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Role of Physical Factors in the Process of Obtaining Copolymers

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Book cover Conformation-Dependent Design of Sequences in Copolymers II

Part of the book series: Advances in Polymer Science ((POLYMER,volume 196))

Abstract

A brief introduction into the principles of the statistical description of the chemical structure of linear heteropolymers is given. A comprehensive analysis of diffusion-controlled polymeranalogous reactions is provided in terms of the statistical chemistry and the statistical physics of polymers. The interplay of these two statistical approaches is conclusively demonstrated for the discussion of the quantitative theory of free-radical copolymerization in anomalous systems. The impact of physical factors on principal regularities of interphase free-radical copolymerization has been discussed in detail.

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Acknowledgments

Support of this work by the Alexander-von-Humboldt Foundation (Program for investment in the Future (ZIP)) and INTAS (Project 01-607) is gratefully acknowledged.

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Authors and Affiliations

  1. Polymers & Crystals Chair, Physics Department, Moscow State University, 119992, Moscow, Russia

    Semion I. Kuchanov & Alexei R. Khokhlov

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  1. Semion I. Kuchanov
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  2. Alexei R. Khokhlov
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Correspondence to Alexei R. Khokhlov .

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Alexei R. Khokhlov

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Kuchanov, S.I., Khokhlov, A.R. Role of Physical Factors in the Process of Obtaining Copolymers. In: Khokhlov, A.R. (eds) Conformation-Dependent Design of Sequences in Copolymers II. Advances in Polymer Science, vol 196. Springer, Berlin, Heidelberg. https://doi.org/10.1007/12_054

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