CAS  Google Scholar 

  65. Verma, R. D.: A 4Σ−− 2π transition of the SiF molecule. Can. J. Phys. 40, 586–97 (1962).

    CAS  Google Scholar 

  66. Johns, J. W. C., Barrow, R. F.: The band spectrum of silicon monofluoride, SiF. Proc. Phys. Soc. (London) 71, 476–84 (1958).

    Article  CAS  Google Scholar 

  67. O'Hare, P. A. G., Wahl, A. C.: Molecular orbital investigation of CF and SiF and their positive and negative ions. J. Chem. Phys. 55, 666–76 (1971).

    Article  Google Scholar 

  68. Barrow, R. F., Butler, D., Johns, J. W. C., Powell, J. L.: Some observations on the spectra of the diatomic fluorides of Si, Ge, Sn, Pb. Proc. Phys. Soc. (London) 73, 317–20 (1959).

    Article  CAS  Google Scholar 

  69. Hastie, J. W., Margrave, J. L.: Re-evaluation of the dissociation energy of CaF. J. Chem. Eng. Data 13, 428–29 (1968).

    Article  CAS  Google Scholar 

  70. Oldershaw, G. A., Robinson, K.: Ultraviolet absorption spectrum of silicon monochloride. J. Mol. Spectr. 38, 306–13 (1971).

    Article  CAS  Google Scholar 

  71. Oldershaw, G. A., Robinson, K.: Ultra-violet spectrum of SiBr. Trans. Faraday Soc. 67, 1870–74 (1971).

    Article  CAS  Google Scholar 

  72. Rao, K. B., Haranath, P. B. V.: The emission band spectrum of SiBr in the visible region, J. Phys. B 2, 1381–84 (1969).

    Article  CAS  Google Scholar 

  73. Kuznetsova, L. A., Kuzyakov, Yu. Ya.: Rotational analysis of the 2Σ-2π1/2 band system of SiBr molecule. Vestn. Mosk. Univ. Ser. II: Khim. 24, 103–04 (1969).

    CAS  Google Scholar 

  74. Oldershaw, G. A., Robinson, K.: Ultra-violet absorption spectra of Gel and SiI. Trans. Faraday Soc. 64, 2256–59 (1968).

    Article  CAS  Google Scholar 

  75. Lakshminarayana, A., Haranath, P. B. W.: The emission band spectrum of silicon monoiodide. J. Phys. B 3, 576–78 (1970).

    Article  CAS  Google Scholar 

  76. Billingsley, J.: The absorption and emission spectrum of SiI. J. Mol. Spectr. 43, 1284–7 (1972).

    Article  Google Scholar 

  77. Houdart, R.: Spectre infrarouge de la molécule AuSi. Compt. Rend. 262, 550–53 (1966).

    Google Scholar 

  78. Kaufman, M., Muenter, J., Klemperer, W. A.: Geometry of some refractory metal dioxides. J. Chem. Phys. 47, 3365–66 (1967).

    Article  CAS  Google Scholar 

  79. Hengge, E.: Properties and preparations of the SiSi linkages in inorganic and organic compounds. Topics in current chemistry.

    Google Scholar 

  80. Bowrey, M., Purnell, J. H.: Insertion reactions of SiH2. J. Am. Chem. Soc. 92, 259–495 (1970).

    Article  Google Scholar 

  81. Skell, P. S., Goldstein, E. J.: Dimethylsilene: CH3 SiCH3. J. Am. Chem. Soc. 86, 1442–43 (1964).

    Google Scholar 

  82. Nefedow, O. M., Manakow, M. N.: Entstehung und Reaktionen des Dimethylsilylens, eines Siliciumanalogons der Carbene. Angew. Chem. 76, 270 (1964).

    Article  Google Scholar 

  83. Atwell, W. H., Weyenberg, D. R.: Zwischenverbindungen des zweiwertigen Siliciums (Silylene). Angew. Chem. 81, 485–93 (1969).

    Article  Google Scholar 

  84. Liu, C. S., Margrave, J. L., Thompson, J. C.: Reactions of silicon difluoride with unsaturated organic compounds. Part II. Alkyl Substituted Alkynes. Can. J. Chem. 50, 465–73 (1972).

    Article  CAS  Google Scholar 

  85. Liu, C. S., Margrave, J. L., Thompson, J. C., Timms, P.: Reactions of unsaturated compounds with silicon difluoride. Part I. Acetylene. Can. J. Chem. 50, 459–64 (1972).

    Article  CAS  Google Scholar 

  86. Margrave, J. L., Wilson, P. W.: Silicon difluoride, a carbene analog. Its reactions and properties. Accounts Chem. Res. 4, 145–52 (1971).

    Article  CAS  Google Scholar 

  87. Timms, P. L.: Some reactions of silicon dichloride. Inorg. Chem. 7, 387–89 (1968).

    Article  CAS  Google Scholar 

  88. Schmid, G., Boese, R.: Silylen — Metallkomplexe. Dijodsilylen — pentacarbonyl — wolfram (0). Chem. Ber. 105, 3306–09 (1972).

    Article  CAS  Google Scholar 

  89. Schmid, G., Balk, H. J.: Silylene als Liganden in Platinkomplexen. Chem. Ber. 103, 2240–44 (1970).

    Article  CAS  Google Scholar 

  90. Dubois, I.: The absorption spectrum of the free SiH2 radical. Can. J. Phys. 46, 2485–90 (1968).

    CAS  Google Scholar 

  91. Hopkins, H. P., Thompson, J. C., Margrave, J. L.: Electron spin resonance studies of silicon difluoride. J. Am. Chem. Soc. 90, 901–02 (1968).

    Article  CAS  Google Scholar 

  92. Rao, D. R., Venkatesvarlu, P.: Emission spectrum of SiF2. Part I. The band system in the region 2755–2179 Å. J. Mol. Spectr. 7, 287–303 (1961).

    Article  CAS  Google Scholar 

  93. Hastie, J. W., Hauge, R. H., Margrave, J. L.: Infrared spectra of silicon difluoride in neon and argon matrices. J. Am. Chem. Soc. 91, 2536–38 (1969).

    Article  CAS  Google Scholar 

  94. Milligan, D. E., Jacox, M.: Matrix-isolation study of the vacuum-ultraviolet photolysis of difluorosilane. The infrared and ultraviolet spectra of the free radical SiF2. J. Chem. Phys. 49, 4269–75 (1968).

    Article  CAS  Google Scholar 

  95. Rao, R. D.: New electronic emission from SiF2. J. Mol. Spectr. 34, 284–87 (1970).

    Article  CAS  Google Scholar 

  96. Dixon, R. N., Halle, M.: Rotational analysis of absorption bands in the 2266 Å system of SiF2. J. Mol. Spectry. 36, 192–203 (1970).

    Article  CAS  Google Scholar 

  97. Khanna, V. M., Besenbruch, G., Margrave, J. L.: Ultraviolet absorption spectrum of SiF2. J. Chem. Phys. 46, 2310–14 (1967).

    Article  CAS  Google Scholar 

  98. Rao, V. M., Curl, R. F., jr.: Microwave spectrum and force constants of SiF2: Centrifugal Distortion. J. Chem. Phys. 45, 2032–36 (1966).

    Article  CAS  Google Scholar 

  99. Johns, J. W. C., Chantry, G. W., Barrow, R. F.: The ultraviolet spectrum of silicon difluoride. Trans. Faraday Soc. 54, 1589–91 (1958).

    Article  CAS  Google Scholar 

  100. Gole, J. L., Hauge, R. H., Margrave, J. L.: The vacuum ultraviolet spectra of SiF2 and GeF2. J. Mol. Spectry. 43, 441–51 (1972).

    Article  CAS  Google Scholar 

  101. Schäfer, H., Morcher, B.: Chemische Transportreaktionen. III. Über den Transport von Silicium im Temperaturgefälle unter Mitwirkung der Silicium(II)-halogenide und über die Druckabhängigkeit der Transportrichtung. Z. Anorg. Allgem. Chem. 290, 279–91 (1957).

    Article  Google Scholar 

  102. Schäfer, H., Bruderreck, H., Morcher, B.: Die Thermochemie der Silicium(II)halogenide. Z. Anorg. Allgem. Chem. 352, 122–37 (1967).

    Article  Google Scholar 

  103. Milligan, D. E., Jacox, M. E.: Matrix-isolation study of the vacuum-ultraviolet photolysis of dichlorosilane. The infrared spectrum of the free radical SiCl2. J. Chem. Phys. 49, 1938–42 (1968).

    Article  CAS  Google Scholar 

  104. Asundi, R. K., Karim, M., Samuel, R.: Emission bands of SiCl2 and SnCl2. Proc. Phys. Soc. (London) 50, 581–98 (1938).

    Article  CAS  Google Scholar 

  105. Herzberg, G., Verma, R. D.: Spectra and structures of the free HSiCl and HSiBr radicals. Can. J. Phys. 42, 395–432 (1964).

    CAS  Google Scholar 

  106. Billingsley, J.: Absorption spectrum of HSiI. Can. J. Phys. 50, 531–43 (1972).

    CAS  Google Scholar 

  107. Hougen, J. T., Watson, J. K. G.: Anomalous rotational line intensities in electronic transitions of polyatomic molecules: Axis-switching. Can. J. Phys. 43, 298–320 (1965).

    CAS  Google Scholar 

  108. Popkov, K. K.: Possibility of the formation of siliconium and silanolate ions. Zh. Obshch. Khim. 39, 2791 (1969).

    CAS  Google Scholar 

  109. Olah, G. A., Mo, Y. K.: Organometallic chemistry. III. Attempted preparation of trivalent silicocations (silicenium ions). The exchange reaction of methylfluorosilanes with antimony pentafluoride. J. Am. Chem. Soc. 93, 4942–43 (1971).

    Article  CAS  Google Scholar 

  110. Jutzi, P.: Massenspektrometrischer Nachweis des 9-methyl-9-silaanthracen-ions. J. Organometal. Chem. 16, 71–72 (1969).

    Article  Google Scholar 

  111. Barton, T. J., McIntosh, C. L.: Spectroscopic evidence for a silicon-carbon double-bond. Chem. Commun. 1972, 861–62.

    Google Scholar 

  112. Davidson, I. M. T.: Some aspects of silicon radical chemistry. Quart. Rev. (London) 25, 111–33 (1971).

    CAS  Google Scholar 

  113. Bowles, A. J., Hudson, A., Jackson, R. A.: An electron resonance study of some reactions involving silyl radicals. J. Chem. Soc. (B) 1971, 1947–49.

    Google Scholar 

  114. Bennett, S. W., Eaborn, C., Jackson, R. A., Root, K. D. J.: An electron spin resonance study of some silyl radicals. J. Chem. Soc. (A) 1970, 348–51.

    Google Scholar 

  115. Bennett, S. W., Eaborn, C., Hudson, A., Hussain, H. A., Jackson, R. A.: Electron spin resonance spectra of trimethylsilyl, trimethylgermyl and related free radicals in solution. J. Organometal. Chem. 16, 36–38 (1969).

    Article  Google Scholar 

  116. Krusic, P. J., Kochi, J. K.: Electron spin resonance of organosilyl radicals in solution. J. Am. Chem. Soc. 91, 3938–40 (1969).

    Article  CAS  Google Scholar 

  117. Morehouse, R. L., Christiansen, J. J., Gordy, W.: ESR of free radicals trapped in inert matrices at low temperature: CH3, SiH3, GeH3, and SnH3. J. Chem. Phys. 45, 1751–58 (1966).

    Article  CAS  Google Scholar 

  118. Jackel, G. S., Gordy, W.: Electron spin resonance of free radicals formed from group-IV and group-V hydrides in inert matrices at low temperature. Phys. Rev. 176, 443–52 (1968).

    Article  CAS  Google Scholar 

  119. Sharp, J. H., Symons, M. C. R.: Unstable intermediates. Part LXXXI. Electron spin resonance spectra of γ-irradiated methyl silanes: Methyl sityl radicals. J. Chem. Soc. (A) 1970, 3084–87.

    Google Scholar 

  120. Geoffroy, M., Lucken, E. A. C.: The electron spin resonance spectrum of triphenylsilyl radical formed by the x-irradiation of monocrystalline triphenylsilane. Helv. Chim. Acta 53, 813–18 (1970).

    Article  CAS  Google Scholar 

  121. Cooper, J., Hudson, A., Jackson, R. A.: Substituent effects on the geometry of some trigonal radicals. Mol. Phys. 23, 209–12 (1972).

    Article  CAS  Google Scholar 

  122. Hesse, C., Leray, N., Roncin, J.: Structure of methylchlorosilyl radicals. J. Chem. Phys. 57, 749–52 (1972).

    Article  CAS  Google Scholar 

  123. Merritt, M. V., Fessenden, R. W.: ESR spectra of the fluorinated silyl radicals. J. Chem. Phys. 56, 2353–57 (1972).

    Article  CAS  Google Scholar 

  124. Birchall, T., Drummond, L: Nuclear magnetic resonance spectra of phenylsilane, phenylgermane, and their anions: Comments on the relative acidities of phenylgermane and germane. J. Chem. Soc. (A) 1970, 1401–05.

    Google Scholar 

  125. Weiss, E., Hencken, G., Kühr, H.: Kristallstrukturen und kernmagnetische Breitlinienresonanz der Alkalisilyle SiH3M (M = K, Rb, Cs). Chem. Ber. 103, 2868–72 (1970).

    Article  CAS  Google Scholar 

  126. Benkeser, R. A.: The chemistry of trichlorosilane-tertiary amine combinations. Accounts Chem. Res. 4, 94–100 (1971).

    Article  CAS  Google Scholar 

  127. Witte, J., Schnering, H. G. V.. Die Kristallstruktur von NaSi und NaGe. Z. Anorg. Allgem. Chem. 327, 260–73 (1964).

    Article  CAS  Google Scholar 

  128. Busmann, E.: Die Kristallstrukturen von KSi, RbSi, CsSi, KGe, RbGe und CsGe. Z. Anorg. Allgem. Chem. 313, 90–106 (1961).

    Article  CAS  Google Scholar 

  129. Janzon, K. H., Schäfer, H., Weiss, A.: Zur Kenntnis der Disilicide der Erdalkalimetalle. Z. Anorg. Allgem. Chem. 372, 87–99 (1970).

    Article  CAS  Google Scholar 

  130. Eisenmann, B., Riekel, C., Schäfer, H., Weiss, A.: Zur Kenntnis ternärer Disllicide der Erdalkalimetalle. Z. Anorg. Allgem. Chem. 372, 325–31 (1970).

    Article  CAS  Google Scholar 

  131. Bürger, H., Eujen, R.: Infrarotspektren der Tetraederionen Si4 4− und Ge4 4−. Z. Anorg. Allgem. Chem. 394, 19–25 (1972).

    Article  Google Scholar 

  132. Hellner, E.: Die Kristallstruktur des CaSi. Z. Anorg. Allgem. Chem. 261, 226–36 (1950).

    CAS  Google Scholar 

  133. Rocktäschel, G., Weiss, A.: Zur Kenntnis der Strontiumsilicide. Z. Anorg. Allgem. Chem. 316, 231–36 (1962).

    Article  Google Scholar 

  134. Rocktäschel, G.: Diss. TH Darmstadt, 1962.

    Google Scholar 

  135. Müller, W., Schäfer, H., Weiss, A.: Zur Kenntnis der Phasen CaLiSi2 und CaLiGe2. Z. Naturforsch. B 26, 534–36 (1971).

    Google Scholar 

  136. Eisenmann, B., Janzon, K. H., Schäfer, H., Weiss, A.: Zur Kenntnis von Ba3Si4. Z. Naturforsch. B 24, 457–58 (1969).

    CAS  Google Scholar 

  137. Axel, H., Schäfer, H., Weiss, A.: Die Kristallstruktur von Lithiumsilicid Li2Si. Angew. Chem. 77, 379–80 (1965).

    Article  CAS  Google Scholar 

  138. Eisenmann, B., May, N., Müller, W., Schäfer, H., Weiss, A., Winter, J., Ziegleder, G.: Neue Vertreter des ThCr2Si2-Typs und dessen Verwandtschaft zum AntiPbFCI-Gitter. Z. Naturforsch. B 25, 1350–52 (1970).

    CAS  Google Scholar 

  139. May, N., Schäfer, H.: Neue Verbindungen im ThCr2Si2-Typ. Z. Naturforsch. B 20, 864–65 (1972).

    Google Scholar 

  140. Schäfer, H., Axel, H., Weiss, A.: Die Kristallstruktur des Li7Si2. Z. Naturforsch. B 20, 1010 (1965).

    Google Scholar 

  141. Nagorsen, G., Rocktäschel, G., Schäfer, H., Weiss, A.: Die Kristallstruktur der Phase Sr5Si3. Z. Naturforsch. B 22, 101–02 (1967).

    CAS  Google Scholar 

  142. Janzon, K., Schäfer, H., Weiss, A.: Die Kristallstruktur der Phase Ba5Si3. Z. Naturforsch. B 21, 287 (1966).

    CAS  Google Scholar 

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  1. Institut für Anorganische Chemie der Technischen Universität, Braunschweig

    Prof. Dr. Hans Bürger & Dipl. Chem. Reint Eujen

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  1. Prof. Dr. Hans Bürger
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  2. Dipl. Chem. Reint Eujen
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© 1974 Springer-Verlag

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Bürger, H., Eujen, R. (1974). Low-valent silicon. In: Silicon Chemistry I. Topics in Current Chemistry Fortschritte der Chemischen Forschung, vol 50. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-06714-0_7

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  • DOI: https://doi.org/10.1007/3-540-06714-0_7

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  • Print ISBN: 978-3-540-06714-6

  • Online ISBN: 978-3-540-38008-5

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