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Nanopattern Evolution in Block Copolymer Films: Experiment, Simulations and Challenges

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Complex Macromolecular Systems I

Part of the book series: Advances in Polymer Science ((POLYMER,volume 227))

Abstract

The present contribution reviews novel insights into block copolymer phase behavior and nanostructure formation in confined geometries. We focus on state-of-the-art experimental and theoretical progress in this area, with an emphasis on characterization methods and techniques that provide a quantitative framework for fundamental analysis. We discuss and compare basic system parameters that are readily controlled in simulations and in experiments, and present comparative studies of increasing degree of complexity concerning the phase behavior and ordering dynamics of cylinder- and lamella-forming block copolymers in thin films.

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Abbreviations

a 0 :

Bulk domain spacing

BCC:

Body-centered cubic

C ∥ :

Parallel-oriented cylinder

C ⊥ :

Perpendicular-oriented cylinder

DDFT:

Dynamic density functional theory

DSCFT:

Dynamic self-consistent field theory

GISAXS:

Grazing incidence small angle X-ray scattering

h:

Film thickness

L:

Lamella

MC:

Monte Carlo

ODT:

Order–disorder transition

P2VP:

Poly(2-vinyl pyridine)

PB:

Polybutadiene

PL:

Hexagonally perforated lamella phase

PS:

Polystyrene

SAXS:

Small angle X-ray scattering

SB:

Polystyrene-block-polybutadiene diblock copolymer

SBS:

Polystyrene-block-polybutadiene triblock copolymer

SCFT:

Self-consistent field theory

SCMF:

Particle-based SCFT

SE:

Spectroscopic ellipsometry

SFM:

Scanning force microscopy

SV:

Polystyrene-block-poly(2-vinyl pyridine) diblock copolymer

SVT:

Polystyrene-block-poly(2-vinylpyridine)-block-poly(tert- butylmethacrylate) triblock copolymer

TEM:

Transmission electron microscopy

ϕ:

Polymer volume fraction

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Acknowledgements

This research has been supported by the DPG (Sonderforschungsbereich 481, TP B7/A9). The authors acknowledge the valuable contribution of R. Magerle, A.V. Zvelindovsky, A. Knoll, S. Ludwigs, A. Horvat, N. Rehse, H. Elbs, K. Lyakhova, J. Gensel, and M. Hund.

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Authors and Affiliations

  1. Physikalische Chemie II, Universität Bayreuth, 95440, Bayreuth, Germany

    Larisa Tsarkova

  2. Leiden Institute of Chemistry, Leiden University, 9502, 2300, RA, Leiden, The Netherlands

    G. J. Agur Sevink

  3. Johannes Gutenberg Universität Mainz, Mainz, Germany

    Georg Krausch

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  1. Larisa Tsarkova
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  2. G. J. Agur Sevink
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  3. Georg Krausch
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Correspondence to Larisa Tsarkova .

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Editors and Affiliations

  1. Inst. Makromolekülforschung, LS für Makromolekulare Chemie II, Universität Bayreuth, Universitätsstr. 30, Bayreuth, 95440, Germany

    Axel H. E. Müller

  2. Inst. Makromolekulare Chemie I, Univ. Bayreuth, Bayreuth, 95440, Germany

    Hans-Werner Schmidt

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Tsarkova, L., Sevink, G.J.A., Krausch, G. (2010). Nanopattern Evolution in Block Copolymer Films: Experiment, Simulations and Challenges. In: Müller, A., Schmidt, HW. (eds) Complex Macromolecular Systems I. Advances in Polymer Science, vol 227. Springer, Berlin, Heidelberg. https://doi.org/10.1007/12_2010_54

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