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Surface-Initiated Living Radical Polymerizations Using Iodine, Organotellurium, and Organic Catalysts

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Controlled Radical Polymerization at and from Solid Surfaces

Part of the book series: Advances in Polymer Science ((POLYMER,volume 270))

Abstract

This chapter reviews surface-initiated living radical polymerizations via iodine transfer polymerization (ITP), organotellurium-mediated radical polymerization (TERP), and reversible chain-transfer catalyzed polymerization (RTCP) using organic catalysts. The successful application of these polymerizations made it possible to graft various polymers with well-defined structures onto flat substrates and nanoparticles. Living radical polymerizations, including ITP, TERP, and RTCP, also lead to a striking increase in the graft density. Because of their unique advantages as synthetic tools, ITP, TERP, and RTCP can be used to expand the scope of controlled surface modification.

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Abbreviations

σ :

Graft density

σ*:

Dimensionless reduced graft density

AT:

Atom transfer

ATRP:

Atom transfer radical polymerization

BHE:

(2-Bromo-2-methyl)propionyloxyhexyltriethoxysilane

BzMA:

Benzyl methacrylate

C ex :

Degenerative (exchange) chain transfer constant

DC:

Dissociation-combination

DT:

Degenerative (exchange) chain transfer

GMA:

Glycidyl methacrylate

GPC:

Gel permeation chromatography

HEA:

2-Hydroxyethyl acrylate

ICAR:

Initiators for continuous activator regeneration

IHE:

(2-Iodo-2-methyl)propionyloxyhexyltriethoxysilane

ITP:

Iodine transfer polymerization

L e :

Equilibrium thickness in a good solvent

LRP:

Living radical polymerization

MMA:

Methyl methacrylate

M n :

Number-average molecular weight

M w :

Weight-average molecular weight

N :

Degree of polymerization

NIPAM:

N-Isopropylacrylamide

NIS:

N-Iodosuccinimide

NMP:

Nitroxide-mediated polymerization

NVC:

N-Vinylcarbazole

NVP:

N-Vinylpyrrolidine

PEGA:

Poly(ethyleneglycol)methylether acrylate

Polymer• :

Polymer radical

Polymer-X:

Dormant species

RAFT:

Reversible addition-fragmentation chain transfer

RCMP:

Reversible complexation mediated polymerization

RITP:

Reverse iodine transfer polymerization

RT:

Reversible chain transfer

RTCP:

Reversible chain transfer catalyzed polymerization

SAM:

Self-assembled monolayer

TeBE:

4-(Triethoxysilyl)butyl 2-methyltellanyl-2-methylpropionate

TeMe:

Methyltelluride

TEOS:

Triethoxysilyl

TERP:

Organotellurium-mediated radical polymerization

VAc:

Vinyl acetate

VDF:

Vinylidene fluoride

X:

Capping agent

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Authors and Affiliations

  1. Institute for Chemical Research, Kyoto University, Uji, Kyoto, 611-0011, Japan

    Atsushi Goto & Yoshinobu Tsujii

Authors
  1. Atsushi Goto
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  2. Yoshinobu Tsujii
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Correspondence to Atsushi Goto .

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Editors and Affiliations

  1. Makromolekulare Chemie, Georg-August-Universität Institut für Physikalische Chemie, Göttingen, Germany

    Philipp Vana

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Goto, A., Tsujii, Y. (2015). Surface-Initiated Living Radical Polymerizations Using Iodine, Organotellurium, and Organic Catalysts. In: Vana, P. (eds) Controlled Radical Polymerization at and from Solid Surfaces. Advances in Polymer Science, vol 270. Springer, Cham. https://doi.org/10.1007/12_2015_310

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